{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,14]],"date-time":"2026-10-14T13:48:49Z","timestamp":1791985729795,"version":"4.4.0"},"reference-count":42,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,10,14]],"date-time":"2026-10-14T00:00:00Z","timestamp":1791936000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,10,14]],"date-time":"2026-10-14T00:00:00Z","timestamp":1791936000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22278046"],"award-info":[{"award-number":["22278046"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100014890","name":"Qilu University of Technology","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100014890","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    5\u2010Hydroxymethylfurfural (HMF) can be electrocatalytically oxidized to 2,5\u2010furandicarboxylic acid (FDCA) with concurrent hydrogen evolution, providing a sustainable route for biomass valorization and clean energy generation. In this study, we synthesized a three\u2010dimensional nanorod heterostructured catalyst composed of NiMoO\n                    <jats:sub>4<\/jats:sub>\n                    and NiMoP\n                    <jats:sub>2<\/jats:sub>\n                    directly on nickel foam (NiMoP@NF) via a one\u2010step hydrothermal method. Mo doping effectively enhanced the material's electrical conductivity and increased the electron cloud density around Ni active sites, while P doping introduced abundant oxygen vacancies and modulated the catalyst's electronic structure, thereby strengthening interfacial electronic coupling and optimizing the adsorption energies of reaction intermediates. Electrochemical testing shows that NiMoP@NF exhibits outstanding HMF oxidation activity: at 1.50\u00a0V vs. RHE, HMF conversion approaches 100%, FDCA yield reaches 97%, and the Faradaic efficiency is 96.8%. Mechanistic analysis indicates that the Ni\n                    <jats:sup>3+<\/jats:sup>\n                    \/Ni\n                    <jats:sup>2+<\/jats:sup>\n                    redox couple serves as the active center, while phosphorus doping improves adsorption energies and lowers the activation barrier of the rate\u2010determining step. This work presents a high\u2010performance, non\u2010precious electrocatalyst for biomass upgrading and offers design principles for heterostructured catalysts in integrated energy systems.\n                  <\/jats:p>","DOI":"10.1002\/smll.75896","type":"journal-article","created":{"date-parts":[[2026,10,14]],"date-time":"2026-10-14T13:12:44Z","timestamp":1791983564000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Molybdenum\u2010Enhanced Conductivity and Nickel Electron Density Synergizing With Phosphorus\u2010Induced Oxygen Vacancies in NiMo\u2010Based Heterostructures for Efficient Electrooxidation of 5\u2010Hydroxymethylfurfural"],"prefix":"10.1002","author":[{"given":"Zengji","family":"Yao","sequence":"first","affiliation":[{"name":"The Liaoning Province Key Laboratory of Paper and Pulp Engineering The Key Laboratory of High Value Utilization of Botanical Resources of China Light Industry College of Light Industry and Chemical Engineering Dalian Polytechnic University  Dalian China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mengchu","family":"Yuan","sequence":"additional","affiliation":[{"name":"The Liaoning Province Key Laboratory of Paper and Pulp Engineering The Key Laboratory of High Value Utilization of Botanical Resources of China Light Industry College of Light Industry and Chemical Engineering Dalian Polytechnic University  Dalian China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yapeng","family":"Jia","sequence":"additional","affiliation":[{"name":"The Liaoning Province Key Laboratory of Paper and Pulp Engineering The Key Laboratory of High Value Utilization of Botanical Resources of China Light Industry College of Light Industry and Chemical Engineering Dalian Polytechnic University  Dalian China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0213-8412","authenticated-orcid":false,"given":"Ying","family":"Han","sequence":"additional","affiliation":[{"name":"The Liaoning Province Key Laboratory of Paper and Pulp Engineering The Key Laboratory of High Value Utilization of Botanical Resources of China Light Industry College of Light Industry and Chemical Engineering Dalian Polytechnic University  Dalian China"},{"name":"State Key Laboratory of Biobased Material and Green Papermaking Qilu University of Technology Shandong Academy of Sciences  Jinan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1539-5741","authenticated-orcid":false,"given":"Xing","family":"Wang","sequence":"additional","affiliation":[{"name":"The Liaoning Province Key Laboratory of Paper and Pulp Engineering The Key Laboratory of High Value Utilization of Botanical Resources of China Light Industry College of Light Industry and Chemical Engineering Dalian Polytechnic University  Dalian China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wudeng","family":"Wang","sequence":"additional","affiliation":[{"name":"The Liaoning Province Key Laboratory of Paper and Pulp Engineering The Key Laboratory of High Value Utilization of Botanical Resources of China Light Industry College of Light Industry and Chemical Engineering Dalian Polytechnic University  Dalian China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zihao","family":"Ma","sequence":"additional","affiliation":[{"name":"The Liaoning Province Key Laboratory of Paper and Pulp Engineering The Key Laboratory of High Value Utilization of Botanical Resources of China Light Industry College of Light Industry and Chemical Engineering Dalian Polytechnic University  Dalian China"},{"name":"State Key Laboratory of Biobased Material and Green Papermaking Qilu University of Technology Shandong Academy of Sciences  Jinan China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,10,14]]},"reference":[{"key":"e_1_2_9_2_1","doi-asserted-by":"crossref","DOI":"10.1016\/j.apsusc.2026.166075","article-title":"Co3\n                  +\/Cu3\n                  + Bi\u2010Site Induced in Ce\u2010Modified Co(OH)2\/Cu2O for Boosting Oxidation of 5\u2010Hydroxymethylfurfural","volume":"728","author":"Huang Y.","year":"2026","journal-title":"Applied Surface Science"},{"key":"e_1_2_9_3_1","doi-asserted-by":"crossref","DOI":"10.1016\/j.ccr.2025.217241","article-title":"Catalytic Electrochemical Oxidation of a Bio\u2010model, 5\u2010hydroxymethyl Furfural, toward a Circular Plastic Economy","volume":"549","author":"Cao W. 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