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However, the commercial application of Li\u2010rich cathodes is significantly hindered by the irreversible release of oxygen and severe voltage and capacity decay. Herein, a synergistic modification strategy is proposed that effectively achieves the simultaneous construction of oxygen vacancies, spinel phase structures, and a TiF\n                    <jats:sub>4<\/jats:sub>\n                    coating. This synergistic interface reconstruction not only synergistically stabilizes the localized O\n                    <jats:sub>2<\/jats:sub>\n                    <jats:sup>n\u2212<\/jats:sup>\n                    and reduces the interfacial side reaction, but also constructs a 3D channel for Li\n                    <jats:sup>+<\/jats:sup>\n                    ion diffusion to enhance rate performance. The modified cathode demonstrates an outstanding discharge capacity of 269.3 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 0.1 C, with nearly unchanged capacity after 300 cycles at 1 C. Moreover, the capacity retention remains as high as 96% after 200 cycles at both 2 C and 5 C. This work offers valuable new insights into enhancing the comprehensive electrochemical performance of Li\u2010rich layered oxides.\n                  <\/jats:p>","DOI":"10.1002\/smll.75842","type":"journal-article","created":{"date-parts":[[2026,10,14]],"date-time":"2026-10-14T09:55:17Z","timestamp":1791971717000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Stabilizing the Localized O\n                    <sub>2<\/sub>\n                    <sup>n\u2212<\/sup>\n                    for Enhanced Cycling Stability in Li\u2010Rich Cathodes"],"prefix":"10.1002","author":[{"given":"Shuli","family":"Zheng","sequence":"first","affiliation":[{"name":"School of Chemical Engineering Sichuan University  Chengdu People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qi","family":"Pang","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering Sichuan University  Chengdu People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhiwei","family":"Yang","sequence":"additional","affiliation":[{"name":"Weichai Power Co., Ltd  Weifang People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0005-3247-3843","authenticated-orcid":false,"given":"Lang","family":"Qiu","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering Sichuan University  Chengdu People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mengke","family":"Zhang","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering Sichuan University  Chengdu People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0004-0905-378X","authenticated-orcid":false,"given":"Fang","family":"Wan","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering 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