{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,1]],"date-time":"2026-10-01T19:59:47Z","timestamp":1790884787643,"version":"4.1.0"},"reference-count":44,"publisher":"Wiley","issue":"55","license":[{"start":{"date-parts":[[2026,8,2]],"date-time":"2026-08-02T00:00:00Z","timestamp":1785628800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,8,2]],"date-time":"2026-08-02T00:00:00Z","timestamp":1785628800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["62404251"],"award-info":[{"award-number":["62404251"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["12574216"],"award-info":[{"award-number":["12574216"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["62341406"],"award-info":[{"award-number":["62341406"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100002858","name":"China Postdoctoral Science Foundation","doi-asserted-by":"publisher","award":["2024M753515"],"award-info":[{"award-number":["2024M753515"]}],"id":[{"id":"10.13039\/501100002858","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"published-print":{"date-parts":[[2026,10]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    The development of rechargeable magnesium batteries (RMBs) is largely constrained by severe interfacial passivation of Mg anodes and sluggish Mg\n                    <jats:sup>2+<\/jats:sup>\n                    transport kinetics. Here, slightly soluble Cu(I)\u2010halide (CuX, X = Cl, Br, I) reservoirs were introduced into the classic magnesium\u2010aluminum chloride complex (MACC) electrolytes, where the continuous Cu\n                    <jats:sup>+<\/jats:sup>\n                    release via dissolution equilibrium drives spontaneous Mg\/Cu displacement alloying throughout cycling. The resulting dynamically reconstructed interface ensures the persistent exposure of magnesiophilic sites, enabling ultralow Mg deposition\/stripping overpotentials (&lt;0.15\u00a0V) at 0.2\u00a0mA cm\n                    <jats:sup>\u2212<\/jats:sup>\n                    <jats:sup>2<\/jats:sup>\n                    (1\u00a0mA h cm\n                    <jats:sup>\u2212<\/jats:sup>\n                    <jats:sup>2<\/jats:sup>\n                    ) over 800 h in Mg||Mg symmetric cells. Electric field simulations further reveal that the in situ formed alloy interphase homogenizes the local electric\u2010field distribution and regulates Mg\n                    <jats:sup>2+<\/jats:sup>\n                    flux, thereby facilitating rapid and uniform Mg electrodeposition. In contrast, on inert electrodes that cannot undergo displacement alloying, Cu\n                    <jats:sup>+<\/jats:sup>\n                    is preferentially reduced to metallic Cu, which further promotes Mg deposition. Consequently, Mg||Cu, Mg||SS, and Mg||Mo asymmetric cells using CuX\u2010modified MACC exhibit greatly improved cycling stability compared with cells employing unmodified MACC. These findings establish a new paradigm for understanding and engineering multi\u2010metallic interfacial chemistries to precisely regulate deposition behavior in multivalent metal batteries.\n                  <\/jats:p>","DOI":"10.1002\/smll.74937","type":"journal-article","created":{"date-parts":[[2026,8,3]],"date-time":"2026-08-03T10:00:35Z","timestamp":1785751235000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Halide\u2010Cu\n                    <sup>+<\/sup>\n                    \u2010Mediated Dynamic Interfacial Reconstruction in Magnesium\u2010Aluminum Chloride Complex Electrolyte Triggers Divergent Mg Deposition Behaviors on Active and Inert Electrodes"],"prefix":"10.1002","volume":"22","author":[{"ORCID":"https:\/\/orcid.org\/0009-0003-5824-4788","authenticated-orcid":false,"given":"Yuanxiang","family":"Zhang","sequence":"first","affiliation":[{"name":"School of Materials Science and Physics China University of Mining and Technology  Xuzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tianlong","family":"Huang","sequence":"additional","affiliation":[{"name":"School of Materials Science and Physics China University of Mining and Technology  Xuzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mengting","family":"Yuan","sequence":"additional","affiliation":[{"name":"School of Materials Science and Physics China University of Mining and Technology  Xuzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Maosheng","family":"Cui","sequence":"additional","affiliation":[{"name":"School of Materials Science and Physics China University of Mining and Technology  Xuzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhen","family":"Mu","sequence":"additional","affiliation":[{"name":"School of Materials Science and Physics China University of Mining and Technology  Xuzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaoyong","family":"Teng","sequence":"additional","affiliation":[{"name":"School of Materials Science and Physics China University of Mining and Technology  Xuzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lingxiu","family":"Chen","sequence":"additional","affiliation":[{"name":"School of Materials Science and Physics China University of Mining and Technology  Xuzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yang","family":"Zhang","sequence":"additional","affiliation":[{"name":"School of Materials Science and Physics China University of Mining and Technology  Xuzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0004-4233-5201","authenticated-orcid":false,"given":"Xiaolan","family":"Xue","sequence":"additional","affiliation":[{"name":"School of Materials Science and Physics China University of Mining and Technology  Xuzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,8,2]]},"reference":[{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3ee40871j"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1038\/35037553"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1039\/D5EE01011J"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202514410"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202510488"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202202602"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2EE03235J"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms1435"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1149\/2.0161513jes"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202301795"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202417450"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1039\/C3CC47896C"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201812824"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202301934"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202500979"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.1c01243"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2023.103087"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2018.05.023"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202516803"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.5c01758"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202500135"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202510737"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202519527"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcis.2025.138508"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202205187"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.esci.2023.100203"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/am508702j"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.electacta.2020.135614"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2021.11.011"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.xcrp.2020.100265"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202100650"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202408296"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c04820"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202318204"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010020\u201020769\u2010x"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010023\u201042549\u2010z"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp076981k"},{"key":"e_1_2_7_39_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202503209"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2025.104652"},{"key":"e_1_2_7_41_1","doi-asserted-by":"publisher","DOI":"10.1038\/nnano.2017.16"},{"key":"e_1_2_7_42_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.7b00115"},{"key":"e_1_2_7_43_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.9b02306"},{"key":"e_1_2_7_44_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201804000"},{"key":"e_1_2_7_45_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.1c00677"}],"container-title":["Small"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/smll.74937","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/smll.74937","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/smll.74937","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,10,1]],"date-time":"2026-10-01T19:45:28Z","timestamp":1790883928000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/smll.74937"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,8,2]]},"references-count":44,"journal-issue":{"issue":"55","published-print":{"date-parts":[[2026,10]]}},"alternative-id":["10.1002\/smll.74937"],"URL":"https:\/\/doi.org\/10.1002\/smll.74937","archive":["Portico"],"relation":{},"ISSN":["1613-6810","1613-6829"],"issn-type":[{"value":"1613-6810","type":"print"},{"value":"1613-6829","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,8,2]]},"assertion":[{"value":"2026-02-25","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-07-17","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-08-02","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e74937"}}