{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,21]],"date-time":"2026-09-21T16:07:40Z","timestamp":1790006860176,"version":"4.0.1"},"reference-count":41,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,9,21]],"date-time":"2026-09-21T00:00:00Z","timestamp":1789948800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,9,21]],"date-time":"2026-09-21T00:00:00Z","timestamp":1789948800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21872086"],"award-info":[{"award-number":["21872086"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Alkaline gel electrolytes in flexible zinc\u2010air batteries (FZABs) suffer from CO\n                    <jats:sub>2<\/jats:sub>\n                    poisoning and water loss, causing decreased conductivity and carbonate crystal blockage. This work presents a Janus asymmetric PVA\/PSSA\u2011K\n                    <jats:sub>2<\/jats:sub>\n                    CO\n                    <jats:sub>3<\/jats:sub>\n                    gel polymer electrolyte (GPE) fabricated via a non\u2010solvent induced phase separation (NIPS) method, which simultaneously provides. PVA, PSSA, and K\n                    <jats:sub>2<\/jats:sub>\n                    CO\n                    <jats:sub>3<\/jats:sub>\n                    are polyvinyl alcohol, poly(4\u2010styrenesulfonic acid), and potassium carbonate, respectively. The top dense layer (pores \u223c0.28\u00a0\u00b5m) physically inhibits CO\n                    <jats:sub>2<\/jats:sub>\n                    diffusion and ensures H\n                    <jats:sub>2<\/jats:sub>\n                    O retention, ensuring conductivity. The bulk spongy layer (pores \u223c1.25\u00a0\u00b5m) stores OH\n                    <jats:sup>\u2212<\/jats:sup>\n                    and CO\n                    <jats:sub>3<\/jats:sub>\n                    <jats:sup>2\u2212<\/jats:sup>\n                    for rapid transport. Pre\u2011embedded CO\n                    <jats:sub>3<\/jats:sub>\n                    <jats:sup>2\u2212<\/jats:sup>\n                    acts as a chemical barrier, shifting the reaction CO\n                    <jats:sub>2<\/jats:sub>\n                    + 2OH\n                    <jats:sup>\u2212<\/jats:sup>\n                    \u21cc CO\n                    <jats:sub>3<\/jats:sub>\n                    <jats:sup>2\u2212<\/jats:sup>\n                    + H\n                    <jats:sub>2<\/jats:sub>\n                    O leftward to suppress carbonate crystallization. A FZAB using this GPE and Pt\/C+RuO\n                    <jats:sub>2<\/jats:sub>\n                    cathode achieves 93.5 mS cm\n                    <jats:sup>\u22121<\/jats:sup>\n                    ionic conductivity, 121.3\u00a0mW cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    peak power density, and prolonged cycling life in a 10 v% CO\n                    <jats:sub>2<\/jats:sub>\n                    atmosphere. Replacing Pt\/C+RuO\n                    <jats:sub>2<\/jats:sub>\n                    with tri\u2011site FeCo\n                    <jats:sub>SA\/NP<\/jats:sub>\n                    @NGA\u2011600 further enhances performance due to faster cathode kinetics. This study demonstrates an effective design strategy combining Janus GPE and tri\u2010site catalysts for high\u2011performance alkaline flexible ZABs.\n                  <\/jats:p>","DOI":"10.1002\/smll.75899","type":"journal-article","created":{"date-parts":[[2026,9,21]],"date-time":"2026-09-21T15:43:58Z","timestamp":1790005438000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Janus Gel Polymer Electrolyte: Asymmetric Structure Design for Anti\u2010CO\n                    <sub>2<\/sub>\n                    in Flexible Zinc\u2010Air Batteries"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0009-0009-7121-339X","authenticated-orcid":false,"given":"Yan","family":"Lu","sequence":"first","affiliation":[{"name":"Key Laboratory of Colloid and Interface Chemistry of the Ministry of Education of the P. R. China Shandong University  Jinan People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0002-2617-0086","authenticated-orcid":false,"given":"Jiamei","family":"Xiang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Colloid and Interface Chemistry of the Ministry of Education of the P. R. China Shandong University  Jinan People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Huizi","family":"Li","sequence":"additional","affiliation":[{"name":"Key Laboratory of Colloid and Interface Chemistry of the Ministry of Education of the P. R. China Shandong University  Jinan People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7055-5720","authenticated-orcid":false,"given":"Renjie","family":"Zhang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Colloid and Interface Chemistry of the Ministry of Education of the P. R. China Shandong University  Jinan People's Republic of China"},{"name":"Key Laboratory of Special Functional Aggregated Materials of the Ministry of Education of the P. R. China Shandong University  Jinan People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,9,21]]},"reference":[{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2024.103594"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202202671"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/0360\u20103199(95)00007\u2010Z"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2025.167166"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.3390\/en14092607"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201000010"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4CS00015C"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2006.07.046"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.1c00012"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2022.231237"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.pmatsci.2025.101426"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202303719"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1039\/d2ta02197h"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202102047"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2020.125031"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.9b09086"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.abb9554"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202507498"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202509503"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201068049\u2010w"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jmst.2024.03.030"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201057888\u20102"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1007\/s40820\u2010025\u201001904\u2010z"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2020.127725"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201056872\u20100"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010026\u201068514\u20100"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1007\/s42765\u2010022\u201000200\u20104"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.2c02094"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201064964\u20100"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.5c00495"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1002\/inf2.12551"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202528150"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mtchem.2023.101384"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010024\u201055677\u2010x"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.snb.2011.10.062"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.1c01065"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.energyfuels.3c05007"},{"key":"e_1_2_7_39_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpclett.3c02026"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.est.2024.110961"},{"key":"e_1_2_7_41_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2022.231020"},{"key":"e_1_2_7_42_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.73590"}],"container-title":["Small"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/smll.75899","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/smll.75899","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/smll.75899","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,9,21]],"date-time":"2026-09-21T15:43:59Z","timestamp":1790005439000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/smll.75899"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,9,21]]},"references-count":41,"alternative-id":["10.1002\/smll.75899"],"URL":"https:\/\/doi.org\/10.1002\/smll.75899","archive":["Portico"],"relation":{},"ISSN":["1613-6810","1613-6829"],"issn-type":[{"value":"1613-6810","type":"print"},{"value":"1613-6829","type":"electronic"}],"sub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