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Herein, we report a Pt\u2013SnO\n                    <jats:sub>x<\/jats:sub>\n                    nanocluster (NC) system featuring weak Pt\/SnO\n                    <jats:sub>x<\/jats:sub>\n                    interfacial interaction, which enables SnO\n                    <jats:sub>x<\/jats:sub>\n                    to effectively modulate the reaction pathway without compromising the intrinsic Pt catalytic properties. Notably, characterization results reveal negligible charge transfer at the interface. The Pt\u2013SnO\n                    <jats:sub>x<\/jats:sub>\n                    NCs exhibit an overpotential of 22\u00a0mV at 10\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    and a Tafel slope of 24\u00a0mV dec\n                    <jats:sup>\u22121<\/jats:sup>\n                    , outperforming Pt NCs, Pt nanoparticles, and Pt\u2013SnO\n                    <jats:sub>2<\/jats:sub>\n                    structures with strong interfacial interactions. Theoretical calculations suggest that the Pt\u2013SnO\n                    <jats:sub>x<\/jats:sub>\n                    architecture facilitates hydrogen spillover, which may promote a shift in the dominant hydrogen evolution reaction (HER) mechanism from Volmer\u2013Heyrovsky to a more efficient Volmer\u2013Tafel route. As the cathode in an ethanol\u2010assisted proton exchange membrane paired\u2010electrolyzer, the Pt\u2013SnO\n                    <jats:sub>x<\/jats:sub>\n                    NC catalyst delivers 1.0 A cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    at below 1.5\u00a0V under 80\u00b0C with stable operation over 70\u00a0h.\n                  <\/jats:p>","DOI":"10.1002\/smll.74788","type":"journal-article","created":{"date-parts":[[2026,7,21]],"date-time":"2026-07-21T10:57:13Z","timestamp":1784631433000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Pt\u2010SnO\n                    <sub>x<\/sub>\n                    Clusters With Weak Interfacial Interaction Boost Hydrogen Evolution"],"prefix":"10.1002","volume":"22","author":[{"given":"Zhen","family":"Jiang","sequence":"first","affiliation":[{"name":"Key Laboratory for Advanced Materials and Feringa Nobel Prize Scientist Joint Research Center School of Chemistry &amp; Molecular Engineering East China University of Science and Technology  Shanghai People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tzu\u2010Hsi","family":"Huang","sequence":"additional","affiliation":[{"name":"Key Laboratory for Advanced Materials and Feringa Nobel Prize Scientist Joint Research Center School of Chemistry &amp; Molecular Engineering East China University of Science and Technology  Shanghai People's Republic of China"},{"name":"Institute of Materials Science and Engineering National Central University  Taoyuan Taiwan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fang\u2010Yu","family":"Chang","sequence":"additional","affiliation":[{"name":"Institute of Materials Science and Engineering National Central University  Taoyuan 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