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Developing high\u2010performance catalysts at low temperature is still a great challenge. Herein, CuO\u2010supported on different AMn\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>5<\/jats:sub>\n                    mullites (A = Pr, Sm, Eu, Y) have been designed in this work. It has been discovered that CuO\/YMn\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>5<\/jats:sub>\n                    demonstrates a superior H\n                    <jats:sub>2<\/jats:sub>\n                    production rate (219.7 \u00b5mol\u00b7g\n                    <jats:sub>cat.<\/jats:sub>\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u00b7s\n                    <jats:sup>\u22121<\/jats:sup>\n                    ) with ultra\u2010low CO selectivity (0.12%) at 240\u00b0C. XAFS, XRD, Raman, FTIR, and DFT calculations have testified that abundant Cu\u2010O\u2010M (M\u2550Y, Mn) interface bonds are formed as reactive sites, due to a strong metal oxide support interaction (SMOSI) occurring between CuO and YMn\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>5<\/jats:sub>\n                    , which is confirmed by a significant H\n                    <jats:sub>2<\/jats:sub>\n                    spillover effect. In situ XPS and\n                    <jats:sup>18<\/jats:sup>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    tracing have proved that the surface oxygen exchange and electron transfer rates can be accelerated, thus forming abundant active surface oxygen sites. Meanwhile, the SMOSI effect remarkably improves the contents of surface Cu\n                    <jats:sup>0<\/jats:sup>\n                    \/Cu\n                    <jats:sup>+<\/jats:sup>\n                    and alkaline sites, and active Cu metallic surface. The synergistic interaction of these factors promotes the activation of CH\n                    <jats:sub>3<\/jats:sub>\n                    OH and H\n                    <jats:sub>2<\/jats:sub>\n                    O molecules and the generation of a great amount of reactive formate intermediates, yielding a catalyst with superior MSR performance.\n                  <\/jats:p>","DOI":"10.1002\/smll.75328","type":"journal-article","created":{"date-parts":[[2026,8,19]],"date-time":"2026-08-19T09:14:21Z","timestamp":1787130861000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Synthesize High Efficiency CuO\/Mullite Catalysts for Methanol Steam Reforming to Produce Hydrogen: On the SMSI Effect Originating from the Strong CuO\u2010Support Interaction"],"prefix":"10.1002","volume":"22","author":[{"given":"Jiamei","family":"Ma","sequence":"first","affiliation":[{"name":"Key Laboratory of Jiangxi Province for Environment and Energy Catalysis, School of Chemistry and Chemical Engineering Nanchang University  Nanchang Jiangxi People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiangyun","family":"He","sequence":"additional","affiliation":[{"name":"Key Laboratory of Jiangxi Province for Environment and Energy Catalysis, School of Chemistry and Chemical Engineering Nanchang University  Nanchang Jiangxi People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jia","family":"Huang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Jiangxi Province for Environment and Energy Catalysis, School of Chemistry and Chemical Engineering Nanchang University  Nanchang Jiangxi People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xinran","family":"Pang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Jiangxi Province for Environment and Energy Catalysis, School 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