{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,22]],"date-time":"2026-08-22T11:25:23Z","timestamp":1787397923845,"version":"build-2736575974"},"reference-count":67,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,8,22]],"date-time":"2026-08-22T00:00:00Z","timestamp":1787356800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,8,22]],"date-time":"2026-08-22T00:00:00Z","timestamp":1787356800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["62474099"],"award-info":[{"award-number":["62474099"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004608","name":"Natural Science Foundation of Jiangsu Province","doi-asserted-by":"publisher","award":["BK20250950"],"award-info":[{"award-number":["BK20250950"]}],"id":[{"id":"10.13039\/501100004608","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Solid\u2010state lithium\u2013sulfur (Li\u2013S) batteries are widely regarded as promising storage systems owing to their intrinsic safety and high theoretical energy density. Nevertheless, their practical applications remain limited by coupled ion transport, interfacial instability, and polysulfide migration. Here, an amphiphile\u2010induced dual\u2010domain poly(1,3\u2010dioxolane) (PDOL) electrolyte is in situ polymerized to resolve this limitation. Microphase separation generates interconnected polar domains embedded within a nonpolar matrix. Li\n                    <jats:sup>+<\/jats:sup>\n                    transport is preferentially facilitated within polar domains, while polysulfide diffusion is spatially confined by nonpolar domains through decoupled ion\/polysulfide transport pathways. At the lithium interface, phospholipid molecules form an adaptive interphase that regulates Li\n                    <jats:sup>+<\/jats:sup>\n                    flux, promotes inorganic\u2010rich solid electrolyte interphase (SEI) formation, and suppresses parasitic reactions. As a result, stable Li\n                    <jats:sup>+<\/jats:sup>\n                    plating\/stripping is sustained for over 5500\u00a0h at 1\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    , while Li\u2013S full cells exhibit an initial capacity of 884.7 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    with 74.6% retention after 400 cycles at 1 C. This work establishes a dual\u2010domain electrolyte design paradigm for decoupling bulk ion transport regulation and interfacial stabilization in Li\u2013S batteries.\n                  <\/jats:p>","DOI":"10.1002\/smll.75348","type":"journal-article","created":{"date-parts":[[2026,8,22]],"date-time":"2026-08-22T11:16:45Z","timestamp":1787397405000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Amphiphile\u2010Induced Dual\u2010Domain PDOL Electrolyte Enabling Decoupled Ion Transport and Interfacial Stability in Li\u2010S Batteries"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-2763-6012","authenticated-orcid":false,"given":"Zhenguo","family":"Wang","sequence":"first","affiliation":[{"name":"School of Microelectronics and Integrated Circuits (Jiangsu Key Laboratory of Semi. Dev. &amp; IC Design, Package and Test) Nantong University  Nantong Jiangsu China"},{"name":"School of Information Science and Technology Nantong University  Nantong Jiangsu China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xi","family":"Li","sequence":"additional","affiliation":[{"name":"School of Microelectronics and Integrated Circuits (Jiangsu Key Laboratory of Semi. Dev. &amp; IC Design, Package and Test) Nantong University  Nantong Jiangsu China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xinyan","family":"Ma","sequence":"additional","affiliation":[{"name":"School of Microelectronics and Integrated Circuits (Jiangsu Key Laboratory of Semi. Dev. &amp; IC Design, Package and Test) Nantong University  Nantong Jiangsu China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhiwen","family":"Zheng","sequence":"additional","affiliation":[{"name":"School of Microelectronics and Integrated Circuits (Jiangsu Key Laboratory of Semi. 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