{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,11]],"date-time":"2026-10-11T12:27:27Z","timestamp":1791721647937,"version":"4.3.4"},"reference-count":55,"publisher":"Wiley","issue":"50","license":[{"start":{"date-parts":[[2026,7,19]],"date-time":"2026-07-19T00:00:00Z","timestamp":1784419200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2026,7,19]],"date-time":"2026-07-19T00:00:00Z","timestamp":1784419200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/100000001","name":"National Science Foundation","doi-asserted-by":"publisher","award":["2501275"],"award-info":[{"award-number":["2501275"]}],"id":[{"id":"10.13039\/100000001","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"published-print":{"date-parts":[[2026,9]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Aqueous zinc\u2010ion batteries (AZIBs) are promising alternatives to lithium\u2010ion systems for safe and low\u2010cost energy storage; however, their practical application is limited by poor cyclability, cathode degradation, and sluggish kinetics. Here, we introduce a magnetic\u2010field\u2010assisted electrodeposition strategy, termed magneto\u2010electrodeposition (MED), to fabricate MnO\n                    <jats:sub>2<\/jats:sub>\n                    cathodes. The applied magnetic field induces Lorentz\u2010force\u2010driven magnetohydrodynamics, enhancing Mn\n                    <jats:sup>2+<\/jats:sup>\n                    ion transport and enabling the formation of uniform and robust MnO\n                    <jats:sub>2<\/jats:sub>\n                    coatings with enhanced \u03b4\u2010MnO\n                    <jats:sub>2<\/jats:sub>\n                    character. Structural analyses confirm that, through the MED approach, MnO\n                    <jats:sub>2<\/jats:sub>\n                    depositions with higher Mn content (14.6%) and mass loading (26.6%) are obtained compared to conventional electrodeposited cathodes. Electrochemical characterization revealed improved charge\u2010transfer kinetics, with \u223c95% reduced interfacial resistance (R\n                    <jats:sub>ct<\/jats:sub>\n                    ). The optimized MED MnO\n                    <jats:sub>2<\/jats:sub>\n                    cathode delivered an initial areal capacity of 0.62\u00a0mAh\u00a0cm\n                    <jats:sup>\u2212<\/jats:sup>\n                    <jats:sup>2<\/jats:sup>\n                    , nearly twice the conventionally electrodeposited cathode, with 73% capacity retention after 100 cycles. Introducing an internal magnetic field during operation further enhances performance, with 10 mT being optimal for improving Zn\n                    <jats:sup>2<\/jats:sup>\n                    <jats:sup>+<\/jats:sup>\n                    transport. Consequently, the Zn\u2010MnO\n                    <jats:sub>2<\/jats:sub>\n                    cell employing the MED cathode delivers stable cycling for \u223c315 cycles, outperforming the conventionally electrodeposited cathode, which fails after \u223c130 cycles. This work demonstrates that coupling magneto\u2010electrodeposition with in\u2010operando magnetic\u2010field\u2010assistance provides a scalable strategy to engineer cathodes and regulate ion transport for high\u2010performance AZIBs.\n                  <\/jats:p>","DOI":"10.1002\/smll.74574","type":"journal-article","created":{"date-parts":[[2026,7,20]],"date-time":"2026-07-20T03:59:53Z","timestamp":1784519993000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Magneto\u2010Electrodeposition and Field\u2010Enhanced Ion Transport in Zn\u2010MnO\n                    <sub>2<\/sub>\n                    Batteries"],"prefix":"10.1002","volume":"22","author":[{"given":"Pedaballi","family":"Sireesha","sequence":"first","affiliation":[{"name":"Department of Chemistry Washington State University  Pullman Washington USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"William T.","family":"McLeod","sequence":"additional","affiliation":[{"name":"Department of Chemistry Washington State University  Pullman Washington USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kaylie A.","family":"McCracken","sequence":"additional","affiliation":[{"name":"Department of Chemistry Washington State University  Pullman Washington USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3470-1043","authenticated-orcid":false,"given":"Jeffrey G.","family":"Bell","sequence":"additional","affiliation":[{"name":"Department of Chemistry Washington State University  Pullman Washington USA"},{"name":"The Gene and Linda Voiland School of Chemical Engineering and Bioengineering Washington State University  Pullman Washington USA"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,7,19]]},"reference":[{"key":"e_1_2_9_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsaem.4c02016"},{"key":"e_1_2_9_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202403712"},{"key":"e_1_2_9_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2024.103689"},{"key":"e_1_2_9_5_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3CS00295K"},{"key":"e_1_2_9_6_1","doi-asserted-by":"publisher","DOI":"10.1002\/eem2.12265"},{"key":"e_1_2_9_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202301291"},{"key":"e_1_2_9_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.1c01389"},{"key":"e_1_2_9_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/admi.201900387"},{"key":"e_1_2_9_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202004862"},{"key":"e_1_2_9_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.202400890"},{"key":"e_1_2_9_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/pssc.201084200"},{"key":"e_1_2_9_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jallcom.2015.04.185"},{"key":"e_1_2_9_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202306652"},{"key":"e_1_2_9_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202403425"},{"key":"e_1_2_9_16_1","doi-asserted-by":"publisher","DOI":"10.1039\/D5TA02851E"},{"key":"e_1_2_9_17_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202500261"},{"key":"e_1_2_9_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2024.234816"},{"key":"e_1_2_9_19_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202312229"},{"key":"e_1_2_9_20_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2TA09165H"},{"key":"e_1_2_9_21_1","doi-asserted-by":"publisher","DOI":"10.20517\/energymater.2023.119"},{"key":"e_1_2_9_22_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jallcom.2024.173780"},{"key":"e_1_2_9_23_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.est.2024.112985"},{"key":"e_1_2_9_24_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4MA00065J"},{"key":"e_1_2_9_25_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.est.2024.113418"},{"key":"e_1_2_9_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.3c00018"},{"key":"e_1_2_9_27_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.matlet.2014.05.211"},{"key":"e_1_2_9_28_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10853\u2010011\u20106237\u20106"},{"key":"e_1_2_9_29_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.matlet.2024.135993"},{"key":"e_1_2_9_30_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202311933"},{"key":"e_1_2_9_31_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202318444"},{"key":"e_1_2_9_32_1","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.202401907"},{"key":"e_1_2_9_33_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.4c02559"},{"key":"e_1_2_9_34_1","doi-asserted-by":"publisher","DOI":"10.1002\/EXP.20210012"},{"key":"e_1_2_9_35_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apsusc.2008.04.044"},{"key":"e_1_2_9_36_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.heliyon.2024.e41427"},{"key":"e_1_2_9_37_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10008\u2010004\u20100500\u20106"},{"key":"e_1_2_9_38_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mtener.2021.100646"},{"key":"e_1_2_9_39_1","doi-asserted-by":"publisher","DOI":"10.1002\/celc.202300495"},{"key":"e_1_2_9_40_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.electacta.2006.03.013"},{"key":"e_1_2_9_41_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.compositesb.2023.110770"},{"key":"e_1_2_9_42_1","doi-asserted-by":"publisher","DOI":"10.1002\/celc.201901122"},{"key":"e_1_2_9_43_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jallcom.2020.154838"},{"key":"e_1_2_9_44_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2023.141900"},{"key":"e_1_2_9_45_1","doi-asserted-by":"publisher","DOI":"10.3390\/su152115419"},{"key":"e_1_2_9_46_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2018.04.004"},{"key":"e_1_2_9_47_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.electacta.2017.03.014"},{"key":"e_1_2_9_48_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.electacta.2019.03.008"},{"key":"e_1_2_9_49_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.electacta.2019.134867"},{"key":"e_1_2_9_50_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.9b04916"},{"key":"e_1_2_9_51_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0167\u20102738(02)00258\u20108"},{"key":"e_1_2_9_52_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.201901649"},{"key":"e_1_2_9_53_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0378\u20107753(02)00595\u20105"},{"key":"e_1_2_9_54_1","doi-asserted-by":"publisher","DOI":"10.1149\/1.1357699"},{"key":"e_1_2_9_55_1","doi-asserted-by":"publisher","DOI":"10.1149\/1945\u20107111\/ad3582"},{"key":"e_1_2_9_56_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.5c08241"}],"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