{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,16]],"date-time":"2026-09-16T12:02:26Z","timestamp":1789560146413,"version":"build-2803163510"},"reference-count":51,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,9,16]],"date-time":"2026-09-16T00:00:00Z","timestamp":1789516800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,9,16]],"date-time":"2026-09-16T00:00:00Z","timestamp":1789516800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52676150"],"award-info":[{"award-number":["52676150"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52674126"],"award-info":[{"award-number":["52674126"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52304098"],"award-info":[{"award-number":["52304098"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>Angstrom\u2010confined water in porous scaffolds is sensitive to interfacial electrostatics, yet cross\u2010material predictability is limited because pore geometry and surface chemistry change simultaneously. This work introduces Surface\u2010Charge\u2010Regulated Porous Water (SCR\u2010PW) as a tunable functional microenvironment where framework charge serves as a deterministic parameter to modulate hydration under fixed topology. By utilizing MFI\u2010type ZSM\u20105 zeolites (\u223c5.5 \u00c5), a continuous gradient of negative framework charge is established by systematically narrowing the Si\/Al ratio. This intensified interfacial electrostatic environment induces pronounced spatial layering and orientational polarization of interfacial water, producing a dynamically persistent, surface\u2010organized hydration state distinct from bulk\u2010like water. Such electrostatic constraint reshapes the phase\u2010transition free\u2010energy landscape, lowering the nucleation barrier by reducing the required structural rearrangement independent of geometric confinement. Experimental data confirm that SCR\u2010PW facilitate gas\u2010liquid mass transfer compared to bulk water. In representative phase transformations, SCR\u2010PW accelerate transition kinetics by curtailing induction times and enhancing conversion, while maintaining invariant equilibrium features. In\u2010situ neutron diffraction reveals that increased framework charge stabilizes the hydrogen\u2010bonded host lattice by suppressing molecular thermal motion. This study provides an MFI\u2010based proof of concept for regulating confined\u2010water phase behavior through framework\u2010charge engineering for creating intelligent porous aqueous microenvironments to regulate phase behavior and selective mass transport.<\/jats:p>","DOI":"10.1002\/smll.75793","type":"journal-article","created":{"date-parts":[[2026,9,16]],"date-time":"2026-09-16T11:04:31Z","timestamp":1789556671000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Surface\u2010Charge\u2010Regulated Porous Water for Interfacial Phase\u2010Transition Control"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-2323-3048","authenticated-orcid":false,"given":"Ying","family":"Teng","sequence":"first","affiliation":[{"name":"State Key Laboratory of Intelligent Construction and Healthy Operation and Maintenance of Deep Underground Engineering Institute of Deep Earth Sciences and Green Energy College of Civil and Transportation Engineering Shenzhen University  Shenzhen China"},{"name":"Advanced Institute for Ocean Research Department of Physics Institute of Major Scientific Facilities for New Materials Southern University of Science and Technology  Shenzhen China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhao","family":"Liang","sequence":"additional","affiliation":[{"name":"Advanced Institute for Ocean Research Department of Physics Institute of Major Scientific Facilities for New Materials Southern University of Science and Technology  Shenzhen China"},{"name":"College of Electromechanical Engineering Qingdao University of Science and Technology  Qingdao China"},{"name":"School of Petroleum Engineering China University of Petroleum (East China)  Qingdao 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Science and Technology  Qingdao China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7314-8394","authenticated-orcid":false,"given":"Jinlong","family":"Zhu","sequence":"additional","affiliation":[{"name":"Advanced Institute for Ocean Research Department of Physics Institute of Major Scientific Facilities for New Materials Southern University of Science and Technology  Shenzhen China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7552-5317","authenticated-orcid":false,"given":"Songbai","family":"Han","sequence":"additional","affiliation":[{"name":"Advanced Institute for Ocean Research Department of Physics Institute of Major Scientific Facilities for New Materials Southern University of Science and Technology  Shenzhen 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China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Huaican","family":"Chen","sequence":"additional","affiliation":[{"name":"Spallation Neutron Source Science Center  Dongguan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xi","family":"Chen","sequence":"additional","affiliation":[{"name":"Wu Jieh Yee School of Interdisciplinary Studies Lingnan University  Hong Kong China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dan","family":"Liu","sequence":"additional","affiliation":[{"name":"Research Center for Eco\u2010Environmental Engineering School of Materials Science and Engineering Dongguan University of Technology  Dongguan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1084-4023","authenticated-orcid":false,"given":"Changping","family":"Li","sequence":"additional","affiliation":[{"name":"Research Center for Eco\u2010Environmental Engineering School of Materials Science and Engineering Dongguan University of Technology  Dongguan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Heping","family":"Xie","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Intelligent Construction and Healthy Operation and Maintenance of Deep Underground Engineering Institute of Deep Earth Sciences and Green Energy College of Civil and Transportation Engineering Shenzhen University  Shenzhen 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