{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,29]],"date-time":"2026-09-29T13:02:02Z","timestamp":1790686922675,"version":"4.1.0"},"reference-count":69,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,9,29]],"date-time":"2026-09-29T00:00:00Z","timestamp":1790640000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,9,29]],"date-time":"2026-09-29T00:00:00Z","timestamp":1790640000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Efficient capture\u2010coupled detection of hazardous\n                    <jats:sup>222<\/jats:sup>\n                    Rn requires porous scintillators that integrate noble\u2010gas affinity, structural robustness, and radioluminescent readout under practical operating conditions. Here, we report two fluoride\u2010bridged, lanthanide\u2010cluster MOF scintillators, Tb\u2010LOF\u2010100 and Tb\u2010LOF\u2010101, together with their high\u2010entropy lanthanide\u2010node analogues (Ln\u2010LOF\u2010100 and Ln\u2010LOF\u2010101), to elucidate how high\u2010entropy node engineering regulates\n                    <jats:sup>222<\/jats:sup>\n                    Rn capture and radiation\u2010responsive performance. The high\u2010entropy MOFs retain the crystalline phases and permanent porosity of their Tb\u2010based parents, while exhibiting enhanced thermal, moisture, and \u03b3\u2010irradiation stability. In particular, Ln\u2010LOF\u2010101 delivers a static\n                    <jats:sup>222<\/jats:sup>\n                    Rn uptake capacity of 46.1 Bq g\n                    <jats:sup>\u22121<\/jats:sup>\n                    and a breakthrough adsorption coefficient of 10.9 Lg\n                    <jats:sup>\u22121<\/jats:sup>\n                    for\n                    <jats:sup>222<\/jats:sup>\n                    Rn, ranking among the best\u2010performing adsorbents reported for Rn capture under ambient conditions. Notably, Ln\u2010LOF\u2010101 exhibits an unusual moisture\u2010enhanced noble\u2010gas adsorption behavior. Xe\u2010loaded single\u2010crystal diffraction of Tb\u2010LOF\u2010101, combined with molecular simulations for Rn, identifies four preferential Rn binding sites concentrated around the metal node. Compared with the parent Tb\u2010MOFs, the high\u2010entropy MOFs show improved radioluminescence retention under repeated X\u2010ray irradiation, and their radioluminescence response toward\n                    <jats:sup>222<\/jats:sup>\n                    Rn confirms their detection capability. Despite the trade\u2010off between gas adsorption capability and scintillation efficiency, our work establishes high\u2010entropy lanthanide\u2010node engineering as a designable strategy for integrating radioactive\u2010gas capture, radiation tolerance, and scintillation readout within porous MOF platforms.\n                  <\/jats:p>","DOI":"10.1002\/smll.75962","type":"journal-article","created":{"date-parts":[[2026,9,29]],"date-time":"2026-09-29T12:42:30Z","timestamp":1790685750000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Coupling Robust\n                    <sup>222<\/sup>\n                    Rn Capture With Scintillation Readout in High\u2010Entropy Lanthanide\u2010Cluster Metal\u2010Organic Framework Scintillators"],"prefix":"10.1002","author":[{"given":"Ningjiang","family":"Song","sequence":"first","affiliation":[{"name":"Institute of Nuclear Physics and Chemistry (INPC) China Academy of Engineering Physics (CAEP)  Mianyang Sichuan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5209-1632","authenticated-orcid":false,"given":"Kai","family":"Lv","sequence":"additional","affiliation":[{"name":"Institute of Nuclear Physics and Chemistry (INPC) China Academy of Engineering Physics (CAEP)  Mianyang Sichuan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiongyu","family":"Lin","sequence":"additional","affiliation":[{"name":"Institute of Nuclear Physics and Chemistry (INPC) China Academy of Engineering Physics (CAEP)  Mianyang Sichuan China"},{"name":"Harbin Engineering University Yantai Graduate School (Harbin Engineering University Yantai Research Institute)  Yantai Shandong China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhengrong","family":"Zhao","sequence":"additional","affiliation":[{"name":"Institute of Nuclear Physics and Chemistry (INPC) China Academy of Engineering Physics (CAEP)  Mianyang Sichuan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zirui","family":"Liu","sequence":"additional","affiliation":[{"name":"Institute of Nuclear Physics and Chemistry (INPC) China Academy of Engineering Physics (CAEP)  Mianyang Sichuan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuhang","family":"Li","sequence":"additional","affiliation":[{"name":"Institute of Nuclear Physics and Chemistry (INPC) China Academy of Engineering Physics (CAEP)  Mianyang Sichuan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xuanhao","family":"Huang","sequence":"additional","affiliation":[{"name":"Institute of Nuclear Physics and Chemistry (INPC) China Academy of Engineering Physics (CAEP)  Mianyang Sichuan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0002-8888-6987","authenticated-orcid":false,"given":"Yu","family":"Gong","sequence":"additional","affiliation":[{"name":"Institute of Nuclear Physics and Chemistry (INPC) China Academy of Engineering Physics (CAEP)  Mianyang Sichuan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhen","family":"Liu","sequence":"additional","affiliation":[{"name":"Chengdu Science and Technology Development Center China Academy of Engineering Physics  Chengdu Sichuan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tie","family":"He","sequence":"additional","affiliation":[{"name":"Chengdu Science and Technology Development Center China Academy of Engineering Physics  Chengdu Sichuan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chuting","family":"Yang","sequence":"additional","affiliation":[{"name":"Institute of Nuclear Physics and Chemistry (INPC) China Academy of Engineering Physics (CAEP)  Mianyang Sichuan China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,9,29]]},"reference":[{"key":"e_1_2_9_2_1","first-page":"280","article-title":"Radon: A Leading Environmental Cause Of Lung Cancer","volume":"98","author":"Field R. W.","year":"2018","journal-title":"American Family Physician"},{"key":"e_1_2_9_3_1","doi-asserted-by":"publisher","DOI":"10.1097\/01.ede.0000152522.80261.e3"},{"key":"e_1_2_9_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202302877"},{"key":"e_1_2_9_5_1","volume-title":"Measurement of Radioactivity in the Environment\u2014Air: Radon\u2010222\u2014Part 5: Continuous Measurement Methods of the Activity Concentration","author":"International Organization for Standardization","year":"2020"},{"key":"e_1_2_9_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.scitotenv.2020.144150"},{"key":"e_1_2_9_7_1","volume-title":"Measurement of Radioactivity in the Environment\u2014Air: Radon\u2010222\u2014Part 4: Integrated Measurement Method for Determining Average Activity Concentration Using Passive Sampling and Delayed Analysis","author":"International Organization for Standardization","year":"2021"},{"key":"e_1_2_9_8_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41566\u2010023\u201001211\u20102"},{"key":"e_1_2_9_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.xcrp.2023.101694"},{"key":"e_1_2_9_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.4c15522"},{"key":"e_1_2_9_11_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4TC05299D"},{"key":"e_1_2_9_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.6c00195"},{"key":"e_1_2_9_13_1","volume-title":"Water Quality\u2014Radon\u2010222\u2014Part 4: Test Method Using Two\u2010Phase Liquid Scintillation Counting","author":"International Organization for Standardization","year":"2023"},{"key":"e_1_2_9_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.seppur.2025.134640"},{"key":"e_1_2_9_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c04025"},{"key":"e_1_2_9_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2025.159450"},{"key":"e_1_2_9_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.scp.2019.100193"},{"key":"e_1_2_9_18_1","doi-asserted-by":"publisher","DOI":"10.1524\/ract.2012.1932"},{"key":"e_1_2_9_19_1","doi-asserted-by":"publisher","DOI":"10.1038\/nmat4035"},{"key":"e_1_2_9_20_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41598\u2010023\u201033253\u20105"},{"key":"e_1_2_9_21_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2024.216358"},{"key":"e_1_2_9_22_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.enchem.2019.100006"},{"key":"e_1_2_9_23_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2022.139189"},{"key":"e_1_2_9_24_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010020\u201016647\u20101"},{"key":"e_1_2_9_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.3c03953"},{"key":"e_1_2_9_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202310270"},{"key":"e_1_2_9_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.4c03124"},{"key":"e_1_2_9_28_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3QI01231J"},{"key":"e_1_2_9_29_1","doi-asserted-by":"publisher","DOI":"10.1038\/s42004\u2010026\u201002017\u20103"},{"key":"e_1_2_9_30_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja500671h"},{"key":"e_1_2_9_31_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8DT04587A"},{"key":"e_1_2_9_32_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b00122"},{"key":"e_1_2_9_33_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.3c03064"},{"key":"e_1_2_9_34_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2SC05143E"},{"key":"e_1_2_9_35_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.4c04569"},{"key":"e_1_2_9_36_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.0c04675"},{"key":"e_1_2_9_37_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202420379"},{"key":"e_1_2_9_38_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202407435"},{"key":"e_1_2_9_39_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201411540"},{"key":"e_1_2_9_40_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4CS00003J"},{"key":"e_1_2_9_41_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsmaterialslett.5c01391"},{"key":"e_1_2_9_42_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010024\u201052225\u20105"},{"key":"e_1_2_9_43_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.5c04892"},{"key":"e_1_2_9_44_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.5c00183"},{"key":"e_1_2_9_45_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3DT03814A"},{"key":"e_1_2_9_46_1","doi-asserted-by":"publisher","DOI":"10.3390\/ma13184165"},{"key":"e_1_2_9_47_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9SC03916C"},{"key":"e_1_2_9_48_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacsau.2c00259"},{"key":"e_1_2_9_49_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4CS00997E"},{"key":"e_1_2_9_50_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.iecr.9b06820"},{"key":"e_1_2_9_51_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.1c02999"},{"key":"e_1_2_9_52_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201065545\u2010x"},{"key":"e_1_2_9_53_1","doi-asserted-by":"publisher","DOI":"10.1515\/pac\u20102014\u20101117"},{"key":"e_1_2_9_54_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr5002589"},{"key":"e_1_2_9_55_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms11831"},{"key":"e_1_2_9_56_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010024\u201054358\u2010z"},{"key":"e_1_2_9_57_1","doi-asserted-by":"publisher","DOI":"10.1021\/cm900049x"},{"key":"e_1_2_9_58_1","doi-asserted-by":"publisher","DOI":"10.1007\/s41365\u2010016\u20100008\u20107"},{"key":"e_1_2_9_59_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja302071t"},{"key":"e_1_2_9_60_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4TC02512A"},{"key":"e_1_2_9_61_1","doi-asserted-by":"publisher","DOI":"10.1039\/B905604C"},{"key":"e_1_2_9_62_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0022\u20102313(97)00113\u20100"},{"key":"e_1_2_9_63_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.cgd.5c00485"},{"key":"e_1_2_9_64_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202520018"},{"key":"e_1_2_9_65_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.1c24759"},{"key":"e_1_2_9_66_1","doi-asserted-by":"publisher","DOI":"10.3390\/molecules29163914"},{"key":"e_1_2_9_67_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.trac.2025.118133"},{"key":"e_1_2_9_68_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.adh1789"},{"key":"e_1_2_9_69_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apmt.2023.101986"},{"key":"e_1_2_9_70_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202207004"}],"container-title":["Small"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/smll.75962","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/smll.75962","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/smll.75962","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,9,29]],"date-time":"2026-09-29T12:42:31Z","timestamp":1790685751000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/smll.75962"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,9,29]]},"references-count":69,"alternative-id":["10.1002\/smll.75962"],"URL":"https:\/\/doi.org\/10.1002\/smll.75962","archive":["Portico"],"relation":{},"ISSN":["1613-6810","1613-6829"],"issn-type":[{"value":"1613-6810","type":"print"},{"value":"1613-6829","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,9,29]]},"assertion":[{"value":"2026-07-14","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-09-18","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-09-29","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e75962"}}