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In this work, a porous Pr(OH)\n                    <jats:sub>3<\/jats:sub>\n                    catalyst (denoted as PrH) was successfully synthesized via an alkali\u2010induced self\u2010templating strategy, using an f\u2010d cyanide\u2010bridged coordination framework as the precursor. The unique porous architecture of PrH, combined with its abundant surface hydroxyl groups, synergistically functions as a powerful \u201cadsorption pump\u201d, efficiently enriching antibiotic norfloxacin (NOR) on the catalyst surface through ligand exchange. Subsequently, the concentrated pollutants are degraded via PMS activation, driven by the reversible Pr\n                    <jats:sup>3<\/jats:sup>\n                    <jats:sup>+<\/jats:sup>\n                    \/Pr\n                    <jats:sup>4<\/jats:sup>\n                    <jats:sup>+<\/jats:sup>\n                    redox cycle at the Pr sites. This intrinsic adsorption\u2010catalysis synergy, centered on the bifunctional Pr centers, effectively enhances the local concentration of reactants and promotes the utilization of reactive oxygen species, leading to high degradation efficiency even at low catalyst dosages. Furthermore, the PrH catalyst exhibits good cycling stability, maintaining high structural integrity over repeated use. This work not only provides an efficient strategy for designing porous rare\u2010earth catalysts but also offers valuable insights into the synergistic adsorption\u2010catalysis mechanism for antibiotic removal.\n                  <\/jats:p>","DOI":"10.1002\/smll.74539","type":"journal-article","created":{"date-parts":[[2026,7,11]],"date-time":"2026-07-11T12:50:16Z","timestamp":1783774216000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Superior \u201cAdsorption Pump\u201d Functionality of Pr(OH)\n                    <sub>3<\/sub>\n                    Catalysts Enables Efficient Antibiotic Degradation via Synergistic Effect"],"prefix":"10.1002","volume":"22","author":[{"given":"Haoran","family":"Niu","sequence":"first","affiliation":[{"name":"Zhuhai Key Laboratory of Coastal Environmental Processes and Ecological Restoration, Advanced Institute of Natural Sciences Beijing Normal University  Zhuhai Guangdong 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