{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,14]],"date-time":"2026-10-14T13:46:14Z","timestamp":1791985574017,"version":"4.4.0"},"reference-count":66,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,10,14]],"date-time":"2026-10-14T00:00:00Z","timestamp":1791936000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,10,14]],"date-time":"2026-10-14T00:00:00Z","timestamp":1791936000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22275170"],"award-info":[{"award-number":["22275170"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>To address the balance between reactivity and safety in nano\u2010HNS, this study presents a green composite molding strategy that facilitates the self\u2010assembly of nano\u2010HNS into micro\u2010nano\u2010structured microspheres within confined spaces. This approach utilizes confined spaces to precisely control the morphology and size of the resultant microspheres. The effects of process parameters on the morphology and size of microspheres were systematically investigated, and the underlying formation mechanisms were elucidated. Comprehensive characterizations encompassing morphology, crystal structure, mechanical sensitivity, thermal behavior, and impact properties were conducted. The results demonstrate that the synthesized HNS microspheres possess high sphericity, an average particle size of 224.2\u00a0\u00b5m, and exhibit favorable fluidity and bulk density. This approach effectively reduces the mechanical sensitivity of the material while preserving the crystal structure and thermal stability of HNS\u2010IV (impact sensitivity: 12 J vs. 20 J; friction sensitivity: 216 N vs. 240 N). Furthermore, it enhances the initial sensitivity to short duration shock, as evidenced by reductions in the 50% and 99.9% initiation voltages by 18\u00a0and 48\u00a0V, respectively. This approach facilitates the synergistic stimulation of selective sensitization and passivation. This methodology is straightforward and applicable, providing a versatile and eco\u2010friendly approach for the multi\u2010structural modification of nano\u2010HNS.<\/jats:p>","DOI":"10.1002\/smll.75857","type":"journal-article","created":{"date-parts":[[2026,10,14]],"date-time":"2026-10-14T12:58:06Z","timestamp":1791982686000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Confined\u2010Space Self\u2010Assembly of Nano\u2010HNS Into Hierarchical Micro\u2010Nano Structured Microspheres for Selective Stimuli Sensitization and Passivation"],"prefix":"10.1002","author":[{"given":"Wenxuan","family":"Liang","sequence":"first","affiliation":[{"name":"School of Environmental and Safety Engineering North University of China  Taiyuan Shanxi China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guoqiang","family":"He","sequence":"additional","affiliation":[{"name":"School of Environmental and Safety Engineering North University of China  Taiyuan Shanxi China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Handong","family":"Shi","sequence":"additional","affiliation":[{"name":"School of Environmental and Safety Engineering North University of China  Taiyuan Shanxi China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wenshuai","family":"Dong","sequence":"additional","affiliation":[{"name":"School of Environmental and Safety Engineering North University of China  Taiyuan Shanxi China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8095-7643","authenticated-orcid":false,"given":"Chongwei","family":"An","sequence":"additional","affiliation":[{"name":"School of Environmental and Safety Engineering North University of China  Taiyuan Shanxi China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,10,14]]},"reference":[{"key":"e_1_2_9_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.msea.2022.143332"},{"key":"e_1_2_9_3_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10853\u2010017\u20100912\u20101"},{"key":"e_1_2_9_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2021.132876"},{"key":"e_1_2_9_5_1","doi-asserted-by":"crossref","DOI":"10.1016\/j.compstruct.2019.111033","article-title":"Lead\u2010Free Piezocomposites With CNT\u2010Modified Matrices: Accounting for Agglomerations and Molecular Defects","volume":"224","author":"Buroni F. C.","year":"2019","journal-title":"Composite Structures"},{"key":"e_1_2_9_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0009\u20102509(00)00355\u20109"},{"key":"e_1_2_9_7_1","doi-asserted-by":"crossref","first-page":"213","DOI":"10.1007\/978-94-024-1201-7_6","volume-title":"Emerging Energetic Materials: Synthesis, Physicochemical, and Detonation Properties","author":"Viswanath D. S.","year":"2018"},{"key":"e_1_2_9_8_1","doi-asserted-by":"publisher","DOI":"10.1017\/S0263034617000854"},{"key":"e_1_2_9_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.fuel.2025.136261"},{"key":"e_1_2_9_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.matdes.2023.111874"},{"key":"e_1_2_9_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.enmf.2023.10.003"},{"key":"e_1_2_9_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.powtec.2025.120814"},{"key":"e_1_2_9_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.partic.2022.10.012"},{"key":"e_1_2_9_14_1","doi-asserted-by":"publisher","DOI":"10.3390\/ijms242216199"},{"key":"e_1_2_9_15_1","doi-asserted-by":"publisher","DOI":"10.34133\/research.0938"},{"key":"e_1_2_9_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202423205"},{"key":"e_1_2_9_17_1","doi-asserted-by":"publisher","DOI":"10.3390\/nano8050336"},{"key":"e_1_2_9_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.dt.2022.05.006"},{"key":"e_1_2_9_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.fuel.2024.132916"},{"key":"e_1_2_9_20_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mtcomm.2025.113088"},{"key":"e_1_2_9_21_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.powtec.2025.121033"},{"key":"e_1_2_9_22_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2023.146842"},{"key":"e_1_2_9_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/asia.201801884"},{"key":"e_1_2_9_24_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.vacuum.2019.108881"},{"key":"e_1_2_9_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.5c00425"},{"key":"e_1_2_9_26_1","doi-asserted-by":"crossref","DOI":"10.1016\/j.cej.2023.147110","article-title":"Towards More Predictive Correlations for Conjugated Mass Transfer Across a Droplet Interface","volume":"478","author":"God\u00e9 H.","year":"2023","journal-title":"Chemical Engineering Journal"},{"key":"e_1_2_9_27_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.87.098304"},{"key":"e_1_2_9_28_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cis.2021.102393"},{"key":"e_1_2_9_29_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.dt.2021.11.004"},{"key":"e_1_2_9_30_1","doi-asserted-by":"publisher","DOI":"10.1039\/D6CE00064A"},{"key":"e_1_2_9_31_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mtcomm.2024.110874"},{"key":"e_1_2_9_32_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2024.154865"},{"key":"e_1_2_9_33_1","doi-asserted-by":"publisher","DOI":"10.3390\/molecules28114478"},{"key":"e_1_2_9_34_1","first-page":"1231","article-title":"Synergy of Activating Substrate and Introducing C\u2010H\u00b7\u00b7\u00b7O Interaction to Achieve Rh2(II)\u2010Catalyzed Asymmetric Cycloisomerization of 1,n\u2010enynes","volume":"63","author":"Wu R.","year":"2020","journal-title":"Science China: Chemistry"},{"key":"e_1_2_9_35_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2022.136539"},{"key":"e_1_2_9_36_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jssc.2026.126204"},{"key":"e_1_2_9_37_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.langmuir.9b00811"},{"key":"e_1_2_9_38_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.langmuir.7b02925"},{"key":"e_1_2_9_39_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.201804523"},{"key":"e_1_2_9_40_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.langmuir.5b04116"},{"key":"e_1_2_9_41_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.201701658"},{"key":"e_1_2_9_42_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41565\u2010023\u201001355\u2010w"},{"key":"e_1_2_9_43_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms15882"},{"key":"e_1_2_9_44_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.langmuir.7b03578"},{"key":"e_1_2_9_45_1","doi-asserted-by":"publisher","DOI":"10.1021\/la035884p"},{"key":"e_1_2_9_46_1","doi-asserted-by":"crossref","first-page":"7472","DOI":"10.1039\/c3ra23358h","article-title":"Microbelts and Flower\u2010Like Particles of Hexakis\u2010(4\u2010(5\u2010styryl\u20101,3,4\u2010oxazodiazol\u20102\u2010yl)\u2010phenoxy)\u2010cyclotriphosphazene: Self\u2010Assembly and Photoreaction","volume":"3","author":"Liu S.\u2010Z.","year":"2013","journal-title":"RSC Advances"},{"key":"e_1_2_9_47_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0001\u20108686(01)00050\u20101"},{"key":"e_1_2_9_48_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.powtec.2020.03.028"},{"key":"e_1_2_9_49_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ijpharm.2004.05.001"},{"key":"e_1_2_9_50_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.renene.2015.08.011"},{"key":"e_1_2_9_51_1","doi-asserted-by":"publisher","DOI":"10.1063\/5.0208981"},{"key":"e_1_2_9_52_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8RA07650B"},{"key":"e_1_2_9_53_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ceramint.2018.06.148"},{"key":"e_1_2_9_54_1","doi-asserted-by":"publisher","DOI":"10.1016\/0040\u20106031(92)80292\u20105"},{"key":"e_1_2_9_55_1","doi-asserted-by":"publisher","DOI":"10.1002\/prep.202400079"},{"key":"e_1_2_9_56_1","doi-asserted-by":"publisher","DOI":"10.1016\/0094\u20105765(79)90032\u20108"},{"key":"e_1_2_9_57_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.869941"},{"key":"e_1_2_9_58_1","doi-asserted-by":"publisher","DOI":"10.1063\/5.0251108"},{"key":"e_1_2_9_59_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.carbon.2018.02.022"},{"key":"e_1_2_9_60_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.matchemphys.2020.123700"},{"key":"e_1_2_9_61_1","doi-asserted-by":"publisher","DOI":"10.3390\/ijms27072955"},{"key":"e_1_2_9_62_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jallcom.2024.177839"},{"key":"e_1_2_9_63_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2026.176600"},{"key":"e_1_2_9_64_1","doi-asserted-by":"publisher","DOI":"10.1002\/prep.201800008"},{"key":"e_1_2_9_65_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.partic.2022.10.012"},{"key":"e_1_2_9_66_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2024.154865"},{"key":"e_1_2_9_67_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.fuel.2024.132916"}],"container-title":["Small"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/smll.75857","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/smll.75857","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/smll.75857","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,10,14]],"date-time":"2026-10-14T12:58:07Z","timestamp":1791982687000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/smll.75857"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,10,14]]},"references-count":66,"alternative-id":["10.1002\/smll.75857"],"URL":"https:\/\/doi.org\/10.1002\/smll.75857","archive":["Portico"],"relation":{},"ISSN":["1613-6810","1613-6829"],"issn-type":[{"value":"1613-6810","type":"print"},{"value":"1613-6829","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,10,14]]},"assertion":[{"value":"2026-07-03","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-09-11","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-10-14","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e75857"}}