{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,30]],"date-time":"2026-09-30T14:59:47Z","timestamp":1790780387378,"version":"4.1.0"},"reference-count":189,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,9,30]],"date-time":"2026-09-30T00:00:00Z","timestamp":1790726400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,9,30]],"date-time":"2026-09-30T00:00:00Z","timestamp":1790726400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22572141"],"award-info":[{"award-number":["22572141"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>Coupling reaction is an effective strategy in the electrosynthesis field, benefiting from its clean energy resources and capacity to enrich the product category. Diverse coupling strategies have been designed to produce value\u2010added chemicals from wastes (plastic, biomass, etc.); however, they still face difficulties including multi\u2010intermediate adsorption and activation, complex catalytic mechanisms, as well as novel reaction design. A fundamental understanding of reaction mechanisms and catalyst design to achieve efficient coupling reaction is essential but remains lacking to date. To fill this gap, this review for the first time summarizes the recent advances of coupling reactions in electrosynthesis, emphasizing design principles for constructing multiple high\u2010valued compounds, reaction mechanisms of different pathways and catalyst engineering to simultaneously catalyze various reactants. We also discussed their applications and scale\u2010up productions in detail combining techno\u2010economic analysis (TEA) and life cycle assessment (LCA), presenting electrolyzer upgrade methods and practical waste recycling routes of the frontier studies. Finally, we presented the existing challenges in this area and future directions in developing more integrated processes and high\u2010performance catalysts to meet industrial needs. This review aims to provide theoretical insights for constructing coupling reactions and inspire innovative ideas to achieve efficient chemical electrosynthesis.<\/jats:p>","DOI":"10.1002\/smll.75993","type":"journal-article","created":{"date-parts":[[2026,9,30]],"date-time":"2026-09-30T14:31:06Z","timestamp":1790778666000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Coupling Reaction in Electrosynthesis: Design Principles, Reaction Mechanisms and Catalyst Engineering"],"prefix":"10.1002","author":[{"given":"Yingjie","family":"Liu","sequence":"first","affiliation":[{"name":"School of Chemical Engineering and Technology Collaborative Innovation Center of Chemical Science and Engineering Key Laboratory for Green Chemical Technology of the Ministry of Education Tianjin University  Tianjin 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