{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,7]],"date-time":"2026-09-07T13:10:15Z","timestamp":1788786615330,"version":"build-2803163510"},"reference-count":41,"publisher":"Wiley","issue":"50","license":[{"start":{"date-parts":[[2026,8,8]],"date-time":"2026-08-08T00:00:00Z","timestamp":1786147200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,8,8]],"date-time":"2026-08-08T00:00:00Z","timestamp":1786147200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22306075"],"award-info":[{"award-number":["22306075"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22578181"],"award-info":[{"award-number":["22578181"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100021171","name":"Basic and Applied Basic Research Foundation of Guangdong Province","doi-asserted-by":"publisher","award":["2025A1515010203"],"award-info":[{"award-number":["2025A1515010203"]}],"id":[{"id":"10.13039\/501100021171","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"published-print":{"date-parts":[[2026,9]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    The application of single\u2010atom catalysts (SACs) based on partially filled 3d orbital metals (e.g., Fe, Co, Cu) in Fenton\u2010like systems faces a fundamental activity\u2010stability trade\u2010off caused by metal leaching and irreversible deactivation during redox cycles. Here we report a coordination\u2010symmetry\u2010breaking strategy that activates inert zinc single atoms via atomic coordination distortion and nanofluidic confinement. Asymmetric Zn\u2010N\n                    <jats:sub>x<\/jats:sub>\n                    sites integrated within carbon nitride nanochannels form a membrane reactor that couples molecular sieving with oxidation catalysis. The synergy between asymmetric coordination and nanoconfinement creates an efficient electron pathway, enabling direct electron transfer from pollutants to peracetic acid (PAA) through metastable complexes, circumventing radical pathways. This coordination asymmetry induces localized charge polarization, lowering the activation barrier for PAA and resulting in exceptional kinetics (0.09 ms\n                    <jats:sup>\u22121<\/jats:sup>\n                    ) under nanoconfinement, negligible Zn leaching (&lt;0.1\u00a0ppm), and strong resilience in complex water conditions. The system achieves industry\u2010leading cost efficiency (0.11 USD\/m\n                    <jats:sup>3<\/jats:sup>\n                    ) over 100\u00a0h operation, outperforming conventional Co SAC. This work establishes a universal design principle integrating atomic symmetry control with nanofluidics to transform inert metals into highly efficient and stable catalytic membranes for sustainable water purification.\n                  <\/jats:p>","DOI":"10.1002\/smll.74615","type":"journal-article","created":{"date-parts":[[2026,8,8]],"date-time":"2026-08-08T07:56:34Z","timestamp":1786175794000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Breaking Coordination Symmetry of Zinc Single Atoms Under Nanoconfinement Enables Ultrafast Electron Transfer in Non\u2010Radical Oxidation"],"prefix":"10.1002","volume":"22","author":[{"given":"Jian","family":"Ye","sequence":"first","affiliation":[{"name":"School of Chemistry and Chemical Engineering Jiangsu University  Zhenjiang China"},{"name":"Applied Research Centre for Pearl River Delta Environment Institute of Advanced Materials Department of Biology Hong Kong Baptist University  Kowloon Tong Hong Kong SAR China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chenxiao","family":"Yu","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Jiangsu University  Zhenjiang China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mingyang","family":"Ren","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Jiangsu University  Zhenjiang China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qiaoyu","family":"Gao","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Jiangsu University  Zhenjiang China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuehan","family":"Jiang","sequence":"additional","affiliation":[{"name":"Applied Research Centre for Pearl River Delta Environment Institute of Advanced Materials Department of Biology Hong Kong Baptist University  Kowloon Tong Hong Kong SAR China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaohui","family":"Dai","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Jiangsu University  Zhenjiang China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiangdong","family":"Dai","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Jiangsu University  Zhenjiang China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaohua","family":"Tian","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Jiangsu University  Zhenjiang China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jianming","family":"Pan","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Jiangsu University  Zhenjiang China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wenhua","family":"Xue","sequence":"additional","affiliation":[{"name":"Applied Research Centre for Pearl River Delta Environment Institute of Advanced Materials Department of Biology Hong Kong Baptist University  Kowloon Tong Hong Kong SAR China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9785-3215","authenticated-orcid":false,"given":"Sai Kishore","family":"Ravi","sequence":"additional","affiliation":[{"name":"School of Energy and Environment City University of Hong Kong  Hong Kong SAR China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3599-0318","authenticated-orcid":false,"given":"Jun","family":"Zhao","sequence":"additional","affiliation":[{"name":"Applied Research Centre for Pearl River Delta Environment Institute of Advanced Materials Department of Biology Hong Kong Baptist University  Kowloon Tong Hong Kong SAR China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,8,8]]},"reference":[{"key":"e_1_2_9_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010023\u201038677\u20101"},{"key":"e_1_2_9_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202202891"},{"key":"e_1_2_9_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.watres.2022.119462"},{"key":"e_1_2_9_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.est.9b02991"},{"key":"e_1_2_9_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.watres.2024.121621"},{"key":"e_1_2_9_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.est.2c01261"},{"key":"e_1_2_9_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.est.1c05980"},{"key":"e_1_2_9_9_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929\u2010023\u201001047\u20107"},{"key":"e_1_2_9_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202009991"},{"key":"e_1_2_9_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202304088"},{"key":"e_1_2_9_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202202338"},{"key":"e_1_2_9_13_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010022\u201031807\u20101"},{"key":"e_1_2_9_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.est.4c07566"},{"key":"e_1_2_9_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202514600"},{"key":"e_1_2_9_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202307151"},{"key":"e_1_2_9_17_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202211575"},{"key":"e_1_2_9_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202403964"},{"key":"e_1_2_9_19_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202527790"},{"key":"e_1_2_9_20_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.checat.2022.01.003"},{"key":"e_1_2_9_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202103977"},{"key":"e_1_2_9_22_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.checat.2022.02.006"},{"key":"e_1_2_9_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202405847"},{"key":"e_1_2_9_24_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202107550"},{"key":"e_1_2_9_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.4c02830"},{"key":"e_1_2_9_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202203001"},{"key":"e_1_2_9_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202311416"},{"key":"e_1_2_9_28_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.76027"},{"key":"e_1_2_9_29_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.watres.2021.118004"},{"key":"e_1_2_9_30_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.desal.2024.118171"},{"key":"e_1_2_9_31_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2025.125207"},{"key":"e_1_2_9_32_1","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.2220608120"},{"key":"e_1_2_9_33_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2024.154034"},{"key":"e_1_2_9_34_1","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.2219923120"},{"key":"e_1_2_9_35_1","doi-asserted-by":"publisher","DOI":"10.1038\/s44221\u2010024\u201000382\u20108"},{"key":"e_1_2_9_36_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.est.1c05374"},{"key":"e_1_2_9_37_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.est.2c02636"},{"key":"e_1_2_9_38_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.est.1c02042"},{"key":"e_1_2_9_39_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.9b01565"},{"key":"e_1_2_9_40_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.est.2c01759"},{"key":"e_1_2_9_41_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202401454"},{"key":"e_1_2_9_42_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201057560\u20109"}],"container-title":["Small"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/smll.74615","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/smll.74615","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/smll.74615","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,9,7]],"date-time":"2026-09-07T12:40:58Z","timestamp":1788784858000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/smll.74615"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,8,8]]},"references-count":41,"journal-issue":{"issue":"50","published-print":{"date-parts":[[2026,9]]}},"alternative-id":["10.1002\/smll.74615"],"URL":"https:\/\/doi.org\/10.1002\/smll.74615","archive":["Portico"],"relation":{},"ISSN":["1613-6810","1613-6829"],"issn-type":[{"value":"1613-6810","type":"print"},{"value":"1613-6829","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,8,8]]},"assertion":[{"value":"2026-04-14","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-06-26","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-08-08","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e74615"}}