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To this end, a liquid\u2010phase synthesis approach combined with an electrochemical technique is proposed to in situ construct a robust LiF\u2010rich interphase on the Si\/C surface. Both the functional interphase and pre\u2010designed void within the carbon layer induce a stable LiF\u2010rich solid electrolyte interface (SEI) through their synergistic management of anisotropic stress evolution, significantly increasing interfacial mechanical strength, suppressing electrode polarization and electron leakage into the electrolyte, and achieving superior interface stability. Fatigue resistance, theoretical simulations, and electrode surface analyses reveal that stress concentration and catastrophic strain localization are effectively restrained, causing an intact interface and reduced energy barriers for Li\n                    <jats:sup>+<\/jats:sup>\n                    de\u2010solvation and diffusion. The dQ\/dV curves and voltage drop analysis disclose a more reversible phase transition process for Li\n                    <jats:sub>15<\/jats:sub>\n                    Si\n                    <jats:sub>4<\/jats:sub>\n                    in the optimal electrode upon cycling. These factors are collectively attributed to the homogeneous stress distribution. Therefore, the optimized electrode delivers outstanding electrochemical robustness, achieving 96.5% capacity retention after 1000 cycles at 4\u00a0A\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    and a rate capacity of 589.5\u00a0mAh\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 6\u00a0A\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    . The proposed strategy, homogenizing stress distribution, offers a novel paradigm for constructing a stable SEI on electrodes undergoing severe volume fluctuations.\n                  <\/jats:p>","DOI":"10.1002\/smll.75780","type":"journal-article","created":{"date-parts":[[2026,9,16]],"date-time":"2026-09-16T11:52:30Z","timestamp":1789559550000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Homogenizing Stress Distribution to Construct a Stable LiF\u2010rich Solid Electrolyte Interphase in Silicon\/Carbon Anodes"],"prefix":"10.1002","author":[{"given":"Xiaoli","family":"Yang","sequence":"first","affiliation":[{"name":"Institute of Advanced Electrochemical Energy &amp; School of Materials Science and Engineering Xi'an University of Technology  Xi'an Shaanxi People's Republic of China"},{"name":"Shaanxi Engineering Research Center of Key Materials For Lithium\/Sodium\u2010ion Batteries  Xi'an Shaanxi People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ming","family":"Li","sequence":"additional","affiliation":[{"name":"Institute of Advanced Electrochemical Energy &amp; 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