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As promising materials for the RWGS reaction, Mo\u2010based catalysts feature accessible raw materials and high activity. However, developing catalysts combining high activity, complete selectivity, and long\u2010term stability poses major challenges. In this context, we provide a comprehensive and critical analysis of recent advances in Mo\u2010based catalysts for the RWGS reaction. This review emphasizes the structure\u2010performance relationships in various Mo\u2010based catalysts, including promotional effects, metal\u2010support interactions, and vacancy engineering that enable enhanced CO\n                    <jats:sub>2<\/jats:sub>\n                    conversion, product selectivity, and long\u2010term durability. We also address the ongoing debate surrounding the nature of active sites and elucidate their dynamic evolution, offering forward\u2010looking perspectives on the rational design of improved Mo\u2010based catalysts. Furthermore, we outline the fundamental reaction mechanisms, with emphasis on the role of advanced in situ\/operando characterization techniques. By critically evaluating current challenges and future opportunities, this work aims to inspire innovations in RWGS technology and support the transition toward sustainable CO\n                    <jats:sub>2<\/jats:sub>\n                    utilization for the production of synthetic chemicals and fuels.\n                  <\/jats:p>","DOI":"10.1002\/smll.74749","type":"journal-article","created":{"date-parts":[[2026,8,5]],"date-time":"2026-08-05T09:26:33Z","timestamp":1785921993000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Recent Advances in Molybdenum\u2010Based Catalysts for the Reverse Water\u2010Gas Shift Reaction"],"prefix":"10.1002","volume":"22","author":[{"given":"Mengqi","family":"Hu","sequence":"first","affiliation":[{"name":"Interdisciplinary Institute of NMR and Molecular Sciences Key Laboratory of Hubei Province for Coal Conversion and New Carbon Materials School of Chemistry and Chemical Engineering Wuhan University of Science and Technology  Wuhan P. 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