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Boron\u2010 and nitrogen\u2010regulated carbon nitride (BCN) was designed as a multifunctional \u201cinterfacial bridge\u201d to assemble HMX with metastable intermolecular composite (MIC) sensitizers, constructing an activatable HMX\u2010BCN\u2010MIC heterointerface. B\/N\u2010regulated heptazine framework reinforces dielectric polarization, charge transport, and hydrogen\u2010bonding interactions through defect\u2010rich grain boundaries, conductive microchannels, and abundant cyanogroup (\u2500C\u2261N) sites. BCN exhibits a 45% increase in apparent carrier density, a 20.3% decrease in charge\u2010transfer resistance, and a 10.3% increase in dielectric loss (\n                    <jats:italic>\u03b5<\/jats:italic>\n                    \u2033) compared with pristine CN. Meanwhile, BCN\u2010mediated heterointerfaces reduce the activation energy of rate\u2010determining step in HMX decomposition by 22.8% through active B\u2010doped sites and multiple NO\n                    <jats:sub>x<\/jats:sub>\n                    conversion pathways. The reinforced hydrogen\u2011bonding network further stabilizes the HMX\u2011BCN\u2011MIC heterointerface, which serves as an electron pump for the rapid conversion from electromagnetic energy to thermal energy. The optimized HMX\u2010based aerogel can achieve a rapid microwave response speed (82.3\u00a0ms) and enhanced flame output. This work provides a design paradigm for developing microwave\u2010programmable EMs.\n                  <\/jats:p>","DOI":"10.1002\/smll.75887","type":"journal-article","created":{"date-parts":[[2026,9,30]],"date-time":"2026-09-30T14:42:18Z","timestamp":1790779338000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Microwave\u2010Activatable Heterointerfaces With B\/N\u2010Regulated Carbon Nitride Bridge for Coupling Microwave Absorption, Catalytic Decomposition, and Programmable Energy Release"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0009-0009-2538-442X","authenticated-orcid":false,"given":"Huijie","family":"Zhang","sequence":"first","affiliation":[{"name":"School of Chemical Engineering\/Xi'an Key Laboratory of Special Energy Materials\/Shaanxi University Key Laboratory of High\u2010Energy Chemical Materials Northwest University  Xi'an Shaanxi 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