{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,7]],"date-time":"2026-09-07T13:10:15Z","timestamp":1788786615338,"version":"build-2803163510"},"reference-count":51,"publisher":"Wiley","issue":"50","license":[{"start":{"date-parts":[[2026,7,11]],"date-time":"2026-07-11T00:00:00Z","timestamp":1783728000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,7,11]],"date-time":"2026-07-11T00:00:00Z","timestamp":1783728000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22275139"],"award-info":[{"award-number":["22275139"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["92572201"],"award-info":[{"award-number":["92572201"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"published-print":{"date-parts":[[2026,9]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    The full utilization of both photocatalytic reduction and oxidation reactions is highly attractive for atom\u2010economic and sustainable chemical synthesis. However, coupling CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction with oxidation of liquid organics is challenging, as their disparate physicochemical properties lead to mismatched adsorption, diffusion, and activation at a common interface. Effective integration requires precise molecular recognition to selectively bind each substrate molecule and tailored spatial confinement to bring them into reactive proximity. Herein, we engineered dual functionality by assembling a cyclodextrin metal\u2013organic framework (CD\u2010MOF) onto ZnCdS nanoparticles. The \u03b3\u2010CD cavities exhibit molecular recognition of benzyl alcohol via host\u2013guest interactions, while the porous framework has spatial confinement effects and accumulates CO\n                    <jats:sub>2<\/jats:sub>\n                    molecules. This well\u2010defined microenvironment with an interfacial dipole field enhances charge separation, accelerates interfacial electron transfer, and drives efficient tandem photoreactions. Under visible light illumination, CO has been produced at a rate of 1195.1 \u00b5mol\u00b7g\n                    <jats:sup>\u2212<\/jats:sup>\n                    <jats:sup>1<\/jats:sup>\n                    \u00b7h\n                    <jats:sup>\u2212<\/jats:sup>\n                    <jats:sup>1<\/jats:sup>\n                    (14.5\u2010folds higher than pristine ZnCdS). Meanwhile, benzyl alcohol is oxidized to benzaldehyde with nearly 100% selectivity, rivaling state\u2010of\u2010the\u2010art performance among non\u2010precious metal systems. This work establishes a supramolecular paradigm of programmable host\u2013guest microenvironments to orchestrate photoredox transformations.\n                  <\/jats:p>","DOI":"10.1002\/smll.74581","type":"journal-article","created":{"date-parts":[[2026,7,11]],"date-time":"2026-07-11T11:24:03Z","timestamp":1783769043000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Molecular Recognition and Spatial Confinement in CD\u2010MOF Drive Tandem Photocatalytic CO\n                    <sub>2<\/sub>\n                    Reduction and Alcohol Oxidation"],"prefix":"10.1002","volume":"22","author":[{"given":"Xiansong","family":"Guo","sequence":"first","affiliation":[{"name":"State Key Laboratory of Crystal Materials Tianjin Key Laboratory of Organic Solar Cells and Photochemical Conversion School of Chemistry and Chemical Engineering Institute of New Energy Materials and Low\u2010Carbon Technologies Tianjin University of Technology  Tianjin China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6105-3286","authenticated-orcid":false,"given":"Wen","family":"Zhang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Crystal Materials Tianjin Key Laboratory of Organic Solar Cells and Photochemical Conversion School of Chemistry and Chemical Engineering Institute of New Energy Materials and Low\u2010Carbon Technologies Tianjin University of Technology  Tianjin China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yixin","family":"Song","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Crystal Materials Tianjin Key Laboratory of Organic Solar Cells and Photochemical Conversion School of Chemistry and Chemical Engineering Institute of New Energy Materials and Low\u2010Carbon Technologies Tianjin University of Technology  Tianjin 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