{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,29]],"date-time":"2026-09-29T14:06:43Z","timestamp":1790690803086,"version":"4.1.0"},"reference-count":48,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,9,29]],"date-time":"2026-09-29T00:00:00Z","timestamp":1790640000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2026,9,29]],"date-time":"2026-09-29T00:00:00Z","timestamp":1790640000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22350410379"],"award-info":[{"award-number":["22350410379"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100006013","name":"United Arab Emirates University","doi-asserted-by":"publisher","award":["12R226"],"award-info":[{"award-number":["12R226"]}],"id":[{"id":"10.13039\/501100006013","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    We demonstrate a tunable organic\/inorganic metal\u2013organic framework (MOF) structure, constructed on\n                    <jats:italic>in\u2010plane<\/jats:italic>\n                    MBene (\n                    <jats:italic>i<\/jats:italic>\n                    \u2010MBene) to serve as electrodes for supercapacitors. Bimetallic Zn\/Cu MOF was synthesized and hybridized in situ over in\u2010plane Mo\n                    <jats:sub>4\/3<\/jats:sub>\n                    Y\n                    <jats:sub>2\/3<\/jats:sub>\n                    B\n                    <jats:sub>2<\/jats:sub>\n                    (ZC\u2010MYB), whereas\n                    <jats:italic>i<\/jats:italic>\n                    \u2010MBene was produced by etching aluminum layers using hydrofluoric acid. The ZC\u2010MYB composite demonstrated a 46% increase in specific capacitance compared to ZC MOF and a 5.6\u2010fold increase over\n                    <jats:italic>i\u2010<\/jats:italic>\n                    MBene at 1 A\/g in hybrid (asymmetric) supercapacitors. The ZC\u2010MYB composite exhibited an 81% cyclic durability over 9000 cycles. The apparent diffusion coefficient of ZC and ZC\u2010MYB obtained from the Warburg element decreased, while electrochemical impedance analysis exhibited a much lower polarization resistance and a CPE response closer to the ideal capacitive behavior in 6\u00a0M KOH. The ZC\u2010MYB\/AC device, operating as an asymmetric supercapacitor, demonstrated a specific capacitance of 73.4 F\/g at a scan rate of 2\u00a0mV\/s and maintained a voltage window of 1.6\u00a0V. A Random Forest model trained on 200 experimental observations from 35 independently synthesized samples showed a moderate within\u2010domain prediction (\n                    <jats:italic>R<\/jats:italic>\n                    <jats:sup>2<\/jats:sup>\n                    = 0.522), under a leave\u2010one\u2010sample\u2010out validation. However, very low prediction of the high specific capacitance data illustrated the role of the model as an exploratory, rather than a universal predictor.\n                  <\/jats:p>","DOI":"10.1002\/smll.75965","type":"journal-article","created":{"date-parts":[[2026,9,29]],"date-time":"2026-09-29T13:19:06Z","timestamp":1790687946000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Bimetallic Zn\/Cu Metal\u2013Organic Framework (MOF)\/ Two\u2010Dimensional\n                    <i>i<\/i>\n                    \u2010MBene Hybrid Electrodes for Enhanced Supercapacitor Performance"],"prefix":"10.1002","author":[{"given":"Sana","family":"Maqbool","sequence":"first","affiliation":[{"name":"Advanced Two\u2010dimensional Materials and Devices Laboratory Department of Physics &amp; Astronomy School of Natural Sciences (SNS) National University of Sciences and Technology (NUST)  Islamabad Pakistan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0005-1259-1666","authenticated-orcid":false,"given":"Imtiaz","family":"Ahmad","sequence":"additional","affiliation":[{"name":"Advanced Two\u2010dimensional Materials and Devices Laboratory Department of Physics &amp; Astronomy School of Natural Sciences (SNS) National University of Sciences and Technology (NUST)  Islamabad Pakistan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Alina","family":"Nawaz","sequence":"additional","affiliation":[{"name":"Advanced Two\u2010dimensional Materials and Devices Laboratory Department of Physics &amp; Astronomy School of Natural Sciences (SNS) National University of Sciences and Technology (NUST)  Islamabad Pakistan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5116-1328","authenticated-orcid":false,"given":"Muhammad","family":"Yousaf","sequence":"additional","affiliation":[{"name":"ZJU\u2010Hangzhou Global Scientific and Technological Innovation Center Zhejiang University  Hangzhou People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6576-2119","authenticated-orcid":false,"given":"Iftikhar","family":"Hussain","sequence":"additional","affiliation":[{"name":"Department of Mechanical Engineering City University of Hong Kong  Kowloon Hong Kong People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5369-5588","authenticated-orcid":false,"given":"Muhammad Z.","family":"Iqbal","sequence":"additional","affiliation":[{"name":"Chemical and Petroleum Engineering United Arab Emirates University Al\u2010Ain UAE"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4119-2219","authenticated-orcid":false,"given":"Thorsten M.","family":"Gesing","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry and Crystallography University of Bremen  Bremen Germany"},{"name":"MAPEX Center for Materials and Processes University of Bremen  Bremen Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6934-0949","authenticated-orcid":false,"given":"Syed","family":"Rizwan","sequence":"additional","affiliation":[{"name":"Advanced Two\u2010dimensional Materials and Devices Laboratory Department of Physics &amp; 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