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In contrast to conventional amidation, this approach uses electrode potential to regulate substrate activation and C\u2500N bond formation, thereby offering opportunities to reduce reagent consumption and improve process sustainability. However, selective amide formation remains difficult because the target pathway competes with substrate over\u2010oxidation, over\u2010reduction, and the formation of non\u2010amide C\u2500N products. In this Review, we summarize recent advances in the electrocatalytic synthesis of carboxamides from an amide\u2010specific mechanistic perspective. The discussion is organized into anodic oxidative amidation, cathodic reductive amidation, and integrated full\u2010cell electrosynthesis. Particular emphasis is placed on carbonyl\u2010level carbon activation, nitrogen\u2010intermediate generation, interfacial regulation, electrolyte mediation, and reactor configuration. Finally, key mechanistic and engineering challenges are identified to guide the further development of selective, scalable amide electrosynthesis.<\/jats:p>","DOI":"10.1002\/smll.75595","type":"journal-article","created":{"date-parts":[[2026,9,7]],"date-time":"2026-09-07T09:26:44Z","timestamp":1788773204000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Electrocatalytic Amide Synthesis: Mechanistic Pathways and Selectivity Control in C\u2010N Coupling"],"prefix":"10.1002","author":[{"given":"Jianguo","family":"Tao","sequence":"first","affiliation":[{"name":"College of Chemistry and Materials Science Anhui Normal University  Wuhu People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dingkun","family":"Yao","sequence":"additional","affiliation":[{"name":"College of Chemistry and Materials Science Anhui Normal University  Wuhu People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mingxin","family":"Guo","sequence":"additional","affiliation":[{"name":"College of Chemistry and Materials Science Anhui Normal University  Wuhu People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0009-4565-4204","authenticated-orcid":false,"given":"Jianrui","family":"Zhang","sequence":"additional","affiliation":[{"name":"Shenzhen X\u2010institute  Shenzhen People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5632-1100","authenticated-orcid":false,"given":"Qing","family":"Qin","sequence":"additional","affiliation":[{"name":"College of Chemistry and Materials Science Anhui Normal University  Wuhu People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,9,7]]},"reference":[{"key":"e_1_2_9_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202510907"},{"key":"e_1_2_9_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/jm200187y"},{"key":"e_1_2_9_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jmedchem.5b01409"},{"key":"e_1_2_9_5_1","doi-asserted-by":"publisher","DOI":"10.1039\/B701677H"},{"issue":"28","key":"e_1_2_9_6_1","doi-asserted-by":"crossref","DOI":"10.1002\/aenm.202303820","article-title":"Electrocatalytic C\u2212 N Couplings at Cathode and Anode","volume":"14","author":"Chen D.","year":"2024","journal-title":"Advanced Energy Materials"},{"issue":"28","key":"e_1_2_9_7_1","article-title":"Rationally Designed Carbon\u2010Based Catalysts for Electrochemical C\u2013N Coupling","volume":"14","author":"Li Y.","year":"2024","journal-title":"Advanced Energy Materials"},{"issue":"3","key":"e_1_2_9_8_1","doi-asserted-by":"crossref","DOI":"10.1002\/anie.202311752","article-title":"Electrocatalytic Systems for nox Valorization in Organonitrogen Synthesis","volume":"63","author":"Liao P.","year":"2024","journal-title":"Angewandte Chemie International Edition"},{"key":"e_1_2_9_9_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929\u2010018\u20100211\u20105"},{"key":"e_1_2_9_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202513012"},{"key":"e_1_2_9_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mattod.2024.01.009"},{"issue":"45","key":"e_1_2_9_12_1","doi-asserted-by":"crossref","DOI":"10.1002\/anie.202513359","article-title":"Steering Amide Synthesis from Acetonitrile by Electrochemically Derived Active Superoxide","volume":"64","author":"Dong L. 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