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However, the development of zinc anodes is severely constrained by dendrite growth, hydrogen evolution, and corrosion, issues that become particularly pronounced under high current densities and large areal capacities. Although constructing Zn anodes dominated by the (002) plane and introducing metal species into grain boundaries (GBs) can enhance corrosion resistance, single\u2010element modification often fails to simultaneously achieve effective electronic regulation and mechanical stability, thereby limiting further performance improvement. To address this challenge, a synergistic GB reinforcement strategy using a SnPb alloy is proposed, along with a comparative platform including commercial Zn foil, interfacial\u2010layer\u2010protected Zn anodes, and GB\u2010reinforced Zn anodes. Owing to the synergistic regulation of local electronic structure and grain\u2010boundary structural stability enabled by the SnPb alloy, the resulting Zn(002)\/SnPb anode exhibits markedly improved long\u2010term cycling stability. It operates stably for 5270\u00a0h at 40\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    with a cumulative deposited capacity of 105 Ah cm\n                    <jats:sup>\u2212<\/jats:sup>\n                    <jats:sup>2<\/jats:sup>\n                    . This work reveals the distinctive role of alloy\u2010enabled GB reinforcement and provides a practical GB engineering strategy for stable zinc anodes under extreme conditions.\n                  <\/jats:p>","DOI":"10.1002\/smll.75954","type":"journal-article","created":{"date-parts":[[2026,9,27]],"date-time":"2026-09-27T17:01:25Z","timestamp":1790528485000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Synergistic Texture Engineering and Grain\u2010Boundary Stabilization for Aqueous Zinc\u2010Ion Batteries With Ultralong Cycling Life Under Extreme Conditions"],"prefix":"10.1002","author":[{"given":"Xijun","family":"Liu","sequence":"first","affiliation":[{"name":"School of Materials Science and Engineering &amp; State Key Laboratory of Advanced Refractories Shanghai University  Shanghai People's Republic of 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