{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,13]],"date-time":"2026-10-13T10:45:06Z","timestamp":1791888306978,"version":"4.3.4"},"reference-count":52,"publisher":"Wiley","issue":"57","license":[{"start":{"date-parts":[[2026,8,7]],"date-time":"2026-08-07T00:00:00Z","timestamp":1786060800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,8,7]],"date-time":"2026-08-07T00:00:00Z","timestamp":1786060800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001659","name":"Deutsche Forschungsgemeinschaft","doi-asserted-by":"publisher","award":["MU 1487\/38\u20101"],"award-info":[{"award-number":["MU 1487\/38\u20101"]}],"id":[{"id":"10.13039\/501100001659","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001659","name":"Deutsche Forschungsgemeinschaft","doi-asserted-by":"publisher","award":["AOBJ: 673749"],"award-info":[{"award-number":["AOBJ: 673749"]}],"id":[{"id":"10.13039\/501100001659","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"published-print":{"date-parts":[[2026,10]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Silicon suboxide (SiO\n                    <jats:sub>x<\/jats:sub>\n                    ) is a promising anode material for next\u2010generation high\u2010energy\u2010density lithium\u2010ion batteries due to its high theoretical capacity. However, pronounced volume expansion during lithiation leads to structural failure and interfacial instability, severely limiting its practical application. Conventional approaches, such as carbon coating or nanostructuring, mainly provide passive buffering and fail to fundamentally mitigate mechanical degradation. Herein, a synergistic modification strategy integrating mechanical reinforcement and interfacial catalysis is proposed for silicon\u2010based anodes. High\u2010performance ceramic silicon nitride (Si\n                    <jats:sub>3<\/jats:sub>\n                    N\n                    <jats:sub>4<\/jats:sub>\n                    ) is incorporated into SiO\n                    <jats:sub>x<\/jats:sub>\n                    via high\u2010energy ball milling (HEBM), forming a SiO\n                    <jats:sub>x<\/jats:sub>\n                    \u2010Si\n                    <jats:sub>3<\/jats:sub>\n                    N\n                    <jats:sub>4<\/jats:sub>\n                    composite anode (denoted as SiO\n                    <jats:sub>x<\/jats:sub>\n                    @Si\n                    <jats:sub>3<\/jats:sub>\n                    N\n                    <jats:sub>4<\/jats:sub>\n                    \u2010HEBM). The introduced Si\n                    <jats:sub>3<\/jats:sub>\n                    N\n                    <jats:sub>4<\/jats:sub>\n                    establishes a rigid supporting structure that suppresses volume expansion and particle agglomeration during lithiation, thereby alleviating mechanical stress. In addition, Si\n                    <jats:sub>3<\/jats:sub>\n                    N\n                    <jats:sub>4<\/jats:sub>\n                    catalyzes the in situ formation of a Li\n                    <jats:sub>3<\/jats:sub>\n                    N\u2010rich solid electrolyte interphase (SEI), enhancing interfacial ion\u2010transport kinetics. At a reversible capacity of 1350 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    , the capacity retention after 100 cycles at 0.5 C is improved from 38.89% to 64.36%, accompanied by enhanced rate capability and significantly reduced interfacial impedance. This work offers an effective strategy for improving the cycling stability of silicon\u2010based anodes through coupled mechanical and interfacial regulation, highlighting its potential for practical applications.\n                  <\/jats:p>","DOI":"10.1002\/smll.75085","type":"journal-article","created":{"date-parts":[[2026,8,8]],"date-time":"2026-08-08T06:47:44Z","timestamp":1786171664000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Silicon Nitride\u2010Enabled Mechanical Reinforcement and Interfacial Catalysis Toward Highly Stable Silicon\u2010Based Anodes"],"prefix":"10.1002","volume":"22","author":[{"given":"Xinyu","family":"Li","sequence":"first","affiliation":[{"name":"Ningbo Institute of Materials Technology and Engineering Chinese Academy of Sciences  Ningbo Zhejiang People's Republic of China"},{"name":"Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of Sciences  Beijing People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ming","family":"Yang","sequence":"additional","affiliation":[{"name":"Technical University of Munich TUM School of Natural Sciences Department of Physics Chair for Functional Materials  Garching Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qifei","family":"Dai","sequence":"additional","affiliation":[{"name":"Ningbo Institute of Materials Technology and Engineering Chinese Academy of Sciences  Ningbo Zhejiang People's Republic of China"},{"name":"Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of Sciences  Beijing People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Taotao","family":"Zhu","sequence":"additional","affiliation":[{"name":"Ningbo Institute of Materials Technology and Engineering Chinese Academy of Sciences  Ningbo Zhejiang People's Republic of China"},{"name":"Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of Sciences  Beijing People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiamin","family":"Duan","sequence":"additional","affiliation":[{"name":"Ningbo Institute of Materials Technology and Engineering Chinese Academy of Sciences  Ningbo Zhejiang People's Republic of China"},{"name":"Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of Sciences  Beijing People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jian","family":"Qian","sequence":"additional","affiliation":[{"name":"Ningbo Institute of Materials Technology and Engineering Chinese Academy of Sciences  Ningbo Zhejiang People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shuang","family":"Tian","sequence":"additional","affiliation":[{"name":"Ningbo Institute of Materials Technology and Engineering Chinese Academy of Sciences  Ningbo Zhejiang People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yiming","family":"Zhang","sequence":"additional","affiliation":[{"name":"Ningbo Institute of Materials Technology and Engineering Chinese Academy of Sciences  Ningbo Zhejiang People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Peter","family":"M\u00fcller\u2010Buschbaum","sequence":"additional","affiliation":[{"name":"Technical University of Munich TUM School of Natural Sciences Department of Physics Chair for Functional Materials  Garching Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ya\u2010Jun","family":"Cheng","sequence":"additional","affiliation":[{"name":"Ningbo Institute of Materials Technology and Engineering Chinese Academy of Sciences  Ningbo Zhejiang People's Republic of China"},{"name":"College of Renewable Energy Hohai University  Changzhou Jiangsu People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4901-1176","authenticated-orcid":false,"given":"Yonggao","family":"Xia","sequence":"additional","affiliation":[{"name":"Ningbo Institute of Materials Technology and Engineering Chinese Academy of Sciences  Ningbo Zhejiang People's Republic of China"},{"name":"Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of Sciences  Beijing People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,8,7]]},"reference":[{"key":"e_1_2_9_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/35104644"},{"key":"e_1_2_9_3_1","doi-asserted-by":"publisher","DOI":"10.1038\/nmat3191"},{"key":"e_1_2_9_4_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-021-25334-8"},{"key":"e_1_2_9_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mattod.2014.10.040"},{"key":"e_1_2_9_6_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-020-17686-4"},{"key":"e_1_2_9_7_1","doi-asserted-by":"publisher","DOI":"10.1038\/nnano.2007.411"},{"key":"e_1_2_9_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cis.2025.103543"},{"key":"e_1_2_9_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201301795"},{"key":"e_1_2_9_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202532199"},{"key":"e_1_2_9_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.pmatsci.2025.101546"},{"key":"e_1_2_9_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2018.07.014"},{"key":"e_1_2_9_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201900784"},{"key":"e_1_2_9_14_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8CS00441B"},{"key":"e_1_2_9_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202414714"},{"key":"e_1_2_9_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2024.150111"},{"key":"e_1_2_9_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jechem.2025.06.054"},{"key":"e_1_2_9_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jechem.2021.04.013"},{"key":"e_1_2_9_19_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202213363"},{"key":"e_1_2_9_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201707430"},{"key":"e_1_2_9_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202303020"},{"key":"e_1_2_9_22_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jechem.2023.07.015"},{"key":"e_1_2_9_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202503136"},{"key":"e_1_2_9_24_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202101796"},{"key":"e_1_2_9_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202302899"},{"key":"e_1_2_9_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202212890"},{"key":"e_1_2_9_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.2c16997"},{"key":"e_1_2_9_28_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2024.156266"},{"key":"e_1_2_9_29_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202407215"},{"key":"e_1_2_9_30_1","doi-asserted-by":"publisher","DOI":"10.1002\/eem2.12248"},{"key":"e_1_2_9_31_1","doi-asserted-by":"publisher","DOI":"10.1002\/eem2.12674"},{"key":"e_1_2_9_32_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202104135"},{"key":"e_1_2_9_33_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.5c02521"},{"key":"e_1_2_9_34_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2025.237486"},{"key":"e_1_2_9_35_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2016.11.044"},{"key":"e_1_2_9_36_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2019.06.031"},{"key":"e_1_2_9_37_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2TA09840G"},{"key":"e_1_2_9_38_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.4c22330"},{"key":"e_1_2_9_39_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202421687"},{"key":"e_1_2_9_40_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2021.229867"},{"key":"e_1_2_9_41_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jechem.2022.02.002"},{"key":"e_1_2_9_42_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202506266"},{"key":"e_1_2_9_43_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201702578"},{"key":"e_1_2_9_44_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-020-17951-6"},{"key":"e_1_2_9_45_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202504107"},{"key":"e_1_2_9_46_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202300431"},{"key":"e_1_2_9_47_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202400003"},{"key":"e_1_2_9_48_1","doi-asserted-by":"publisher","DOI":"10.1002\/eem2.70154"},{"key":"e_1_2_9_49_1","doi-asserted-by":"publisher","DOI":"10.1149\/2.008303jes"},{"key":"e_1_2_9_50_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b05029"},{"key":"e_1_2_9_51_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202502913"},{"key":"e_1_2_9_52_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2024.151151"},{"key":"e_1_2_9_53_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202412350"}],"container-title":["Small"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/smll.75085","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/smll.75085","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/smll.75085","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,10,13]],"date-time":"2026-10-13T09:48:48Z","timestamp":1791884928000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/smll.75085"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,8,7]]},"references-count":52,"journal-issue":{"issue":"57","published-print":{"date-parts":[[2026,10]]}},"alternative-id":["10.1002\/smll.75085"],"URL":"https:\/\/doi.org\/10.1002\/smll.75085","archive":["Portico"],"relation":{},"ISSN":["1613-6810","1613-6829"],"issn-type":[{"value":"1613-6810","type":"print"},{"value":"1613-6829","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,8,7]]},"assertion":[{"value":"2026-02-05","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-07-27","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-08-07","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e75085"}}