{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,2]],"date-time":"2026-09-02T11:17:55Z","timestamp":1788347875945,"version":"build-2803163510"},"reference-count":65,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,9,2]],"date-time":"2026-09-02T00:00:00Z","timestamp":1788307200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,9,2]],"date-time":"2026-09-02T00:00:00Z","timestamp":1788307200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Conventional photocatalysts pronounced electron\u2010hole recombination and a limited number of active sites. To address these challenges, Bi\u2010N bridged bonds were interlinked at the interface of the heterojunction via coating crystalline Bi\n                    <jats:sub>2<\/jats:sub>\n                    MoO\n                    <jats:sub>6<\/jats:sub>\n                    with amorphous MOF (Bi\n                    <jats:sub>2<\/jats:sub>\n                    MoO\n                    <jats:sub>6<\/jats:sub>\n                    @ZIF\u2010Fe). Simultaneously, Bi metal vacancies (V\n                    <jats:sub>M<\/jats:sub>\n                    ) and MoO\n                    <jats:sub>3<\/jats:sub>\n                    quantum dots (QDs) were formed to accelerate the transfer of electrons (e\n                    <jats:sup>\u2212<\/jats:sup>\n                    ). This system facilitates the formation of an S\u2010scheme heterojunction, in which photogenerated holes (h\n                    <jats:sup>+<\/jats:sup>\n                    ) are attracted by metal vacancies, thereby suppressing the recombination of photogenerated charge carriers. Meanwhile, electrons (e\n                    <jats:sup>\u2212<\/jats:sup>\n                    ) in the amorphous ZIF\u2010Fe valence band (VB) and the Bi\n                    <jats:sub>2<\/jats:sub>\n                    MoO\n                    <jats:sub>6<\/jats:sub>\n                    conduction band (CB) were involved in the photocatalytic reaction. The highest visible light catalytic activity for nitrogen fixation in pure water was measured at 4551.38 \u00b5mol L\n                    <jats:sup>\u22121<\/jats:sup>\n                    g\n                    <jats:sup>\u22121<\/jats:sup>\n                    h\n                    <jats:sup>\u22121<\/jats:sup>\n                    . A nitrogen fixation performance of 6309.1 \u00b5mol L\n                    <jats:sup>\u22121<\/jats:sup>\n                    g\n                    <jats:sup>\u22121<\/jats:sup>\n                    h\n                    <jats:sup>\u22121<\/jats:sup>\n                    was attained using methanol as a sacrificial agent (water\/methanol = 95\/5, v\/v). Density functional theory (DFT) calculations, including ab initio molecular dynamics (AIMD) simulations of amorphous ZIF\u2010Fe, reveal that the presence of Bi\u2010N bridges facilitates the formation of rapid electron transfer pathways. Concurrently, the inclusion of MoO\n                    <jats:sub>3<\/jats:sub>\n                    quantum dots significantly enhances the capabilities of electron transfer and accelerates the process in amorphous ZIF\u2010Fe\u2010based heterojunctions.\n                  <\/jats:p>","DOI":"10.1002\/smll.75608","type":"journal-article","created":{"date-parts":[[2026,9,2]],"date-time":"2026-09-02T11:01:37Z","timestamp":1788346897000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Amorphous MOF \/ Crystalline Bi\n                    <sub>2<\/sub>\n                    MoO\n                    <sub>6<\/sub>\n                    Heterojunction Interfaces: Engineering Quantum Dots and Electron Bridges for Synergistic High\u2010Efficiency Photocatalytic Nitrogen Fixation"],"prefix":"10.1002","author":[{"given":"Haibo","family":"Guo","sequence":"first","affiliation":[{"name":"College of Chemical Engineering Inner 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