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However, it holds huge challenges for the practical application of conventional nickel\u2010based catalysts under industrial\u2010level current density. Herein, the amorphous\/crystalline heterostructured oxygen vacancy\u2010rich MnO\n                    <jats:sub>x<\/jats:sub>\n                    \/Ni\n                    <jats:sub>9<\/jats:sub>\n                    S\n                    <jats:sub>8<\/jats:sub>\n                    nanoarrays induced by lattice oxygen leaching are constructed for efficient methanol oxidation reaction (MOR). The MnO\n                    <jats:sub>x<\/jats:sub>\n                    \/Ni\n                    <jats:sub>9<\/jats:sub>\n                    S\n                    <jats:sub>8<\/jats:sub>\n                    exhibits an extremely low potential of 1.55\u00a0V (vs. RHE) at an industrial\u2010grade current density of 1 A cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    , together with a 96.76% Faradaic efficiency of formate. A membrane\u2010free MnO\n                    <jats:sub>x<\/jats:sub>\n                    \/Ni\n                    <jats:sub>9<\/jats:sub>\n                    S\n                    <jats:sub>8<\/jats:sub>\n                    || MnO\n                    <jats:sub>x<\/jats:sub>\n                    \/Ni\n                    <jats:sub>9<\/jats:sub>\n                    S\n                    <jats:sub>8<\/jats:sub>\n                    cell for MOR || HER delivers electrocatalytic activity that requires merely a cell voltage of 1.57\u00a0V for 100\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    , yielding a 95.66% Faradaic efficiency while maintaining continuous electrolysis for 150\u00a0h. The systematic studies manifest that the coupling of amorphous\/crystalline interfaces and numerous oxygen vacancies not only modulates electron distribution and accelerates the generation of active sites Ni\n                    <jats:sup>III<\/jats:sup>\n                    \u2010OOH, but also enhances the adsorption capacity for OH\n                    <jats:sup>\u2212<\/jats:sup>\n                    and methanol, thereby boosting overall performance. This work demonstrates an efficient lattice oxygen leaching\u2010induced strategy for industrial\u2010level methanol electro\u2010reforming to formate, providing a new prototype for valorization of biomass into high\u2010value chemicals and production of hydrogen energy.\n                  <\/jats:p>","DOI":"10.1002\/smll.75755","type":"journal-article","created":{"date-parts":[[2026,9,15]],"date-time":"2026-09-15T08:49:44Z","timestamp":1789462184000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Lattice Oxygen Leaching Induced Amorphous\/Crystalline Heterostructured MnO\n                    <sub>x<\/sub>\n                    \/Ni\n                    <sub>9<\/sub>\n                    S\n                    <sub>8<\/sub>\n                    Nanoarrays Construction for Efficient Methanol Electro\u2010Reforming at Large Current 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China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8466-1196","authenticated-orcid":false,"given":"Xia","family":"Tao","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Organic\u2010Inorganic Composites College of Chemical Engineering Beijing University of Chemical Technology  Beijing People's Republic of 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