{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,18]],"date-time":"2026-10-18T13:45:19Z","timestamp":1792331119823,"version":"4.4.0"},"reference-count":41,"publisher":"Wiley","issue":"58","license":[{"start":{"date-parts":[[2026,8,11]],"date-time":"2026-08-11T00:00:00Z","timestamp":1786406400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,8,11]],"date-time":"2026-08-11T00:00:00Z","timestamp":1786406400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["62404251"],"award-info":[{"award-number":["62404251"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["12574216"],"award-info":[{"award-number":["12574216"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["62341406"],"award-info":[{"award-number":["62341406"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100002858","name":"China Postdoctoral Science Foundation","doi-asserted-by":"publisher","award":["2024M753515"],"award-info":[{"award-number":["2024M753515"]}],"id":[{"id":"10.13039\/501100002858","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"published-print":{"date-parts":[[2026,10]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Al is a promising anode for next\u2010generation batteries due to its abundance, high theoretical capacity, and good safety. However, the deployment of Al metal batteries (AMBs) is hindered by the lack of efficient electrolytes capable of enabling highly reversible and uniform Al plating\/stripping. Here we develop a relatively economical and low\u2010corrosive AlCl\n                    <jats:sub>3<\/jats:sub>\n                    \/tetramethylurea (TMU) deep eutectic electrolyte (DEE) that supports reversible Al electrodeposition with an enhanced (111) orientation tendency. To further reduce viscosity and enhance ionic conductivity, a non\u2010solvating 1,2\u2010difluorobenzene (1,2\u2010dFBn) co\u2010solvent is introduced to construct a localized\u2010high\u2010concentration\u2010electrolyte\u2010like (LHCE\u2010like) DEE. The 1,2\u2010dFBn incorporation selectively modulates the local environment of chloroaluminate species without altering their intrinsic speciation, thereby improving electrolyte fluidity and ion transport. Moreover, 1,2\u2010dFBn promotes the formation of a robust SEI, accompanied by a reduced apparent nucleation overpotential and more uniform Al deposition. Consequently, the optimized electrolyte enables stable Al cycling for over 1,600\u00a0h at 1.0\u00a0mA\u00a0cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    and 1.0\u00a0mAh\u00a0cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    with an ultralow polarization of \u223c80\u00a0mV. Al||graphite cells deliver 80.6\u00a0mAh\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    after 600 cycles at 500\u00a0mA\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    with nearly 100% Coulombic efficiency. This work provides valuable insights into the rational design of low\u2010cost and high\u2010performance electrolytes for AMBs.\n                  <\/jats:p>","DOI":"10.1002\/smll.75189","type":"journal-article","created":{"date-parts":[[2026,8,12]],"date-time":"2026-08-12T05:51:31Z","timestamp":1786513891000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["A Deep Eutectic Electrolyte Mimicking a Localized High\u2010Concentration Environment Enables Reversible Aluminum Electrodeposition for High\u2010Performance Aluminum Metal Batteries"],"prefix":"10.1002","volume":"22","author":[{"given":"Xiaoxiao","family":"Wang","sequence":"first","affiliation":[{"name":"School of Materials Science and Physics China University of Mining and Technology  Xuzhou Jiangsu 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Mining and Technology  Xuzhou Jiangsu China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Meng","family":"Yuan","sequence":"additional","affiliation":[{"name":"School of Materials Science and Physics China University of Mining and Technology  Xuzhou Jiangsu China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lingxiu","family":"Chen","sequence":"additional","affiliation":[{"name":"School of Materials Science and Physics China University of Mining and Technology  Xuzhou Jiangsu China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yue","family":"Yu","sequence":"additional","affiliation":[{"name":"School of Materials Science and Physics China University of Mining and Technology  Xuzhou Jiangsu China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shixuan","family":"Wang","sequence":"additional","affiliation":[{"name":"School of Materials Science and Physics China University of Mining and Technology  Xuzhou Jiangsu 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