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The rational integration of Lewis acidic metal centers and tunable porosity within the UiO\u201066 framework enables enhanced catalytic activity and selectivity. These catalysts achieve high conversions and excellent selectivity toward polyesters and cyclic carbonates under mild conditions (80\u00b0C for CO\n                    <jats:sub>2<\/jats:sub>\n                    coupling; 110\u00b0C for ROCOP), with minimal by\u2010products. Importantly, the catalysts exhibit robust recyclability, maintaining structural integrity and performance over multiple cycles. This work demonstrates a versatile and durable MOF platform for green polymerization and CO\n                    <jats:sub>2<\/jats:sub>\n                    valorization, aligning with principles of sustainable catalysis and circular carbon utilization.\n                  <\/jats:p>","DOI":"10.1002\/smll.75139","type":"journal-article","created":{"date-parts":[[2026,8,12]],"date-time":"2026-08-12T07:38:08Z","timestamp":1786520288000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["A Bifunctional UiO\u201066 Platform Enabled by Schiff\u2010Base Engineering for CO\n                    <sub>2<\/sub>\n                    Conversion and Epoxide\u2013Anhydride Copolymerization"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-5853-6826","authenticated-orcid":false,"given":"Chen\u2010Yen","family":"Tsai","sequence":"first","affiliation":[{"name":"Department of Chemistry National Chung Hsing 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