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However, when dispersed in biological media, these NCs undergo non\u2010specific interactions with surrounding species, including biomolecules. Such interactions may compromise their colloidal and physicochemical stability, alter their photoluminescence properties, and impair both in vitro and in vivo imaging and sensing performance. Here, we show that incorporating NIR\u2010emitting Ag\n                    <jats:sub>2<\/jats:sub>\n                    S\u2010based NCs into colloidal dendritic silica effectively minimizes environmental interference in complex biological media, including blood plasma and whole blood. Steady\u2010state and time\u2010resolved photoluminescence measurements reveal that both emission intensity and lifetime are substantially better preserved following incorporation into silica colloids. This preservation has a dual benefit: maintaining photoluminescence intensity enables precise NIR imaging, while retention of spectral and temporal responses preserves the NCs\u2019 thermal sensing capability. Proof\u2010of\u2010concept experiments in tissue phantoms and small\u2010animal models confirm these findings. The approach supports reliable optical readouts under biologically relevant conditions without modifying the NC composition. Overall, incorporation into dendritic silica colloids offers a viable strategy for protecting luminescent nanoparticles from biological interference and retaining their optical properties for biomedical imaging and sensing applications.\n                  <\/jats:p>","DOI":"10.1002\/smll.75921","type":"journal-article","created":{"date-parts":[[2026,9,29]],"date-time":"2026-09-29T12:43:50Z","timestamp":1790685830000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Safeguarding the Photoluminescence of Silver Sulfide Nanocrystals in Biological Environments via Silica Shielding"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0009-0002-6679-6665","authenticated-orcid":false,"given":"Alejandro","family":"Hern\u00e1ndez Medel","sequence":"first","affiliation":[{"name":"Nanomaterials for Bioimaging Group (nanoBIG) Departamento de F\u00edsica Aplicada Facultad de Ciencias Universidad Aut\u00f3noma de Madrid  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Investigaci\u00f3n Sanitaria (IRYCIS)  Madrid Spain"},{"name":"Institute for Advanced Research in Chemistry (IAdChem)  Madrid Spain"},{"name":"Instituto Nicol\u00e1s Cabrera Universidad Aut\u00f3noma de Madrid  Madrid Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3270-892X","authenticated-orcid":false,"given":"Riccardo","family":"Marin","sequence":"additional","affiliation":[{"name":"Institute for Advanced Research in Chemistry (IAdChem)  Madrid Spain"},{"name":"Intelligent Optical Nanomaterials (IONs) Lab Departamento de Qu\u00edmica Org\u00e1nica Facultad de Ciencias Universidad Aut\u00f3noma de Madrid  Madrid Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2879-0051","authenticated-orcid":false,"given":"C\u00e9lia T.","family":"Sousa","sequence":"additional","affiliation":[{"name":"Institute for Advanced Research in Chemistry (IAdChem)  Madrid Spain"},{"name":"Departamento 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