{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,25]],"date-time":"2026-09-25T14:06:04Z","timestamp":1790345164972,"version":"4.1.0"},"reference-count":55,"publisher":"Wiley","issue":"54","license":[{"start":{"date-parts":[[2026,8,5]],"date-time":"2026-08-05T00:00:00Z","timestamp":1785888000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,8,5]],"date-time":"2026-08-05T00:00:00Z","timestamp":1785888000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/100000001","name":"National Science Foundation","doi-asserted-by":"publisher","award":["2502179"],"award-info":[{"award-number":["2502179"]}],"id":[{"id":"10.13039\/100000001","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100016180","name":"Stevens Institute of Technology","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100016180","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"published-print":{"date-parts":[[2026,9]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>Creating ordered plasmonic nanoparticle lattices on soft, curved templates remains challenging due to curvature\u2011induced frustration and kinetic trapping at fluid interfaces. Here we report a chemically programmable route to organize 5\u2011nm gold nanoparticles (AuNPs) into hexagonally ordered surface \u201cpatches\u201d on crosslinked liquid\u2010crystalline polymer nanoparticles (LCNPs) synthesized via miniemulsion polymerization. We find that, contrary to expectations from elastic templating alone, AuNPs remain predominantly surface\u2011dispersed in the absence of proper co\u2010stabilizer. By tuning the identity and concentration of hydrophobic co\u2011stabilizers, we induce a controlled transition from surface\u2010dispersed distributions to monolayer patches with local hexagonal packing and tunable interparticle gaps. Quantitative gap statistics and Voronoi topology (via Delaunay analysis) show that thiol co\u2011stabilization yields the most uniform nearest\u2011neighbor separations and the highest degree of hexagonal coordination, whereas non\u2011thiol analogs produce broader gap distributions and increased disorder. These structurally distinct states directly correlate with optical response: as the mean inter\u2010AuNP gap decreases, the ensemble localized surface plasmon resonance (LSPR) peaks at longer wavelengths with stronger intensity, which is consistent with coupling signatures and near\u2011field hybridization confirmed in the full\u2010wave electrodynamic simulations. This work provides a general chemical handle for programming plasmonic lattices on curved soft templates.<\/jats:p>","DOI":"10.1002\/smll.74823","type":"journal-article","created":{"date-parts":[[2026,8,5]],"date-time":"2026-08-05T09:10:28Z","timestamp":1785921028000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Chemically Controlled Order and Geometries of Plasmonic Patches at Soft Curved Interfaces"],"prefix":"10.1002","volume":"22","author":[{"given":"Jingru","family":"Chen","sequence":"first","affiliation":[{"name":"Department of Chemistry and Chemical Biology Stevens Institute of Technology  Hoboken New Jersey USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiehao","family":"Zheng","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Chemical Biology Stevens Institute of Technology  Hoboken New Jersey 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