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Here, we develop a solvation\u2010engineered hybrid electrolyte comprising 3\u00a0M Zn(OTf)\n                    <jats:sub>2<\/jats:sub>\n                    in water, methanol, and dimethyl sulfoxide (3:1:1, v\/v\/v). Methanol disrupts the hydrogen\u2010bond network, while DMSO stabilizes Zn\n                    <jats:sup>2+<\/jats:sup>\n                    coordination, collectively forming a unique solvation structure as confirmed by isothermal titration calorimetry, density functional theory, and Raman spectroscopy. This environment promotes preferential triflate anion decomposition, yielding an in situ fluorine\u2010rich solid electrolyte interphase (SEI) that passivates zinc, reduces water activity, and suppresses hydrogen evolution. As a result, Zn||Zn cells cycle stably for over 4000 h at 0.5\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    , Zn||Cu cells achieve 99.8% coulombic efficiency over 2000 cycles, and Zn||MnO\n                    <jats:sub>2<\/jats:sub>\n                    cells deliver &gt;\u00a0150 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 1C with sustained cathode stability. This work demonstrates a simple, scalable solvation\u2010engineering strategy that stabilizes zinc interfaces without complex additives or highly concentrated electrolytes, advancing the practical deployment of aqueous ZMBs.\n                  <\/jats:p>","DOI":"10.1002\/smll.75649","type":"journal-article","created":{"date-parts":[[2026,9,12]],"date-time":"2026-09-12T06:51:06Z","timestamp":1789195866000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Tailoring Zn\n                    <sup>2+<\/sup>\n                    Solvation for Dendrite\u2010Free and High\u2010Efficiency Aqueous Zinc Batteries"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-7704-0498","authenticated-orcid":false,"given":"Siyanand Kumar","family":"Chaudhary","sequence":"first","affiliation":[{"name":"Nano\u2010electrochemistry Laboratory Department of Chemical Engineering National Taiwan University of Science and 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