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Here, we report a Zn(II) coordination complex, [Zn(NCS)\n                    <jats:sub>2<\/jats:sub>\n                    (Z\u2010fppan)\n                    <jats:sub>2<\/jats:sub>\n                    ] (\n                    <jats:bold>Z\u20101<\/jats:bold>\n                    , Z\u2010fppan = (Z)\u20102\u2010(3\u2010fluorophenyl)\u20103\u2010(pyridin\u20104\u2010yl)acrylonitrile), where the synergy between photochemical isomerization and photothermal\u2010induced temperature gradients enables millisecond\u2010scale response. Driven by this dual mechanism, the crystal demonstrates robust and reversible photoinduced bending (&gt;100 cycles). The generation of these localized stress gradients enables precise control over diverse photoactuated motions, including bending, rolling, and deflection. Additionally, single crystals of\n                    <jats:bold>Z\u20101<\/jats:bold>\n                    exhibit remarkable two\u2010dimensional elastic flexibility under mechanical stress, deforming reversibly along the (110)\/(\u20101\u201010) and (\u2010110)\/(1\u201010) planes. The combination of rapid photomechanical actuation and mechanical adaptability presents a unique example of dual\u2010stimulus responsive behavior in metal\u2010organic systems. To demonstrate this practical utility, we leveraged this photomechanical behavior for wireless manipulation, successfully achieving remote\u2010controlled actuation. Such properties position\n                    <jats:bold>Z\u20101<\/jats:bold>\n                    as a promising candidate for light\u2010driven smart actuators and soft robotics.\n                  <\/jats:p>","DOI":"10.1002\/smll.75146","type":"journal-article","created":{"date-parts":[[2026,8,20]],"date-time":"2026-08-20T09:57:07Z","timestamp":1787219827000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Rapid, Robust, and Reversible Photomechanical Bending in a Flexible Zinc(II) Complex Crystal with 2D Elasticity for Controlled Motion"],"prefix":"10.1002","volume":"22","author":[{"given":"Jianmin","family":"Zhou","sequence":"first","affiliation":[{"name":"School of Chemical Engineering and Technology National Engineering Research Center of Industrial Crystallization Technology Tianjin University  Tianjin China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bo","family":"Jing","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering and Technology National Engineering Research Center of Industrial Crystallization Technology Tianjin University  Tianjin China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yingzi","family":"Zheng","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering and Technology National Engineering Research Center of Industrial Crystallization Technology Tianjin University  Tianjin China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuhan","family":"Yang","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering and Technology National Engineering Research Center of Industrial Crystallization Technology Tianjin University  Tianjin 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Engineering and Low\u2010Carbon Technology Tianjin University  Tianjin China"},{"name":"Haihe Laboratory of Sustainable Chemical Transformations  Tianjin 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