{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,24]],"date-time":"2026-09-24T15:08:04Z","timestamp":1790262484736,"version":"4.1.0"},"reference-count":56,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,9,24]],"date-time":"2026-09-24T00:00:00Z","timestamp":1790208000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,9,24]],"date-time":"2026-09-24T00:00:00Z","timestamp":1790208000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["U2541264"],"award-info":[{"award-number":["U2541264"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Combustion catalysts commonly improve the burning performance of composite solid propellants by lowering the thermal decomposition temperature of ammonium perchlorate (AP) and increasing AP heat release. However, heat release over a narrow temperature range is also critical for ignition response and regulation of the burning rate. To address this gap, we propose a concentrated heat release strategy for AP catalysis. This strategy is implemented using the Cu\u2010BDC\u2010NH\n                    <jats:sub>2<\/jats:sub>\n                    @TpPa heterostructure (Cu\u2010BDC\u2010NH\n                    <jats:sub>2<\/jats:sub>\n                    \u00a0=\u00a0copper 2\u2010aminoterephthalate; TpPa is formed by Tp, 1,3,5\u2010triformylphloroglucinol, and Pa, p\u2010phenylenediamine). The TpPa layer regulates contact between AP and Cu active sites. DSC results show that Cu\u2010BDC\u2010NH\n                    <jats:sub>2<\/jats:sub>\n                    @TpPa\u20100.20 centers the main AP exothermic peak at 322\u00b0C and narrows the heat release range from 60\u00b0C for Cu\u2010BDC\u2010NH\n                    <jats:sub>2<\/jats:sub>\n                    to 12\u00b0C. Electrochemical measurements reveal lower electrochemical polarization and a more sensitive interfacial current response in the redox potential region. Condensed\u2010phase in situ FTIR and TG\u2010DSC\u2010FTIR\u2010MS analyses indicate that the TpPa interface modulates the local NH\n                    <jats:sub>4<\/jats:sub>\n                    <jats:sup>+<\/jats:sup>\n                    \/ClO\n                    <jats:sub>4<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    vibrational environment and gaseous product evolution. DFT calculations suggest that the thermally evolved CuO\/C composite interface favors the adsorption and transformation of NH\n                    <jats:sub>3<\/jats:sub>\n                    \u2010related intermediates while facilitating the desorption of NO and NO\n                    <jats:sub>2<\/jats:sub>\n                    products. This work provides an interface regulation strategy for combustion catalysis in energetic materials.\n                  <\/jats:p>","DOI":"10.1002\/smll.75938","type":"journal-article","created":{"date-parts":[[2026,9,24]],"date-time":"2026-09-24T14:33:11Z","timestamp":1790260391000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Heterointerface\u2010Driven Combustion Catalysis for Concentrated Heat Release of Ammonium Perchlorate Over Cu\u2010BDC\u2010NH\n                    <sub>2<\/sub>\n                    @TpPa"],"prefix":"10.1002","author":[{"given":"Jiamin","family":"Qiu","sequence":"first","affiliation":[{"name":"Xi'an Modern Chemistry Research Institute  Xi'an People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yu","family":"Liu","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Shaanxi Normal University  Xi'an People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhenlong","family":"Liu","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Shaanxi Normal University  Xi'an People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiajun","family":"Li","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Shaanxi Normal University  Xi'an People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Siqi","family":"Geng","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Shaanxi Normal University  Xi'an People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0000-1250-1273","authenticated-orcid":false,"given":"Jizhen","family":"Li","sequence":"additional","affiliation":[{"name":"Xi'an Modern Chemistry Research Institute  Xi'an People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6978-7812","authenticated-orcid":false,"given":"Guofang","family":"Zhang","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Shaanxi Normal University  Xi'an People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2547-9375","authenticated-orcid":false,"given":"Ziwei","family":"Gao","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Shaanxi Normal University  Xi'an People's Republic of China"},{"name":"Research Institute of Comprehensive Energy Industry Technology College of Chemistry &amp; Chemical Engineering Yan'an University  Yan'an Shaanxi People's Republic of China"},{"name":"School of Chemistry &amp; Chemical Engineering Xinjiang Normal University  Urumqi People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,9,24]]},"reference":[{"key":"e_1_2_10_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.pecs.2016.08.002"},{"key":"e_1_2_10_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.carbon.2021.10.069"},{"key":"e_1_2_10_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.fuel.2019.115646"},{"key":"e_1_2_10_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.dt.2020.06.007"},{"key":"e_1_2_10_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.dt.2020.08.004"},{"key":"e_1_2_10_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202300661"},{"key":"e_1_2_10_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.dt.2025.08.007"},{"key":"e_1_2_10_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202501761"},{"key":"e_1_2_10_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202204109"},{"key":"e_1_2_10_11_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2RA03772F"},{"key":"e_1_2_10_12_1","doi-asserted-by":"publisher","DOI":"10.1007\/s42114\u2010023\u201000767\u20105"},{"key":"e_1_2_10_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.combustflame.2017.04.010"},{"key":"e_1_2_10_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apsusc.2025.165028"},{"key":"e_1_2_10_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/ar3002427"},{"key":"e_1_2_10_16_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41598\u2010021\u201001994\u2010w"},{"key":"e_1_2_10_17_1","doi-asserted-by":"publisher","DOI":"10.2514\/1.B37923"},{"key":"e_1_2_10_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic8008283"},{"key":"e_1_2_10_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcis.2017.01.065"},{"key":"e_1_2_10_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.langmuir.1c00108"},{"key":"e_1_2_10_21_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2020.126287"},{"key":"e_1_2_10_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.2c02384"},{"key":"e_1_2_10_23_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2023.147394"},{"key":"e_1_2_10_24_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.langmuir.5c05985"},{"key":"e_1_2_10_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr9003924"},{"key":"e_1_2_10_26_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1230444"},{"key":"e_1_2_10_27_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7CS00033B"},{"key":"e_1_2_10_28_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2QI00968D"},{"key":"e_1_2_10_29_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscentsci.8b00232"},{"key":"e_1_2_10_30_1","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.548"},{"key":"e_1_2_10_31_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.9b00550"},{"key":"e_1_2_10_32_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.0c00386"},{"key":"e_1_2_10_33_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.matt.2021.03.022"},{"key":"e_1_2_10_34_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201705454"},{"key":"e_1_2_10_35_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201806862"},{"key":"e_1_2_10_36_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2018.10.043"},{"key":"e_1_2_10_37_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1TA04493A"},{"key":"e_1_2_10_38_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202101884"},{"key":"e_1_2_10_39_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.xcrp.2023.101657"},{"key":"e_1_2_10_40_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja308278w"},{"key":"e_1_2_10_41_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jhazmat.2020.122358"},{"key":"e_1_2_10_42_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apsusc.2020.145849"},{"key":"e_1_2_10_43_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1CE00663K"},{"key":"e_1_2_10_44_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jaap.2021.105372"},{"key":"e_1_2_10_45_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.1c20510"},{"key":"e_1_2_10_46_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.csite.2024.104281"},{"key":"e_1_2_10_47_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apsusc.2023.158970"},{"key":"e_1_2_10_48_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.langmuir.5c01862"},{"key":"e_1_2_10_49_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202504755"},{"key":"e_1_2_10_50_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpca.7b01862"},{"key":"e_1_2_10_51_1","doi-asserted-by":"publisher","DOI":"10.1016\/0022\u20102860(72)80008\u20105"},{"key":"e_1_2_10_52_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41598\u2010025\u201092707\u20100"},{"key":"e_1_2_10_53_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.carbon.2012.01.036"},{"key":"e_1_2_10_54_1","doi-asserted-by":"publisher","DOI":"10.1021\/es403711y"},{"key":"e_1_2_10_55_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.tca.2015.04.025"},{"key":"e_1_2_10_56_1","doi-asserted-by":"publisher","DOI":"10.1016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