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Confining Li deposition from one\u2010dimensional dendritic to three\u2010dimensional spherical growth is an effective solution. Herein, we propose a synergistic strategy catalyzed by Li\u2010Au alloy nucleation sites to generate a LiF\u2010rich solid electrolyte interphase layer. This achieves low Li nucleation potential and high interfacial ion transport kinetics, making Li deposition reaction\u2010controlled (leading to spherical Li) instead of diffusion\u2010controlled processes (leading to dendritic Li). Symmetric cells with the modified Li electrode cycle nearly 7500\u00a0h (18,000 cycles) at 10\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    . LiFePO\n                    <jats:sub>4<\/jats:sub>\n                    (LFP) full cells retains 80.3% of their initial capacity after 1000 cycles at 2C; LiCoO\n                    <jats:sub>2<\/jats:sub>\n                    full cells demonstrated a capacity of 153 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at an ultra\u2010high 40C (7.3\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    ) rate. Even at a low N:P ratio of 1.4, the LFP full cell can still be stably cycled for over 200 cycles at 1C (1.8\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    ) while delivering a high capacity of 151.5 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    . This scalable interfacial design strategy provides important insights for the preparation of dendrite\u2010free Li anodes to improve battery safety.\n                  <\/jats:p>","DOI":"10.1002\/smll.75683","type":"journal-article","created":{"date-parts":[[2026,9,11]],"date-time":"2026-09-11T09:56:52Z","timestamp":1789120612000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Fast Li Ion Flux LiF\u2010Rich SEI Inducing Spatially\u2010Confined Deposition for Dendrite\u2010Free Li Metal Anode"],"prefix":"10.1002","author":[{"given":"Huifeng","family":"Zhuang","sequence":"first","affiliation":[{"name":"State Key Laboratory of New Ceramic Materials School of Materials Science and Engineering Tsinghua University  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rongchuan","family":"Cao","sequence":"additional","affiliation":[{"name":"State Key Laboratory of New Ceramic Materials School of 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