{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,18]],"date-time":"2026-10-18T13:44:46Z","timestamp":1792331086116,"version":"4.4.0"},"reference-count":54,"publisher":"Wiley","issue":"58","license":[{"start":{"date-parts":[[2026,8,13]],"date-time":"2026-08-13T00:00:00Z","timestamp":1786579200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,8,13]],"date-time":"2026-08-13T00:00:00Z","timestamp":1786579200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100004442","name":"Narodowym Centrum Nauki","doi-asserted-by":"publisher","award":["UMO\u20102023\/49\/BST11\/01504"],"award-info":[{"award-number":["UMO\u20102023\/49\/BST11\/01504"]}],"id":[{"id":"10.13039\/501100004442","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"published-print":{"date-parts":[[2026,10]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Beam\u2010induced chemistry in liquid\u2010phase imaging is now recognized as a key factor in interpreting nanoscale redox processes, yet its consequences depend strongly on the irradiation modality, solvent chemistry, and reacting material system. Here, we compare how soft X\u2010ray and electron irradiation redirect the same galvanic replacement reaction between Cu\n                    <jats:sub>2<\/jats:sub>\n                    O nanocubes and gold precursors. In this model system, soft X\u2010ray irradiation generates an oxidizing environment that promotes Cu\n                    <jats:sub>2<\/jats:sub>\n                    O dissolution and hollow Au nanobox formation, whereas electron irradiation favors surface\u2010confined Au deposition and Au@Cu\n                    <jats:sub>2<\/jats:sub>\n                    O core\u2010shell architectures. Adjusting the solution chemistry during LC\u2010TEM restores the hollowing pathway, showing that the local beam\u2010induced chemical environment controls the balance between deposition and dissolution. These findings demonstrate that, in Cu\n                    <jats:sub>2<\/jats:sub>\n                    O\u2010Au galvanic replacement, the imaging beam is not merely a passive probe, but can actively reshape the observed nanoscale reaction pathway.\n                  <\/jats:p>","DOI":"10.1002\/smll.75209","type":"journal-article","created":{"date-parts":[[2026,8,13]],"date-time":"2026-08-13T08:02:33Z","timestamp":1786608153000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Electrons Make Shells, Photons Make Boxes: Unmasking Radiation Chemistry in Liquid\u2010Phase Imaging"],"prefix":"10.1002","volume":"22","author":[{"given":"Babak","family":"Alavi","sequence":"first","affiliation":[{"name":"Institute of Nuclear Physics Polish Academy of Sciences  Krakow Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Joanna","family":"Depciuch","sequence":"additional","affiliation":[{"name":"Institute of Nuclear Physics Polish Academy of Sciences  Krakow Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mohammad Sadegh","family":"Shakeri","sequence":"additional","affiliation":[{"name":"Institute of Nuclear Physics Polish Academy of Sciences  Krakow Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kamil","family":"Sobczak","sequence":"additional","affiliation":[{"name":"Faculty of Chemistry Biological and Chemical Research Centre  Warsaw Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Krzysztof","family":"Matlak","sequence":"additional","affiliation":[{"name":"Solaris National Synchrotron Radiation Centre Jagiellonian University  Krakow Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Magdalena","family":"Parlinska","sequence":"additional","affiliation":[{"name":"Institute of Nuclear Physics Polish Academy of Sciences  Krakow Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,8,13]]},"reference":[{"key":"e_1_2_9_2_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9SC02227A"},{"key":"e_1_2_9_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c03906"},{"key":"e_1_2_9_4_1","doi-asserted-by":"publisher","DOI":"10.1557\/s43577\u2010024\u201000661\u20105"},{"key":"e_1_2_9_5_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0CP06369J"},{"key":"e_1_2_9_6_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202514610"},{"key":"e_1_2_9_7_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929\u2010019\u20100338\u2010z"},{"key":"e_1_2_9_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.5b00482"},{"key":"e_1_2_9_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.3c02575"},{"key":"e_1_2_9_10_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7CC02352A"},{"key":"e_1_2_9_11_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9NR01359H"},{"key":"e_1_2_9_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.0c00940"},{"key":"e_1_2_9_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.1c04176"},{"key":"e_1_2_9_14_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms5946"},{"key":"e_1_2_9_15_1","doi-asserted-by":"publisher","DOI":"10.1063\/5.0203665"},{"key":"e_1_2_9_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.3c00646"},{"key":"e_1_2_9_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.est.0c04694"},{"key":"e_1_2_9_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.8b00527"},{"key":"e_1_2_9_19_1","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.2216480120"},{"key":"e_1_2_9_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.3c02359"},{"key":"e_1_2_9_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp507400n"},{"key":"e_1_2_9_22_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.radphyschem.2018.08.001"},{"key":"e_1_2_9_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.2c11477"},{"key":"e_1_2_9_24_1","volume-title":"Liquid Cell Electron Microscopy","author":"Ross F. 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