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In this study, benefit from the introduction of Co to Mo\n                    <jats:sup>n+<\/jats:sup>\n                    C catalyst, a rapid diffusion of Li\n                    <jats:sub>2<\/jats:sub>\n                    C\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>4<\/jats:sub>\n                    has been realized with a solution\u2010mediated dissolution process, leading to heterostructure products with mixed growth of Li\n                    <jats:sub>2<\/jats:sub>\n                    CO\n                    <jats:sub>3<\/jats:sub>\n                    and C. Furthermore, in this Co\u2010loaded Mo\n                    <jats:sup>n+<\/jats:sup>\n                    C catalyst, the Mo\n                    <jats:sup>+2\/+3<\/jats:sup>\n                    C serves as a solid redox mediator and facilitate electron transfer from Mo\n                    <jats:sup>+2\/+3<\/jats:sup>\n                    C to the CO\n                    <jats:sub>2<\/jats:sub>\n                    molecule through the formation of C\u2500O\u2500Mo bond, then they achieved an ultrahigh discharge voltage of 3.1\u00a0V in the CO\n                    <jats:sub>2<\/jats:sub>\n                    RR process. Through the regulation of the CO\n                    <jats:sub>2<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    and Li\n                    <jats:sub>2<\/jats:sub>\n                    CO\n                    <jats:sub>3<\/jats:sub>\n                    absorbing of Mo\n                    <jats:sub>2<\/jats:sub>\n                    C, the synchronous decomposition of both discharge products, Li\n                    <jats:sub>2<\/jats:sub>\n                    CO\n                    <jats:sub>3<\/jats:sub>\n                    and C is achieved, avoiding the irreversible accumulation of carbon that leads to capacity decay. This enables Li\u2010CO\n                    <jats:sub>2<\/jats:sub>\n                    batteries to achieve an ultra\u2010long cycle life exceeding 4800 h. This design provides new insights for the future optimization of charge\/discharge pathways, especially the synchronous decomposition of two solid\u2010phase products Li\n                    <jats:sub>2<\/jats:sub>\n                    CO\n                    <jats:sub>3<\/jats:sub>\n                    and C in Li\u2010CO\n                    <jats:sub>2<\/jats:sub>\n                    batteries.\n                  <\/jats:p>","DOI":"10.1002\/smll.75243","type":"journal-article","created":{"date-parts":[[2026,8,13]],"date-time":"2026-08-13T06:55:38Z","timestamp":1786604138000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Ultra\u2010Long Cycle Life in Lithium\u2010Carbon Dioxide Batteries via Synergistic Solution Pathway Regulation and Redox\u2010Mediating Effect of Mo\/Co Species"],"prefix":"10.1002","volume":"22","author":[{"given":"Yangjie","family":"Yan","sequence":"first","affiliation":[{"name":"Department 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