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Here, we propose a strategy for designing a nano\u2010gradient solid\u2010state super\u2010slippery (NSS) coating, with a nanoscale through\u2010thickness compositional gradient, applicable to substrates of different roughness levels and materials, as fabricated via plasma\u2010enhanced chemical vapor deposition, to enable highly\u2010efficient dropwise condensation. Enabled by the low thermal resistance (only \u223c300\u00a0nm thick in total), high droplet shedding frequency, and small initial sliding diameter, we achieve a stable 20% higher condensation heat transfer coefficient (HTC) on the NSS surface than that on a superhydrophobic surface over a wide subcooling range from 2 to 8 K, and a &gt;100% HTC enhancement compared to that of filmwise condensation on a hydrophilic surface. With the nano\u2010gradient functional design, the NSS surface also exhibits ultra\u2010high thermal and mechanical durability under harsh conditions, surviving rigorous heating tests with only a 20% HTC deterioration after being heated at 250\u00b0C for 240 h, and maintains stable condensation performance over a 2\u2010month continuous test. This facile yet effective strategy enables ultra\u2010durable high\u2010performance dropwise condensation heat transfer for industrial applications.<\/jats:p>","DOI":"10.1002\/smll.75810","type":"journal-article","created":{"date-parts":[[2026,9,21]],"date-time":"2026-09-21T15:16:16Z","timestamp":1790003776000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Ultra\u2010Durable High\u2010Performance Dropwise Condensation Heat Transfer Enabled by a Solid\u2010State Super\u2010Slippery Surface With Nanoscale Through\u2010Thickness Compositional Gradient"],"prefix":"10.1002","author":[{"given":"Yu\u2010Chen","family":"Zhang","sequence":"first","affiliation":[{"name":"State Key Laboratory of Clean Energy Utilization Zhejiang University  Hangzhou China"},{"name":"Institute of Thermal Science and Power Systems School of Energy Engineering Zhejiang University  Hangzhou 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