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Solid\u2010state electrolytes hold potential for effectively addressing issues in aqueous electrolytes. However, the development of solid\u2010state ZIBs is fundamentally limited by the physicochemical characteristics of Zn\n                    <jats:sup>2+<\/jats:sup>\n                    . Due to the multivalent nature of Zn\n                    <jats:sup>2+<\/jats:sup>\n                    , they are subject to stronger coordination constraints, and Zn\n                    <jats:sup>2+<\/jats:sup>\n                    migration is dominated by desolvation processes and coordination restructuring, contributing to slow ion transport in solid\u2010state environments. Here, we establish a mechanism\u2010oriented framework for understanding Zn\n                    <jats:sup>2+<\/jats:sup>\n                    transport in solid\u2010state electrolytes, including inorganic solid\u2010state electrolytes, solid\u2010state polymer electrolytes, and quasi\u2010solid\u2010state electrolytes. Specifically, we summarize the vacancy transport mechanism and gap transport mechanism for Zn\n                    <jats:sup>2+<\/jats:sup>\n                    transport in inorganic solid\u2010state electrolytes, the chain segment motion\u2010assisted transport mechanism in solid\u2010state polymer electrolytes, and the liquid\u2013solid synergistic mechanism in quasi\u2010solid\u2010state electrolytes. On this basis, we propose general design principles for overcoming coordination constraints in each type of solid\u2010state electrolyte. Importantly, the concepts presented here extend beyond zinc\u2010ion systems and offer a unified perspective on multivalent\u2010ion transport in solid\u2010state electrolytes. This work will provide actionable insights for the rational design of next\u2010generation solid\u2010state batteries.\n                  <\/jats:p>","DOI":"10.1002\/smll.75216","type":"journal-article","created":{"date-parts":[[2026,8,20]],"date-time":"2026-08-20T12:31:26Z","timestamp":1787229086000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Coordination\u2010Constrained Zinc Ions Transport in Solid\u2010State Electrolytes: Mechanisms and Design Principles"],"prefix":"10.1002","volume":"22","author":[{"given":"Jian","family":"Zhang","sequence":"first","affiliation":[{"name":"State Key Laboratory of High Performance Ceramics Shanghai Institute of Ceramics Chinese Academy of Sciences  Shanghai P. R. China"},{"name":"Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of Sciences  Beijing P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kaihang","family":"Yue","sequence":"additional","affiliation":[{"name":"State Key Laboratory of High Performance Ceramics Shanghai Institute of Ceramics Chinese Academy of Sciences  Shanghai P. R. China"},{"name":"Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of Sciences  Beijing P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zihan","family":"Xu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of High Performance Ceramics Shanghai Institute of Ceramics Chinese Academy of Sciences  Shanghai P. R. China"},{"name":"Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of Sciences  Beijing P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mei","family":"Han","sequence":"additional","affiliation":[{"name":"State Key Laboratory of High Performance Ceramics Shanghai Institute of Ceramics Chinese Academy of Sciences  Shanghai P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8474-1954","authenticated-orcid":false,"given":"Jian","family":"Zhi","sequence":"additional","affiliation":[{"name":"State Key Laboratory of High Performance Ceramics Shanghai Institute of Ceramics Chinese Academy of Sciences  Shanghai P. R. China"},{"name":"Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of Sciences  Beijing P. R. 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