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Herein, inspired by the water\u2010regulation strategy of extremophiles, hydroxyectoine (HE), a natural solute with strong hydration capability, is introduced for the first time as a multifunctional electrolyte additive for AZIBs. HE enables a dual\u2010phase regulation strategy by simultaneously modulating the electrolyte hydrogen\u2010bonding network and stabilizing the zinc electrode interface. Experimental characterizations and theoretical calculations reveal that HE reconstructs the water hydrogen\u2010bonding environment, reduces free water activity, and participates in Zn\n                    <jats:sup>2+<\/jats:sup>\n                    solvation regulation, thereby suppressing parasitic hydrogen evolution and facilitating Zn\n                    <jats:sup>2+<\/jats:sup>\n                    desolvation. Meanwhile, HE preferentially interacts with the Zn surface and modifies the interfacial environment, promoting more uniform Zn deposition. Benefiting from these synergistic effects, the Zn||Zn symmetric cells deliver ultralong cycling stability over 7300\u00a0h at 5.0\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    and achieve an accumulated plating capacity of 18.25 Ah cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    . Zn||Cu cells maintain a high average Coulombic efficiency of 99.73% over 1500 cycles, while Zn\u2010based full cells retain 70.86% of their initial capacity after 3000 cycles at 5.0 A g\n                    <jats:sup>\u22121<\/jats:sup>\n                    . This bio\u2010inspired electrolyte design offers a robust route to durable, high\u2010performance AZIBs.\n                  <\/jats:p>","DOI":"10.1002\/smll.76007","type":"journal-article","created":{"date-parts":[[2026,9,27]],"date-time":"2026-09-27T16:44:21Z","timestamp":1790527461000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Extremophile\u2010Inspired Hydroxyectoine Reconstructs Water Networks and Stabilizes Zinc Interfaces in Aqueous Zinc Batteries"],"prefix":"10.1002","author":[{"given":"Juanjuan","family":"Zhang","sequence":"first","affiliation":[{"name":"State Key Laboratory of Chemistry and Utilization of Carbon Based Energy Resources College of Chemistry Xinjiang University  Urumqi Xinjiang China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zihao","family":"Zhong","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Chemistry and Utilization of Carbon Based Energy Resources College of Chemistry Xinjiang University  Urumqi Xinjiang China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yang","family":"Wang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Chemistry and Utilization of Carbon Based Energy Resources College of Chemistry Xinjiang University  Urumqi Xinjiang China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yu","family":"Zhang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Chemistry and Utilization of Carbon Based Energy Resources College of Chemistry Xinjiang University  Urumqi Xinjiang China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kuan","family":"Hu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Chemistry and Utilization of Carbon Based Energy Resources College of Chemistry Xinjiang University  Urumqi Xinjiang 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