{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,25]],"date-time":"2026-09-25T02:59:10Z","timestamp":1790305150752,"version":"4.1.0"},"reference-count":36,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,9,22]],"date-time":"2026-09-22T00:00:00Z","timestamp":1790035200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2026,9,22]],"date-time":"2026-09-22T00:00:00Z","timestamp":1790035200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22306196"],"award-info":[{"award-number":["22306196"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Developing fragmentation\u2010locked polymeric carbon nitride with global\u2010to\u2010local electron allocation is crucial for enhancing its catalytic performance toward peroxymonosulfate (PMS) activation. Herein, we propose a sodium\u2010ion\u2010locked, iodide\u2010induced structural memory strategy to synthesize fragmented polymeric carbon nitride (NI\u2010PCN), which enables a continuous global\u2010to\u2010local electron allocation pathway for boosted PMS activation.\u00a0Benefiting from this structural\u2010electronic synergism, NI\u2010PCN achieves 98% degradation of lornoxicam (LC) within 6\u00a0min (\n                    <jats:italic>K<\/jats:italic>\n                    = 0.5751 min\n                    <jats:sup>\u22121<\/jats:sup>\n                    ), which is 19.3 times higher than that of pristine PCN. Experimental characterizations combined with density functional theory (DFT) calculations reveal that Na\n                    <jats:sup>+<\/jats:sup>\n                    incorporation globally lowers the work function of the carbon nitride framework, thereby promoting long\u2010range electron migration. Meanwhile, the cyano\u2010rich edges formed during fragmentation and Na\n                    <jats:sup>+<\/jats:sup>\n                    mediated electronic regulation synergistically promote local charge polarization and interfacial electron transfer to PMS molecules. This global\u2010to\u2010local electron allocation synergy facilitates O\u2500O bond elongation and accelerates interfacial electron transfer, thus enabling efficient PMS activation. This work provides a new paradigm for the structural\u2010electronic synergistic design of high\u2010performance catalysts for PMS activation.\n                  <\/jats:p>","DOI":"10.1002\/smll.75892","type":"journal-article","created":{"date-parts":[[2026,9,22]],"date-time":"2026-09-22T13:53:24Z","timestamp":1790085204000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Fragmentation\u2010Locked Polymeric Carbon Nitride Enables Global\u2010to\u2010Local Electron Allocation for Enhanced Peroxymonosulfate Activation"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0009-0000-1145-0769","authenticated-orcid":false,"given":"Xiaoxu","family":"Zhao","sequence":"first","affiliation":[{"name":"School of Environmental Science and Engineering Tiangong University  Tianjin People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sunyu","family":"Feng","sequence":"additional","affiliation":[{"name":"School of Environmental Science and Engineering Tiangong University  Tianjin People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ying","family":"Wang","sequence":"additional","affiliation":[{"name":"School of Environmental Science and Engineering Tiangong University  Tianjin People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wei","family":"Shao","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering and Technology Tiangong University  Tianjin People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Na","family":"Chang","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering and Technology Tiangong University  Tianjin People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lijing","family":"Wang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Civil Aviation Thermal Hazards Prevention and Emergency Response School of Safety Science and Engineering Civil Aviation University of China  Tianjin People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Haitao","family":"Wang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Advanced Separation Membrane Materials Tiangong University  Tianjin People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0001-2164-1216","authenticated-orcid":false,"given":"Xiaowen","family":"Ruan","sequence":"additional","affiliation":[{"name":"School of Energy and Environment City University of Hong Kong  Kowloon Hong Kong SAR Hong Kong"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,9,22]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2024.124533"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/eem2.70347"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202526697"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2024.149155"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2021.120441"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.pmatsci.2024.101242"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.carbon.2026.121612"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.75360"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.seppur.2024.129432"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.73985"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.nanoen.2025.111551"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2023.122879"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2024.149830"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mattod.2024.09.019"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6c02423"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2024.152896"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2025.169174"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2024.124492"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.4c00266"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202111769"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202508675"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1007\/s12274\u2010024\u20106736\u20109"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2022.121941"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202303602"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202409352"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2022.136501"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202510119"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202507945"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2024.157670"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c05234"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jmst.2025.02.091"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2023.142512"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202302510"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jallcom.2020.156206"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929\u2010026\u201001507\u2010w"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202410394"}],"container-title":["Small"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/smll.75892","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/smll.75892","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/smll.75892","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,9,25]],"date-time":"2026-09-25T02:29:51Z","timestamp":1790303391000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/smll.75892"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,9,22]]},"references-count":36,"alternative-id":["10.1002\/smll.75892"],"URL":"https:\/\/doi.org\/10.1002\/smll.75892","archive":["Portico"],"relation":{},"ISSN":["1613-6810","1613-6829"],"issn-type":[{"value":"1613-6810","type":"print"},{"value":"1613-6829","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,9,22]]},"assertion":[{"value":"2026-06-04","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-09-15","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-09-22","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e75892"}}