{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,27]],"date-time":"2026-09-27T16:57:23Z","timestamp":1790528243248,"version":"4.1.0"},"reference-count":75,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,9,27]],"date-time":"2026-09-27T00:00:00Z","timestamp":1790467200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,9,27]],"date-time":"2026-09-27T00:00:00Z","timestamp":1790467200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100007128","name":"Natural Science Foundation of Shaanxi Province","doi-asserted-by":"publisher","award":["2022JM\u2010087"],"award-info":[{"award-number":["2022JM\u2010087"]}],"id":[{"id":"10.13039\/501100007128","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012226","name":"Fundamental Research Funds for the Central Universities","doi-asserted-by":"publisher","award":["ZYTS25129"],"award-info":[{"award-number":["ZYTS25129"]}],"id":[{"id":"10.13039\/501100012226","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100013314","name":"Higher Education Discipline Innovation Project","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100013314","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Understanding how far solid surfaces influence the structure of adjacent water remains a central challenge in interfacial science. Here, we demonstrate that nanoscale surface roughness can induce long\u2010range ordering of interfacial water extending over tens of molecular layers under ambient conditions. We develop an attenuated total reflection infrared (ATR\u2010FTIR) differential spectroscopy strategy that enables quantitative extraction of interfacial water spectra from the overwhelming bulk\u2010water background and allows simultaneous determination of interfacial water thickness. Applied to TiO\n                    <jats:sub>2<\/jats:sub>\n                    \u2010water interfaces, this approach reveals a clear transition in hydrogen\u2010bond structure: smooth single\u2010crystal surfaces exhibit moderately strengthened hydrogen bonding similar to bulk water perturbation, whereas rough surfaces generate pronounced low\u2010frequency O\u2010H stretching bands characteristic of strongly hydrogen\u2010bonded, ice\u2010like networks. Cluster\u2010based vibrational analysis indicates that these spectral features originate from highly coordinated hydrogen\u2010bond motifs. Quantitative analysis further shows that interfacial water extends to 23\u201341 molecular layers on rough TiO\n                    <jats:sub>2<\/jats:sub>\n                    surfaces, significantly exceeding the 11\u201315 layers observed on smooth crystals. These results provide direct experimental evidence that nanoscale confinement at realistic solid\u2010liquid interfaces can stabilize extended hydrogen\u2010bond networks and establish a quantitative framework for probing interfacial water beyond the limits of conventional surface\u2010sensitive techniques.\n                  <\/jats:p>","DOI":"10.1002\/smll.76003","type":"journal-article","created":{"date-parts":[[2026,9,27]],"date-time":"2026-09-27T16:46:25Z","timestamp":1790527585000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Nanoscale Surface Roughness Induces Long\u2010Range Ordering of Interfacial Water Over Tens of Molecular Layers"],"prefix":"10.1002","author":[{"given":"Jialin","family":"Bai","sequence":"first","affiliation":[{"name":"School of Physics Xidian University  Xi'an China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xingyue","family":"Li","sequence":"additional","affiliation":[{"name":"School of Physics Xidian University  Xi'an China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhiqiang","family":"Wang","sequence":"additional","affiliation":[{"name":"School of Physics Xidian University  Xi'an China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ruiting","family":"Zhang","sequence":"additional","affiliation":[{"name":"School of Physics Xidian University  Xi'an China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lin","family":"Ma","sequence":"additional","affiliation":[{"name":"School of Physics Xidian University  Xi'an China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ke","family":"Lin","sequence":"additional","affiliation":[{"name":"School of Physics Xidian University  Xi'an China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,9,27]]},"reference":[{"key":"e_1_2_9_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586\u2010021\u201004068\u2010z"},{"key":"e_1_2_9_3_1","doi-asserted-by":"crossref","DOI":"10.1002\/anie.202425590","article-title":"Water in Electrocatalysis","volume":"64","author":"Yuan Y.","year":"2025","journal-title":"Angewandte Chemie International Edition"},{"key":"e_1_2_9_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.1c23575"},{"key":"e_1_2_9_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.paerosci.2014.07.003"},{"key":"e_1_2_9_6_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586\u2010022\u201005036\u2010x"},{"key":"e_1_2_9_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.colsurfa.2024.133604"},{"key":"e_1_2_9_8_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1NA00253H"},{"key":"e_1_2_9_9_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.ado1544"},{"key":"e_1_2_9_10_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010017\u201002635\u20105"},{"key":"e_1_2_9_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.4c08614"},{"key":"e_1_2_9_12_1","doi-asserted-by":"publisher","DOI":"10.1038\/nature14295"},{"key":"e_1_2_9_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c04271"},{"key":"e_1_2_9_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp306273d"},{"key":"e_1_2_9_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c14897"},{"key":"e_1_2_9_16_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41563\u2010019\u20100356\u2010x"},{"key":"e_1_2_9_17_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010019\u201008292\u20100"},{"key":"e_1_2_9_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cplett.2024.141666"},{"key":"e_1_2_9_19_1","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.2221304120"},{"key":"e_1_2_9_20_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1261412"},{"key":"e_1_2_9_21_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apsusc.2025.164620"},{"key":"e_1_2_9_22_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.saa.2024.125640"},{"key":"e_1_2_9_23_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.saa.2024.124413"},{"key":"e_1_2_9_24_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcb.5c00078"},{"key":"e_1_2_9_25_1","article-title":"Local Structure and Spectra of Liquid Water","volume":"46","author":"Lin K.","year":"2016","journal-title":"Scientia Sinica Physica, Mechanica & Astronomica"},{"key":"e_1_2_9_26_1","doi-asserted-by":"publisher","DOI":"10.1080\/00032719.2022.2162914"},{"key":"e_1_2_9_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpca.2c00161"},{"key":"e_1_2_9_28_1","doi-asserted-by":"crossref","first-page":"1439","DOI":"10.1021\/acs.jpcb.0c10564","article-title":"Spectroscopic and Structural Characterization of Water\u2010Shared Ion\u2010Pairs in Aqueous Sodium and Lithium Hydroxide","volume":"125","author":"Oliveira D. 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D.","year":"2024","journal-title":"Journal of Molecular Modeling"}],"container-title":["Small"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/smll.76003","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/smll.76003","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/smll.76003","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,9,27]],"date-time":"2026-09-27T16:46:28Z","timestamp":1790527588000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/smll.76003"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,9,27]]},"references-count":75,"alternative-id":["10.1002\/smll.76003"],"URL":"https:\/\/doi.org\/10.1002\/smll.76003","archive":["Portico"],"relation":{},"ISSN":["1613-6810","1613-6829"],"issn-type":[{"value":"1613-6810","type":"print"},{"value":"1613-6829","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,9,27]]},"assertion":[{"value":"2026-04-29","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-09-18","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-09-27","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e76003"}}