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However, the low electrochemical potential of lithiated phases in lithium\u2013silicon alloys drives spontaneous electrolyte reduction, resulting in interfacial instability. Herein, a high\u2010performance silicon composite anode assembled with a Li\n                    <jats:sub>4<\/jats:sub>\n                    (BH\n                    <jats:sub>4<\/jats:sub>\n                    )\n                    <jats:sub>3<\/jats:sub>\n                    I hydride electrolyte is developed. Prelithiation compensates for initial irreversible lithium consumption, while the combination of the Li\n                    <jats:sub>22<\/jats:sub>\n                    Si\n                    <jats:sub>5<\/jats:sub>\n                    alloy and hydride electrolyte suppresses interfacial degradation, enabling an initial Coulombic efficiency of 99.6%. In silicon\u2013sulfur full cells, the opposite volume changes of the Li\n                    <jats:sub>22<\/jats:sub>\n                    Si\n                    <jats:sub>5<\/jats:sub>\n                    anode and sulfur cathode dynamically compensate for stress evolution during cycling and maintain intimate interfacial contact and structural integrity, enabling this configuration to deliver an ultra\u2010high areal capacity of 23.88 mAh cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    and retain 63.2% of its capacity after 1000 cycles, without observable cracking or structural degradation. These results provide an effective interfacial and structural design strategy for high\u2010performance silicon\u2010based anodes in all\u2010solid\u2010state batteries.\n                  <\/jats:p>","DOI":"10.1002\/smll.75828","type":"journal-article","created":{"date-parts":[[2026,9,23]],"date-time":"2026-09-23T11:26:48Z","timestamp":1790162808000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["High\u2010Performance All\u2010Solid\u2010State Silicon\u2013Sulfur Batteries Enabled by Li\n                    <sub>4<\/sub>\n                    (BH\n                    <sub>4<\/sub>\n                    )\n                    <sub>3<\/sub>\n                    I Hydride Electrolyte"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0009-0007-2897-7349","authenticated-orcid":false,"given":"Tao","family":"Huang","sequence":"first","affiliation":[{"name":"Graduate School of Advanced Science and Engineering Hiroshima University  Hiroshima Japan"},{"name":"Baima Lake Laboratory  Hangzhou Zhejiang China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhaotong","family":"Hu","sequence":"additional","affiliation":[{"name":"College of Materials Science and Technology Nanjing University of Aeronautics and Astronautics  Nanjing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yifei","family":"Shao","sequence":"additional","affiliation":[{"name":"Graduate School of Innovation and Practice for Smart Society Hiroshima University  Hiroshima Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiang","family":"Zhang","sequence":"additional","affiliation":[{"name":"Baima Lake Laboratory  Hangzhou Zhejiang China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Caiting","family":"Yuan","sequence":"additional","affiliation":[{"name":"College of Materials Science and Technology Nanjing University of Aeronautics and Astronautics  Nanjing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhanning","family":"Wu","sequence":"additional","affiliation":[{"name":"College of Materials Science and Technology Nanjing University of Aeronautics and Astronautics  Nanjing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Takayuki","family":"Ichikawa","sequence":"additional","affiliation":[{"name":"Graduate School of Advanced Science and Engineering Hiroshima University  Hiroshima Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8064-1470","authenticated-orcid":false,"given":"Fangqin","family":"Guo","sequence":"additional","affiliation":[{"name":"Graduate School of Advanced Science and Engineering Hiroshima University  Hiroshima Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9576-1093","authenticated-orcid":false,"given":"Tengfei","family":"Zhang","sequence":"additional","affiliation":[{"name":"Baima Lake Laboratory  Hangzhou Zhejiang China"},{"name":"College of Materials Science and Technology Nanjing University of Aeronautics and Astronautics  Nanjing China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,9,23]]},"reference":[{"key":"e_1_2_9_2_1","doi-asserted-by":"publisher","DOI":"10.1080\/10408436.2021.1886045"},{"key":"e_1_2_9_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202003666"},{"key":"e_1_2_9_4_1","doi-asserted-by":"crossref","DOI":"10.1016\/j.cej.2022.139923","article-title":"Advances in sulfide\u2010based all\u2010solid\u2010state lithium\u2010sulfur battery: Materials, composite electrodes and electrochemo\u2010mechanical effects","volume":"454","author":"Gu J.","year":"2023","journal-title":"Chemical Engineering Journal"},{"key":"e_1_2_9_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2020.01.002"},{"key":"e_1_2_9_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.8b19354"},{"key":"e_1_2_9_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201301795"},{"key":"e_1_2_9_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2019.06.024"},{"key":"e_1_2_9_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2023.102875"},{"key":"e_1_2_9_10_1","doi-asserted-by":"crossref","first-page":"217","DOI":"10.1016\/j.ensm.2019.10.012","article-title":"A safe and efficient lithiated silicon\u2010sulfur battery enabled by a bi\u2010functional composite interlayer","volume":"25","author":"Ren Y. 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