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Conventional NH\n                    <jats:sub>3<\/jats:sub>\n                    decomposition, however, relies on Ru\u2010based noble metal catalysts and requires temperatures above 400\u00b0C, resulting in high cost and limited scalability. The development of efficient, low\u2010cost catalysts that operate under mild conditions is therefore imperative. Here, we report a novel Z\u2010scheme photocatalyst composed of Co\u2010doped CdS quantum dots anchored on NH\n                    <jats:sub>2<\/jats:sub>\n                    \u2010MIL\u201053(Al) (Co\u2010CdS QDs\/MIL) via an interfacial N\u2013Co\u2013S single atom electron bridge (Co\u2010SAEB). By precisely steering the separation and migration of photogenerated charges, this architecture drives efficient photocatalytic NH\n                    <jats:sub>3<\/jats:sub>\n                    decomposition at ambient temperature. The catalyst achieves an exceptional H\n                    <jats:sub>2<\/jats:sub>\n                    evolution rate of 18 \u00b5mol\u00b7g\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u00b7s\n                    <jats:sup>\u22121<\/jats:sup>\n                    , surpassing existing photocatalytic systems and approaching the performance of photothermal NH\n                    <jats:sub>3<\/jats:sub>\n                    decomposition processes. Combined characterization and theoretical analyses reveal that the Co\u2010SAEB is pivotal in establishing a direct Z\u2010scheme charge\u2010transfer pathway, which suppresses carrier recombination and enhances both redox capability and photocatalytic durability. This work advances the fundamental understanding of Z\u2010scheme electron transfer and provides a design strategy for highly active, stable and adaptable photocatalytic materials.\n                  <\/jats:p>","DOI":"10.1002\/smll.74549","type":"journal-article","created":{"date-parts":[[2026,7,9]],"date-time":"2026-07-09T20:42:31Z","timestamp":1783629751000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["N\u2013Co\u2013S Single\u2010Atom Electronic Bridge Enables a Z\u2010Scheme Heterojunction for Room\u2010Temperature Photocatalytic Hydrogen Production From Ammonia Decomposition"],"prefix":"10.1002","volume":"22","author":[{"given":"Ning","family":"Zhao","sequence":"first","affiliation":[{"name":"State Key Laboratory of Advanced Chemical Power Sources Haihe Laboratory of Sustainable Chemical Transformations College of Chemistry School of Medicine Nankai University  Tianjin 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