{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,30]],"date-time":"2026-09-30T06:55:15Z","timestamp":1790751315009,"version":"4.1.0"},"reference-count":53,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,9,29]],"date-time":"2026-09-29T00:00:00Z","timestamp":1790640000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,9,29]],"date-time":"2026-09-29T00:00:00Z","timestamp":1790640000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22475178"],"award-info":[{"award-number":["22475178"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012226","name":"Fundamental Research Funds for the Central Universities","doi-asserted-by":"publisher","award":["SWU\u2010XDJH202314"],"award-info":[{"award-number":["SWU\u2010XDJH202314"]}],"id":[{"id":"10.13039\/501100012226","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Self\u2010assembled monolayers (SAMs) play an important role in high\u2010efficiency inverted perovskite solar cells (PSCs), which optimize interfacial contact and facilitate efficient hole extraction. Conventional SAMs adopt flexible alkyl chains as linkers, which may suffer from loose molecular arrangement, unfavorable surface coverage, and poor interfacial stability, limiting the overall device performance. Although SAMs incorporating rigid linkers have recently been reported, their molecular structures are mostly confined to phenyl\u2010based linkers. In this work, a rigid furan linker was introduced for the first time to construct new SAMs, and we investigated how anchoring\u2010group substitution positions affect device performance. Results showed that the rigid furan linker effectively enabled a uniform and dense coverage on the substrate. Moreover, TA2 with a carboxylic acid at C5 position possesses a larger dipole moment than TA1, which could more effectively modulate the substrate work function, facilitate interfacial charge transport, and suppress nonradiative recombination. Inverted PSCs based on TA2 achieved an optimized efficiency of 25.34%. Additionally, large\u2010area devices (1 cm\n                    <jats:sup>2<\/jats:sup>\n                    ) and modules (15.136 cm\n                    <jats:sup>2<\/jats:sup>\n                    ) delivered efficiencies of 23.3% and 22.99%, respectively. This work suggests that furan could work well as the linker to connect the terminal group and the anchoring unit, establishing an effective molecular design guideline for high\u2010performance SAMs.\n                  <\/jats:p>","DOI":"10.1002\/smll.76034","type":"journal-article","created":{"date-parts":[[2026,9,30]],"date-time":"2026-09-30T05:58:37Z","timestamp":1790747917000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Furan\u2010Bridged SAMs: Anchoring Position Regulation for High\u2010Performance Inverted Perovskite Solar Cells"],"prefix":"10.1002","author":[{"given":"Wanjia","family":"Yao","sequence":"first","affiliation":[{"name":"Chongqing Key Laboratory of Battery Materials and Technologies School of Materials &amp; Energy Southwest University Chongqing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mingxin","family":"Wang","sequence":"additional","affiliation":[{"name":"Chongqing Key Laboratory of Battery Materials and Technologies School of Materials &amp; Energy Southwest University Chongqing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Huilin","family":"Xie","sequence":"additional","affiliation":[{"name":"Chongqing Key Laboratory of Battery Materials and Technologies School of Materials &amp; Energy Southwest University Chongqing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Miaoxin","family":"Li","sequence":"additional","affiliation":[{"name":"Chongqing Key Laboratory of Battery Materials and Technologies School of Materials &amp; Energy Southwest University Chongqing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Peng","family":"Wang","sequence":"additional","affiliation":[{"name":"Yunnan Key Laboratory For Micro\/Nano Materials &amp; Technology International Joint Research Center for Optoelectronic and Energy Materials School of Materials and Energy Yunnan University  Kunming China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4799-2871","authenticated-orcid":false,"given":"Yong","family":"Hua","sequence":"additional","affiliation":[{"name":"Yunnan Key Laboratory For Micro\/Nano Materials &amp; Technology International Joint Research Center for Optoelectronic and Energy Materials School of Materials and Energy Yunnan University  Kunming China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wei","family":"Gao","sequence":"additional","affiliation":[{"name":"Xiamen Key Laboratory of Optoelectronic Materials and Advanced Manufacturing Institute of Luminescent Materials and Information Displays College of Materials Science and Engineering Huaqiao University  Xiamen China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wenjun","family":"Zhang","sequence":"additional","affiliation":[{"name":"School of New Energy Ningbo University of Technology Ningbo China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7756-9313","authenticated-orcid":false,"given":"Cheng","family":"Zhong","sequence":"additional","affiliation":[{"name":"Hubei Key Lab On Organic and Polymeric Optoelectronic Materials Department of Chemistry Wuhan University Wuhan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fei","family":"Wu","sequence":"additional","affiliation":[{"name":"Chongqing Key Laboratory of Battery Materials and Technologies School of Materials &amp; Energy Southwest University Chongqing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0666-2462","authenticated-orcid":false,"given":"Linna","family":"Zhu","sequence":"additional","affiliation":[{"name":"Chongqing Key Laboratory of Battery Materials and Technologies School of Materials &amp; Energy Southwest University Chongqing China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,9,29]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.nanoen.2024.110523"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1007\/s40843\u2010024\u20103093\u20109"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/accountsmr.5c00170"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202500536"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.3c00396"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4EE02492C"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586\u2010022\u201005268\u2010x"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202419391"},{"key":"e_1_2_8_10_1","doi-asserted-by":"crossref","DOI":"10.1039\/C8RA01513A","article-title":"Bottom\u2010Electrode Induced Defects in Self\u2010Assembled Monolayer (SAM)\u2010Based Tunnel Junctions Affect Only the SAM Resistance, not the Contact Resistance or SAM Capacitance","volume":"8","author":"Sangeeth C. 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