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While artificial solid electrolyte interfaces mitigate these issues, their fabrication is complex and time\u2010consuming. In this study, an ultrafast chemical solution reaction and selective etching are designed to in situ exfoliate a highly durable (002) plane\u2010exposed GA@Zn layer across the non\u2010uniform topography of the primary zinc substrate, effectively addressing these problems. Theoretical calculations combined with the experimental characterization show that a specific (002)\u2010dominant GA@Zn layer, as a multifunctional structure, mitigates the electrodeposition \u201ctip effect\u201d and suppresses dendrite formation. Moreover, the surface polarization field regulates interfacial electric field distribution, guiding uniform Zn\n                    <jats:sup>2+<\/jats:sup>\n                    diffusion and deposition, while preventing water\u2010Zn direct contact, increasing hydrogen evolution overpotential, and eliminating side reactions. Consequently, the 4%GA@Zn symmetric cell maintains stable cycling for more than 4200\u00a0h at 2\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    , and the Zn\u01c1\u03c3\u2010MnO\n                    <jats:sub>2<\/jats:sub>\n                    full battery keeps an 80% capacity retention rate after 1000 cycles at 1 A g\n                    <jats:sup>\u22121<\/jats:sup>\n                    . The present investigation offers a straightforward method for developing high\u2010stability Zn anodes for advanced AZIBs.\n                  <\/jats:p>","DOI":"10.1002\/smll.74956","type":"journal-article","created":{"date-parts":[[2026,8,13]],"date-time":"2026-08-13T08:38:06Z","timestamp":1786610286000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Glutaric Acid\u2010Mediated Selective Etching: Constructing (002)\u2010Dominant and Passivation\u2010Free Zn Anodes for Ultra\u2010Stable Aqueous Zinc\u2010Ion Batteries"],"prefix":"10.1002","volume":"22","author":[{"ORCID":"https:\/\/orcid.org\/0009-0003-6686-2121","authenticated-orcid":false,"given":"Yena","family":"Jiang","sequence":"first","affiliation":[{"name":"School of Chemistry South China Normal University  Guangzhou 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