{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,21]],"date-time":"2026-09-21T16:02:10Z","timestamp":1790006530649,"version":"4.0.1"},"reference-count":45,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,9,21]],"date-time":"2026-09-21T00:00:00Z","timestamp":1789948800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,9,21]],"date-time":"2026-09-21T00:00:00Z","timestamp":1789948800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100002367","name":"Chinese Academy of Sciences","doi-asserted-by":"publisher","award":["123GJHZ2022055MI"],"award-info":[{"award-number":["123GJHZ2022055MI"]}],"id":[{"id":"10.13039\/501100002367","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012226","name":"Fundamental Research Funds for the Central Universities","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100012226","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100009076","name":"University of Science and Technology of China","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100009076","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Optimizing adsorption thermodynamics inevitably introduces deep\u2010level defects that aggravate carrier recombination, making it challenging to simultaneously regulate surface reaction thermodynamics and suppress recombination kinetics within a single catalytic system. Herein, we develop a CoNiP\u2010modified TiO\n                    <jats:sub>2<\/jats:sub>\n                    magnetic composite photocatalyst (CoNiP@TiO\n                    <jats:sub>2<\/jats:sub>\n                    ), employing a strategy that combines intrinsic electronic structure regulation with an external magnetic field to address this issue. The electronic interaction between Co and Ni modulates the d\u2010band centers, reduces the reaction barriers, and improves H* adsorption\/desorption thermodynamics. Simultaneously, the applied magnetic field promotes photogenerated charge separation and interfacial charge transfer while suppressing carrier recombination. As a result, this synergistic mechanism yields an ultrahigh hydrogen evolution rate of 5041.30\u00a0\u00b5mol\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u00a0h\n                    <jats:sup>\u22121<\/jats:sup>\n                    , nearly an order of magnitude higher than that under non\u2010magnetic conditions. Our findings provide compelling evidence that coupling intrinsic electronic\u2010structure modulation with external magnetic field regulation enables the decoupling and synergistic optimization of surface reaction thermodynamics and charge transport kinetics in CoNiP@TiO\n                    <jats:sub>2<\/jats:sub>\n                    .\n                  <\/jats:p>","DOI":"10.1002\/smll.75838","type":"journal-article","created":{"date-parts":[[2026,9,21]],"date-time":"2026-09-21T15:12:31Z","timestamp":1790003551000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Synergizing Electronic\u2010Structure Modulation With Magnetic\u2010Field\u2010Assisted Charge Dynamics for Enhanced Photocatalytic Hydrogen Evolution"],"prefix":"10.1002","author":[{"given":"Linyi","family":"Wu","sequence":"first","affiliation":[{"name":"Department of Thermal Science and Energy Engineering University of Science and Technology of China  Hefei People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiale","family":"He","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Inorganic Synthesis and Preparative Chemistry College of Chemistry International Center of Future Science Jilin University  Changchun People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qingxian","family":"Wu","sequence":"additional","affiliation":[{"name":"Department of Thermal Science and Energy Engineering University of Science and Technology of China  Hefei People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0000-0605-6900","authenticated-orcid":false,"given":"Guiqiang","family":"Li","sequence":"additional","affiliation":[{"name":"Department of Thermal Science and Energy Engineering University of Science and Technology of China  Hefei People's Republic of 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