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As a consequence, experimental development and theoretical understanding of phosphosulfides have focused on individual compounds rather than on accelerated broad\u2010range exploration. In this work, we first evaluate the synthesizability and band gaps of 909 hypothetical ternary phosphosulfides by density functional theory. We find 19 previously unknown thermodynamically stable compounds, including the first Si\u2010 and Ge\u2010based phosphosulfides. For rapid band gap prediction, we then develop a multi\u2010fidelity machine learning model to translate semilocal density functional theory band gaps into experimentally calibrated band gaps. Importantly, we extend the accelerated material development workflow to the experimental domain by demonstrating a route to high\u2010throughput synthesis and characterization of virtually any phosphosulfide material system. The method is based on thin\u2010film combinatorial libraries and yields over 100 unique compositions in each experiment, enabling us to synthesize four distinct phosphosulfide compounds in only four combinatorial experiments without prior synthesis recipes and without compromising on material quality. Thus, we argue that accelerated materials development workflows combining theory, artificial intelligence, synthesis, and characterization can be viable even for experimentally challenging inorganic materials.<\/jats:p>","DOI":"10.1002\/smll.74742","type":"journal-article","created":{"date-parts":[[2026,8,3]],"date-time":"2026-08-03T05:11:53Z","timestamp":1785733913000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Machine\u2010Learning\u2010Assisted Discovery and Accelerated Synthesis of Metal Phosphosulfides"],"prefix":"10.1002","volume":"22","author":[{"given":"Javier","family":"Sanz Rodrigo","sequence":"first","affiliation":[{"name":"National Centre for Nano Fabrication and Characterization (DTU Nanolab) Technical University of Denmark Kongens Lyngby Denmark"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nicholas A.","family":"Kryger\u2010Nelson","sequence":"additional","affiliation":[{"name":"National Centre for Nano Fabrication and Characterization (DTU Nanolab) Technical University of Denmark Kongens Lyngby Denmark"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lena A.","family":"Mittmann","sequence":"additional","affiliation":[{"name":"National Centre for Nano Fabrication and Characterization (DTU Nanolab) Technical University of Denmark Kongens Lyngby Denmark"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Eug\u00e8ne","family":"Bertin","sequence":"additional","affiliation":[{"name":"National Centre for Nano Fabrication and Characterization (DTU Nanolab) Technical University of Denmark Kongens Lyngby Denmark"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5880-5045","authenticated-orcid":false,"given":"Ivano E.","family":"Castelli","sequence":"additional","affiliation":[{"name":"Department of Energy Conversion and Storage Technical University of Denmark Kongens Lyngby Denmark"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1499-8740","authenticated-orcid":false,"given":"Andrea","family":"Crovetto","sequence":"additional","affiliation":[{"name":"National Centre for Nano Fabrication and Characterization (DTU Nanolab) Technical University of Denmark Kongens Lyngby Denmark"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,8,2]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201408222"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/nl5028843"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1088\/2515-7639\/ad3aa3"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202513255"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-021-26200-3"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586-020-2520-5"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsphotonics.2c00131"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202503047"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202307237"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2025.216524"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.0c17818"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1107\/S0021889811038970"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41563-022-01291-5"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1016\/0165-1633(82)90085-5"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c04868"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1088\/1361-6463\/ac1538"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1524\/ncrs.2009.0164"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202100499"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.1600225"},{"key":"e_1_2_8_21_1","unstructured":"F.Tadge J. 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