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Controlling such adaptability of metal\u2010oxide\u2010based catalysts is crucial yet challenging for understanding catalyst dynamics and enabling rational catalyst design. Here, we report a dislocation\u2010mediated strategy to steer the dynamic evolution of vanadium oxides by systematically tuning the lattice dislocation density of TiO\n                    <jats:sub>2<\/jats:sub>\n                    supports. A combination of in situ Raman and DRIFTS reveals that in response to reaction conditions, dislocations of TiO\n                    <jats:sub>2<\/jats:sub>\n                    enable the depolymerization of crystalline V\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>5<\/jats:sub>\n                    into polymeric VO\n                    <jats:sub>x<\/jats:sub>\n                    species while simultaneously inducing charge redistribution through strong V\u2500O\u2500Ti interfacial polarization. Those polymeric, electrophilic VO\n                    <jats:sub>x<\/jats:sub>\n                    centers exhibit enhanced C\u2500H activation ability, boosting selective oxidation of ethane to acetic acid via the Mars\u2013van Krevelen mechanism. These findings provide a conceptual framework linking dislocation\u2010induced lattice dynamics to catalytic function and highlight the potential of dislocation engineering as a feasible strategy for designing adaptive catalytic systems with tunable redox properties and structural resilience under operating conditions.\n                  <\/jats:p>","DOI":"10.1002\/smll.75696","type":"journal-article","created":{"date-parts":[[2026,9,9]],"date-time":"2026-09-09T13:21:46Z","timestamp":1788960106000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Dislocation Engineering Steers Reaction\u2010Induced Reconstruction of Vanadium Oxides for Selective Oxidation of Ethane"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-8328-5483","authenticated-orcid":false,"given":"Zhenchao","family":"Xu","sequence":"first","affiliation":[{"name":"State Key Laboratory of Low Carbon Catalysis and Carbon Dioxide Utilization, Shanghai Advanced Research Institute Chinese Academy of Sciences  Shanghai People's Republic of China"},{"name":"University of Chinese Academy of Sciences  Beijing People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Haoxu","family":"Chang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Low Carbon Catalysis and Carbon Dioxide Utilization, Shanghai Advanced Research Institute Chinese Academy of Sciences  Shanghai People's Republic of China"},{"name":"University of Chinese Academy of Sciences  Beijing People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yihai","family":"Wu","sequence":"additional","affiliation":[{"name":"Gaolu Air Products and Chemicals (Shanghai) Energy Technology Co., Ltd.  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