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However, their practical application is limited by insufficient energy efficiency and cycle stability, with the primary bottleneck being the slow kinetics of the oxygen evolution reaction (OER) at the positive electrode. To enhance the energy efficiency and cycle life of ZABs, a highly promising strategy is the development of hybrid ZAB (HZAB) systems, which replace the slow OER with the highly efficient oxidation reactions of small molecules. This review systematically summarizes HZABs utilizing the low\u2010overpotential oxidation reactions of urea, iodine, and ethanol. It focuses on the catalytic challenges faced by HZABs and their solutions, while also exploring the potential shuttle effect of small molecules and innovative battery structure designs. Additionally, the paper analyzes the economic feasibility of integrating HZABs with clean energy sources for waste treatment and the production of high\u2010value\u2010added chemicals. Finally, we outline solutions to current and future challenges in the HZABs field and highlight emerging research trends.<\/jats:p>","DOI":"10.1002\/smll.75789","type":"journal-article","created":{"date-parts":[[2026,10,1]],"date-time":"2026-10-01T07:33:37Z","timestamp":1790840017000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Advanced Materials and Architecture Design for Efficient Hybrid Zinc\u2010Air Batteries"],"prefix":"10.1002","author":[{"given":"Yuhang","family":"Tu","sequence":"first","affiliation":[{"name":"School of Microelectronics Shanghai University  Shanghai People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chang","family":"Wang","sequence":"additional","affiliation":[{"name":"School of Microelectronics Shanghai University  Shanghai People's Republic of 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