{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,18]],"date-time":"2026-10-18T13:44:51Z","timestamp":1792331091246,"version":"4.4.0"},"reference-count":64,"publisher":"Wiley","issue":"58","license":[{"start":{"date-parts":[[2026,8,11]],"date-time":"2026-08-11T00:00:00Z","timestamp":1786406400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,8,11]],"date-time":"2026-08-11T00:00:00Z","timestamp":1786406400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100017596","name":"Natural Science Basic Research Program of Shaanxi Province","doi-asserted-by":"publisher","award":["2025JC\u2010YBMS\u2010576"],"award-info":[{"award-number":["2025JC\u2010YBMS\u2010576"]}],"id":[{"id":"10.13039\/501100017596","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52175156"],"award-info":[{"award-number":["52175156"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52505167"],"award-info":[{"award-number":["52505167"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"published-print":{"date-parts":[[2026,10]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Lubrication additives that combine high efficiency at low concentrations with broad universality are urgently needed for breaking through the bottleneck of current lubricants. Herein, two novel green deep eutectic solvents are designed using tartaric acid (TA), malic acid (MA), and L\u2010carnitine and inserted into layered double hydroxide (LDH) gallery to fabricate four intercalated LDH composites. The intercalation successfully exfoliates pristine LDH material, and ultra\u2010thin flexible sheets can be obtained with the controllable interlayer spacing, based on guest molecular geometries and interlayer configurations. The tribological performance reveal that molecular intercalation expands the interlayer spacing and improves interlayer shear, while the confined gallery space together with hydrogen bonding interactions enables in situ carbonization of guest molecules, forming a carbonaceous or nitrogen\u2010doped carbon film. Moreover, LDH itself undergoes tribo\u2010chemical reactions to transform into inorganic nanocrystals (ZnO, ZnAl\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>4<\/jats:sub>\n                    ), which together with the carbon film, constitute a robust hybrid tribofilm. Eventually, TADES\u2010LDH (rigid planar geometry, flat\u2010lying configuration) exhibits excellent long\u2010term lubrication, anti\u2010wear (decreases by over 90%), and load\u2010bearing properties (500 N), while achieves surprising universality across a wide range of base fluids (PEG, water, ester oil, liquid paraffin). This work offers a new paradigm for designing high\u2010performance, universal lubricant additives toward the sustainable lubrication technology.\n                  <\/jats:p>","DOI":"10.1002\/smll.75157","type":"journal-article","created":{"date-parts":[[2026,8,12]],"date-time":"2026-08-12T05:16:46Z","timestamp":1786511806000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Molecular Geometry Governs Interlayer Orientation: Confined Carbonization of Deep Eutectic Solvent\u2010Intercalated Hydrotalcite for Universal Lubrication via Hybrid Tribofilm"],"prefix":"10.1002","volume":"22","author":[{"given":"Ke","family":"Yang","sequence":"first","affiliation":[{"name":"College of Chemistry and Materials Engineering Baoji University of Arts and Sciences  Baoji People's Republic of 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People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shibo","family":"Liu","sequence":"additional","affiliation":[{"name":"College of Chemistry and Materials Engineering Baoji University of Arts and Sciences  Baoji People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ping","family":"Wen","sequence":"additional","affiliation":[{"name":"College of Chemistry and Materials Engineering Baoji University of Arts and Sciences  Baoji People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rui","family":"Dong","sequence":"additional","affiliation":[{"name":"College of Chemistry and Materials Engineering Baoji University of Arts and Sciences  Baoji People's Republic of China"},{"name":"State Key Laboratory of Solid Lubrication Lanzhou Institute of Chemical Physics Chinese Academy of Sciences  Lanzhou People's Republic of China"},{"name":"State Key Laboratory of Solidification 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