{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,1]],"date-time":"2026-09-01T15:26:54Z","timestamp":1788276414629,"version":"build-2803163510"},"reference-count":62,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,9,1]],"date-time":"2026-09-01T00:00:00Z","timestamp":1788220800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,9,1]],"date-time":"2026-09-01T00:00:00Z","timestamp":1788220800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22275003"],"award-info":[{"award-number":["22275003"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52573188"],"award-info":[{"award-number":["52573188"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Polyhedral boron clusters possess unique properties, yet their luminescence applications have largely been confined to carborane derivatives. Here, we introduce decaborane clusters [B\n                    <jats:sub>10<\/jats:sub>\n                    H\n                    <jats:sub>12<\/jats:sub>\n                    L\n                    <jats:sub>2<\/jats:sub>\n                    ] (L = pyridine\u2010like ligands) as an innovative class of organic\u2010inorganic TADF materials. These clusters exhibit exceptional air and moisture stability, and are readily accessible. A series of fourteen emitters, displaying tunable green\u2010to\u2010orange TADF with the quantum efficiency of up to 99%, was synthesized. Detailed photophysical studies reveal that these clusters adopt a flexible A\u2013D\u2013A architecture [L\u2013B\n                    <jats:sub>10<\/jats:sub>\n                    H\n                    <jats:sub>12<\/jats:sub>\n                    \u2013L] with a pronounced charge\u2010transfer character and ultranarrow singlet\u2010triplet energy splittings (as small as 29 cm\n                    <jats:sup>\u22121<\/jats:sup>\n                    , \u22480.0036 eV). Beyond TADF properties, these heavy\u2010atom\u2010free emitters demonstrate pronounced\u00a0 X\u2010ray scintillation (detection limit: 67 \u00b5Gy\n                    <jats:sub>air<\/jats:sub>\n                    s\n                    <jats:sup>\u22121<\/jats:sup>\n                    ) and strong aggregation\u2010induced emission (AIE) behavior. Their utility is further evidenced by electroluminescence in proof\u2010of\u2010concept OLEDs, including a white\u2010emitting device. This work establishes decaborane clusters as a versatile and readily accessible platform for next\u2010generation TADF materials, expanding the frontiers of p\u2010block cluster chemistry.\n                  <\/jats:p>","DOI":"10.1002\/smll.75612","type":"journal-article","created":{"date-parts":[[2026,9,1]],"date-time":"2026-09-01T15:07:54Z","timestamp":1788275274000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Decaborane Clusters: A New Class of Organic\u2010Inorganic TADF Materials for X\u2010Ray Scintillation and Electroluminescence"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-6418-9477","authenticated-orcid":false,"given":"Maria P.","family":"Davydova","sequence":"first","affiliation":[{"name":"Nikolaev Institute of Inorganic Chemistry SB RAS  Novosibirsk Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0402-1138","authenticated-orcid":false,"given":"Evgeny A.","family":"Mostovich","sequence":"additional","affiliation":[{"name":"Novosibirsk State University  Novosibirsk Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4571-394X","authenticated-orcid":false,"given":"Lingqiang","family":"Meng","sequence":"additional","affiliation":[{"name":"School of Advanced Materials, Peking University Shenzhen Graduate School Peking University  Shenzhen People's Republic of China"},{"name":"Henan Institute of FlexibleElectronics (HIFE) Henan University  Zhengzhou People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8114-6479","authenticated-orcid":false,"given":"Anton V.","family":"Kuzmin","sequence":"additional","affiliation":[{"name":"Favorsky Irkutsk Institute of Chemistry SB RAS  Irkutsk Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Haoyu","family":"Zhao","sequence":"additional","affiliation":[{"name":"School of Physics and Technology Wuhan University  Wuhan Hubei People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhenglin","family":"Jia","sequence":"additional","affiliation":[{"name":"School of Physics and Technology Wuhan University  Wuhan Hubei People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Marianna I.","family":"Rakhmanova","sequence":"additional","affiliation":[{"name":"Nikolaev Institute of Inorganic Chemistry SB RAS  Novosibirsk Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Taisiya S.","family":"Sukhikh","sequence":"additional","affiliation":[{"name":"Nikolaev Institute of Inorganic Chemistry SB RAS  Novosibirsk Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Konstantin Yu","family":"Zhizhin","sequence":"additional","affiliation":[{"name":"Kurnakov Institute of General and Inorganic Chemistry RAS  Moscow Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Konstantin A.","family":"Brylev","sequence":"additional","affiliation":[{"name":"Nikolaev Institute of Inorganic Chemistry SB RAS  Novosibirsk Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1766-173X","authenticated-orcid":false,"given":"Anastasiya A.","family":"Globa","sequence":"additional","affiliation":[{"name":"Institute of Physiologically Active Compounds of the FSBIS of the Federal Research Center for Problems of Chemical Physics and Medicinal Chemistry of the RAS  Chernogolovka Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dmitriy N.","family":"Polovyanenko","sequence":"additional","affiliation":[{"name":"Vorozhtsov Institute of Organic Chemistry SB RAS  Novosibirsk Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5877-359X","authenticated-orcid":false,"given":"Hong","family":"Meng","sequence":"additional","affiliation":[{"name":"School of Advanced Materials, Peking University Shenzhen Graduate School Peking University  Shenzhen People's Republic of China"},{"name":"Henan Institute of FlexibleElectronics (HIFE) Henan University  Zhengzhou People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6144-1761","authenticated-orcid":false,"given":"Qianqian","family":"Lin","sequence":"additional","affiliation":[{"name":"School of Physics and Technology Wuhan University  Wuhan Hubei People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1389-7078","authenticated-orcid":false,"given":"Alexander V.","family":"Artem'ev","sequence":"additional","affiliation":[{"name":"Nikolaev Institute of Inorganic Chemistry SB RAS  Novosibirsk Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,9,1]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"crossref","first-page":"657","DOI":"10.1021\/ed081p657","article-title":"Boron Clusters Come of Age","volume":"81","author":"Grimes R. 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