{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,11,2]],"date-time":"2026-11-02T01:28:26Z","timestamp":1793582906052,"version":"4.5.0"},"reference-count":50,"publisher":"Wiley","issue":"51","license":[{"start":{"date-parts":[[2026,7,25]],"date-time":"2026-07-25T00:00:00Z","timestamp":1784937600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,7,25]],"date-time":"2026-07-25T00:00:00Z","timestamp":1784937600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["2020YFC1807902"],"award-info":[{"award-number":["2020YFC1807902"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"published-print":{"date-parts":[[2026,9]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Catalytic ozonation technology occupies a pivotal position in the treatment of chlorinated volatile organic compounds (Cl\u2010VOCs) owing to its mild reaction conditions and exceptional efficiency. However, the efficacy of catalytic ozonation remains governed by the electronic properties and interfacial interactions of the catalyst. It constitutes a formidable challenge to improve chlorine poisoning resistance while preserving efficient electron transfer. In this study, cobalt (Co) was introduced into the MnFeO framework via in situ engineering to yield a MnFeO\u2010Co\n                    <jats:sub>0.02<\/jats:sub>\n                    (F) catalyst with Co\u2013O\u2013Mn\/Fe. Through catalytic ozonation, the catalyst maintained 100% 1,2\u2010DCE conversion and over 95% mineralization within 50\u00a0h, outperforming reported catalysts. Mechanistic studies showed that Co\u2013O\u2013Mn\/Fe modulated the local electronic environment, inducing differentiated shifts in the d\u2010 and p\u2010band centers and forming an interfacial electron bridge between the Mn\u2010rich shell and Fe\u2010rich core. This accelerated electron transfer reduced the energy barrier of the rate\u2010determining step in O\n                    <jats:sub>3<\/jats:sub>\n                    activation and promoted reactive oxygen species generation. Additionally, the Co\u2013O\u2013Mn\/Fe stabilized the catalyst surface, facilitated chlorine species migration, and suppressed metal chloride formation, thereby enhancing chlorine resistance. This work provides insights into designing high\u2010performance catalysts with efficient O\n                    <jats:sub>3<\/jats:sub>\n                    activation and durability, promoting practical catalytic ozonation of Cl\u2010VOCs.\n                  <\/jats:p>","DOI":"10.1002\/smll.74589","type":"journal-article","created":{"date-parts":[[2026,7,26]],"date-time":"2026-07-26T03:52:44Z","timestamp":1785037964000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Electron Bridge Effect Induced by Oxygen\u2010Bridged Co on MnFe Core\u2010Shell Sphere for Boosting Catalytic Ozonation of 1,2\u2010Dichloroethane"],"prefix":"10.1002","volume":"22","author":[{"given":"Qi","family":"Jiang","sequence":"first","affiliation":[{"name":"Department of Environmental Science and Engineering Beijing University of Chemical Technology  Beijing People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shaobo","family":"Chen","sequence":"additional","affiliation":[{"name":"Department of Environmental Science and Engineering Beijing University of Chemical Technology  Beijing People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Linjin","family":"Li","sequence":"additional","affiliation":[{"name":"Faculty of Environmental Science and Engineering Kunming University of Science and Technology  Kunming Yunnan People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiayin","family":"Liu","sequence":"additional","affiliation":[{"name":"Department of Environmental Science and Engineering Beijing University of Chemical Technology  Beijing People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Menghao","family":"Fang","sequence":"additional","affiliation":[{"name":"Department of Environmental Science and Engineering Beijing University of Chemical Technology  Beijing People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiaben","family":"Yin","sequence":"additional","affiliation":[{"name":"Department of Environmental Science and Engineering Beijing University of Chemical Technology  Beijing People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tian","family":"Gao","sequence":"additional","affiliation":[{"name":"Department of Environmental Science and Engineering Beijing University of Chemical Technology  Beijing People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhongjun","family":"Xu","sequence":"additional","affiliation":[{"name":"Department of Environmental Science and Engineering Beijing University of Chemical Technology  Beijing People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,7,25]]},"reference":[{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.3390\/pr9010119"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0RA10037D"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mcat.2024.113959"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/jctb.6308"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jhazmat.2021.126847"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.2134\/jeq2004.6100"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2RA05828F"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.seppur.2023.123255"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1007\/s40820\u2010024\u201001528\u20109"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.26599\/NR.2025.94907016"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202500137"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202114696"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.5c02654"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.seppur.2025.135065"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2021.130814"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.seppur.2022.121191"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jece.2023.109299"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jhazmat.2020.122218"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2020.126534"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2025.125905"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.est.2c03811"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.3390\/nano13040775"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2020.125172"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.est.0c05235"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c02483"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201910879"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202504869"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1002\/cjce.23784"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202318924"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.est.0c02680"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202507109"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1007\/s00339\u2010025\u201008894\u20100"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.5c04450"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202513526"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.surfin.2023.102750"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202514600"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202313209"},{"key":"e_1_2_7_39_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202311879"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010021\u201024424\u2010x"},{"key":"e_1_2_7_41_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcata.2024.119575"},{"key":"e_1_2_7_42_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.proci.2022.10.021"},{"key":"e_1_2_7_43_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.4c04906"},{"key":"e_1_2_7_44_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2021.11.011"},{"key":"e_1_2_7_45_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202402883"},{"key":"e_1_2_7_46_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcata.2024.119784"},{"key":"e_1_2_7_47_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.psep.2023.01.015"},{"key":"e_1_2_7_48_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2SC05596A"},{"key":"e_1_2_7_49_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5CY00044K"},{"key":"e_1_2_7_50_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2022.135501"},{"key":"e_1_2_7_51_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2019.118493"}],"container-title":["Small"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/smll.74589","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/smll.74589","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/smll.74589","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,11,2]],"date-time":"2026-11-02T01:12:26Z","timestamp":1793581946000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/smll.74589"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,7,25]]},"references-count":50,"journal-issue":{"issue":"51","published-print":{"date-parts":[[2026,9]]}},"alternative-id":["10.1002\/smll.74589"],"URL":"https:\/\/doi.org\/10.1002\/smll.74589","archive":["Portico"],"relation":{},"ISSN":["1613-6810","1613-6829"],"issn-type":[{"value":"1613-6810","type":"print"},{"value":"1613-6829","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,7,25]]},"assertion":[{"value":"2026-03-25","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-06-30","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-07-25","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e74589"}}